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    Process for preparing TCD-monenal
    11.
    发明申请
    Process for preparing TCD-monenal 失效
    制备TCD- monenal的方法

    公开(公告)号：US20050107640A1

    公开(公告)日：2005-05-19

    申请号：US10968760

    申请日：2004-10-19

    Applicant: Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    Inventor： Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    IPC: C07B61/00 ,  C07C45/50 ,  C07C45/82 ,  C07C47/44 ,  C07C47/445 ,  C07C47/38

    CPC classification number: C07C47/445 ,  C07C45/50 ,  C07C45/82

    Abstract: A process for selectively hydroformylating dicyclopentadiene to 8(9)-formyltricyclo-[5.2.1.02,6]dec-3-ene in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus(III) compounds in complex-bound form, of group VIII of the Periodic Table of the Elements, wherein the water-soluble organic phosphorus(III) compounds are alkali metal or alkaline earth metal salts of sulfonated arylphosphines and aryldiphosphines.

    Abstract translation: 使用含水的过渡金属化合物的水溶液在非均相反应体系中选择性地将二环戊二烯加氢甲酰化为8（9） - 甲酰基三环[5.2.1.0 2,6]癸-3-烯的方法 其中水溶性有机磷（III）化合物是磺化芳基膦和芳基二膦的碱金属或碱土金属盐，它们是复合结合形式的元素周期表第Ⅷ族的可溶性有机磷（III）化合物。

    Process for preparing TCD-dialdehyde
    12.
    发明申请
    Process for preparing TCD-dialdehyde 失效
    制备TCD-二醛的方法

    公开(公告)号：US20050101805A1

    公开(公告)日：2005-05-12

    申请号：US10967731

    申请日：2004-10-18

    Applicant: Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    Inventor： Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    IPC: B01J31/24 ,  C07B61/00 ,  C07C45/50 ,  C07C45/82 ,  C07C47/347 ,  C07C47/445 ,  C07C47/28

    CPC classification number: C07C47/347 ,  C07C2603/68

    Abstract: A process for preparing 3(4),8(9)-bisformyltricyclo[5.2.1.02.6]decane by hydroformylating dicyclopentadiene with subsequent distillation wherein the hydroformylation of dicyclopentadiene is carried out in two stages, and, in the first hydroformylation stage, the reaction is effected in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus (lll) compounds in complex-bound form, of group Vlll of the Period Table of the Elements to give 8(9)-bisformyltricyclo[5.2.1.02.6]dec-3-ene, and, in a second hydroformylation stage, the thus obtained 8(9)-bisformyltricyclo[5.2.1.02.6]dec-3-ene is converted, in homogeneous organic phase in the presence of transition metal compounds of group Vlll of the Periodic Table of the Elements to 3(4),8(9)-bisformyltricyclo[5.2.1.02.6]decane.

    Abstract translation: 通过加氢甲酰化二环戊二烯制备3（4），8（9） - 双甲基三环[5.2.1.0]癸烷的方法，随后蒸馏，其中二环戊二烯的加氢甲酰化分两个阶段进行， 第一加氢甲酰化阶段，反应在非均相反应体系中使用过渡金属化合物的水溶液进行，所述过渡金属化合物含有复合结合形式的水溶性有机磷（III）化合物，元素周期表第VI1组 得到8（9） - 二甲基三环[5.2.1.0,26.6]癸-3-烯，并在第二加氢甲酰化阶段中，由此得到的8（9） - 二甲基三环[5.2.1.0] 在（3），（9） - 双甲基三环[5.2]的元素周期表第VI1组的过渡金属化合物的存在下，在均相有机相中转化2,6-二烯-3-烯。 1.06D癸烷。

    Process for the recovery of rhodium from the residues of distillation processes
    13.
    发明授权
    Process for the recovery of rhodium from the residues of distillation processes 失效
    从蒸馏工艺残留物中回收铑的方法

    公开(公告)号：US5151537A

    公开(公告)日：1992-09-29

    申请号：US741643

    申请日：1991-08-07

    Applicant: Peter Lappe ,  Helmut Springer

    Inventor： Peter Lappe ,  Helmut Springer

    IPC: B01J38/00 ,  B01J31/40 ,  C01G55/00 ,  C07C45/50 ,  C07C47/02

    CPC classification number: B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/4046 ,  C01G55/001 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/822 ,  B01J31/04 ,  B01J31/26 ,  Y02P20/584

    Abstract: The recovery of rhodium, present as a homogeneous dissolved complex compound especially in residues of products of the oxo process, is carried out in a two-stage process. In the first stage, the residues are treated with a gas-containing oxygen in the presence of a C.sub.2 - to C.sub.4 - monocarboxylic acid and an alkali metal salt of a C.sub.2 - to C.sub.4 -monocarboxylic acid, and are then extracted with water. In the second reaction stage, they are treated again with a gas-containing oxygen, an aldehyde, a C.sub.2 - to C.sub.4 -monocarboxylic acid, and an alkali metal salt of a C.sub.2 to C.sub.4 monocarboxylic acid, and are extracted once more with water.

