摘要:
Siloxanes containing epoxy groups having the formula 1 ##STR1## Formula 1 whereinA means a C.sub.1 -C.sub.20 alkyl radical with epoxy groupsB means R.sup.1 or AR.sup.1, R.sup.2 independently of each other, means C.sub.1 -C.sub.20 alkyl or C.sub.6 -C.sub.10 aryla means zero or a whole number from 1-100b means zero or a whole number from 1-100c means a whole number from 1-5.
摘要:
Mixtures ofA) 75 to 99.5 wt. % of a high molecular weight, thermoplastic, aromatic polycarbonate with a molecular weight M.sub.w (weight average) of at least 10,000 which contains bifunctional carbonate structural units of the formula (I), ##STR1## in which R.sup.1 and R.sup.2, independently of each other, represent hydrogen, halogen, preferably chlorine or bromine, or a C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.6 -cycloalkyl, C.sub.6 -C.sub.10 -aryl, preferably phenyl, or C.sub.7 -C.sub.12 -aralkyl, preferably phenyl-C.sub.1 -C.sub.4 -alkyl, in particular a benzyl group,m is an integer from 4 to 7, preferably 4 or 5,R.sup.3 and R.sup.4 can be selected separately for each X and, independently of each other, represent hydrogen or a C.sub.1 -C.sub.6 -alkyl group andX represents carbon,with the proviso that R.sup.3 and R.sup.4 simultaneously represent an alkyl group on at least one X atom.B) 0.5 to 15 wt. % of an aliphatic hydrocarbon with a molecular weight of 300 to 3,000 in particular mineral oil andC) 0 to 11 wt. % of a terpolymer of ethylene, acrylate and a monomer with epoxy groups, and the preparation of these mixtures.
摘要:
A process for the production of polyamide mouldings, characterized in that a polyamide melt is extruded through nozzles to form strands, which at a temperature of from 25.degree. C. below to the respective polyamide softing point in a ratio of from 1:1.5 to 1:8 are stretched and granulated, and the granulate is worked-up in a known manner to produce injection mouldings.
摘要:
This disclosure is concerned with a process for molding polyethylene terephthalate at a reduced mold temperature, i.e., less than 120.degree. C., and still obtaining crystalline parts by incorporating a small amount of a two phase polyacrylate comprised of a cross-linked elastomeric first phase to which a rigid thermoplastic second phase has been grafted. It is also concerned with a glass reinforced polyethylene terephthalate especially suitable for molding into colder molds which contain this two phase polyacrylate.
摘要:
This disclosure is concerned with a process for injection molding polyethylene terephthalate into colder molds, i.e., less than 120.degree. C., and still obtaining crystalline parts by incorporating an organic imide containing compound having a melting point in excess of 240.degree. C. into the composition. The presence of this additive enhances the crystallization velocity of the composition and permits the achievement of crystalline parts with optimum properties with colder molds and shorter molding cycles than are conventional for polyethylene terephthalate molding compositions.
摘要:
This invention relates to polyalkylene terephthalates which crystallize rapidly, and process of making such compositions and a process of using such compositions in injection molding. The compositions comprise polyalkylene terephthalates with intrinsic viscosities in excess of about 0.4 dl/g in 1:1 phenol/tetrachloroethane at 25.degree. C. and at least about 0.5 wt. %, based on the weight of resin and additive, of an aromatic carboxylic acid ester. These compositions may be prepared by intimately mixing the ingredients, for example by extrusion. These compositions, particularly those wherein the polyester consists essentially of polyethylene terephthalate, may be injection molded with mold temperatures less than about 120.degree. C. and still retain a significant degree of crystallinity even with short mold residence times.
摘要:
Terephthalic copolyesters, the diol component of which consists of ethylene glycol and 2.2-diethyl propane-1.3-diol crystallize more rapidly than pure polyethylene terephthalate and can be molded in a way comparable to butylene terephthalate.
摘要:
An arrangement for motorized assistance in movement of manually movable components of medical apparatuses is provided. The arrangement includes at least one torque sensor that is arranged in a drivetrain of a movable component of a medical apparatus. The at least one torque sensor detects the moments occurring in the drivetrain in a stationary state and in motion. Using an evaluation unit, the torque detected by the at least one torque sensor may be compared against a predefinable first threshold value. The first threshold value is predefined according to a possible position of the movable component. The arrangement includes a drive unit, by which the drive of the drivetrain may be provided with motorized assistance when the first threshold value is exceeded.
摘要:
A multilayered article is disclosed, which includes, in sequence: (1) a substrate (S), e.g., of thermoplastic polycarbonate; (2) a scratch-resistant layer (SR); and (3) a top layer (T). The scratch-resistant layer is prepared by curing a scratch-resistant coating composition comprising a polycondensate prepared from at least one silane, said polycondensate being prepared by a sol-gel process. The top layer is prepared by curing a top layer coating composition prepared by hydrolyzing a composition which includes: at lest one compound represented by general formula I, M(R′)m (I) wherein M is an element selected from the group consisting of Si, Ti, Zr, Sn, Ce, Al, B, VO, In and Zn, R′ represents a hydrolysable radical, and m is an integer from 2 to 4; and optionally at least one compound represented by general formula II, RbSiR′a, (II) wherein the radicals R′ and R are the same or different, R′ is as defined for general formula (I), R represents a group selected from an alkyl group, an alkenyl group, an aryl group, a hydrocarbon group with at least one halogen group, an epoxide group, a glycidyloxy group, an amino group, a mercapto group, a methacryloxy group and a cyano group, and a and b independently of one another have a value from 1 to 3, provided that the sum of a and b is four. The multilayered articles are distinguished by possessing outstanding scratch and abrasion resistance.
摘要:
A process for the production of polycarbonate molded article having low dust attraction is disclosed. the process entails treating at least a portion of the surface of a molded article by at least one procedure selected from the group consisting of flame treatment, corona treatment and plasma treatment to obtain a treated surface.