    Abstract translation: 作为均匀溶解的络合物，特别是在羰基工艺的产物的残基中存在的铑的回收在两步法中进行。 在第一阶段中，在C2- C4-一元羧酸和C2- C4-一元羧酸的碱金属盐的存在下，用含氧气体处理残留物，然后用水萃取。 在第二反应阶段，用含气体的氧，醛，C 2〜C 4 - 一元羧酸和C 2〜C 4一元羧酸的碱金属盐再次处理，再次用水萃取。

    Process for preparing TCD-alcohol DM
    15.
    发明授权
    Process for preparing TCD-alcohol DM 失效
    制备TCD-醇DM的方法

    公开(公告)号：US06939997B2

    公开(公告)日：2005-09-06

    申请号：US10967580

    申请日：2004-10-18

    Applicant: Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    Inventor： Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    IPC: B01J31/24 ,  C07B61/00 ,  C07C29/141 ,  C07C29/16 ,  C07C31/27 ,  C07C45/50 ,  C07C47/347 ,  C07C47/445 ,  C07C35/22

    CPC classification number: C07C29/141 ,  C07C29/16 ,  C07C45/50 ,  C07C47/347 ,  C07C2603/68 ,  C07C31/278 ,  C07C47/12 ,  C07C47/02

    Abstract: A process for preparing 3(4),8(9)-dihydroxymethyltricyclo[5.2.1.02,6]decane by hydroformylating dicyclopentadiene with subsequent distillation wherein the hydroformylation of dicyclopentadiene is carried out in two stages, and, in a first hydroformylation stage, the reaction is effected in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus (III) compounds in complex-bound form, of group VIII of the Periodic Table to give 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene, and, in a second hydroformylation stage, the thus obtained 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene is converted, in homogeneous organic phase in the presence of transition metal compounds of group VIII of the Periodic Table of the Elements to 3(4),8(9)-bisformyltricyclo[5.2.1.02,6]decane.

    Abstract translation: 通过加氢甲酰化二环戊二烯制备3（4），8（9） - 二羟基甲基三环[5.2.1.0 2,6]癸烷的方法，随后蒸馏，其中二环戊二烯的加氢甲酰化分两个阶段进行， 在第一加氢甲酰化阶段，反应在非均相反应体系中使用过渡金属化合物的水溶液进行，该过渡金属化合物含有复合结合形式的元素周期表第Ⅷ族的水溶性有机磷（III）化合物，得到 8（9） - 甲酰三环[5.2.1.0 2,6]癸-3-烯，并在第二加氢甲酰化阶段，由此得到的8（9） - 甲酰基三环[5.2.1.0 < 在3元周期表的第Ⅷ族过渡金属化合物存在下，在均相有机相中转变为3,6-亚甲基三环，8（9） - 二甲基三环 [5.2.1.0 2,6]癸烷。

    Process for preparing TCD-diamine
    16.
    发明申请
    Process for preparing TCD-diamine 失效
    制备TCD-二胺的方法

    公开(公告)号：US20050101796A1

    公开(公告)日：2005-05-12

    申请号：US10967597

    申请日：2004-10-18

    Applicant: Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    Inventor： Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    IPC: C07C209/24 ,  C07B61/00 ,  C07C47/347 ,  C07C47/445 ,  C07C209/26 ,  C07C211/19 ,  C07C211/38 ,  C07C255/31 ,  C07C29/24

    CPC classification number: C07C209/26 ,  C07C47/347 ,  C07C47/445 ,  C07C2603/68 ,  C07C211/19

    Abstract: A process for preparing 3(4),8(9)-bis(aminomethyl)tricycle-[5.2.1.02,6]decane by hydroformylating dicyclopentadiene with subsequent reductive amination wherein the hydroformylation of dicyclopentadiene is carried out in two stages, and, in a first hydroformylation stage, the reaction is effected in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus (III) compounds in complex-bound form, of group VIII of the Periodic Table to give 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene, and, in a second hydroformylation stage, the thus obtained 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene is converted, in a homogeneous organic phase in the presence of transition metal compounds of group VIII of the Periodic Table of the Elements to 3(4),8(9)-bisformyltricyclo[5.2.1.02,6]decane

    Abstract translation: 通过加氢甲酰化二环戊二烯制备3（4），（9） - 双（氨基甲基）三环[5.2.1.0 2,6]癸烷的方法，随后还原胺化，其中携带二环戊二烯的加氢甲酰化 在两个阶段中，并且在第一加氢甲酰化阶段中，使用过渡金属化合物的水溶液在非均相反应体系中进行反应，所述过渡金属化合物含有复合结合形式的水溶性有机磷（III）化合物，第VIII族 的化合物，得到8（9） - 甲酰基三环[5.2.1.0 2,6]癸-3-烯，并在第二加氢甲酰化阶段，由此得到的8（9） - 甲酰三环 在[...]元素周期表第Ⅷ族过渡金属化合物存在下，在均相有机相中将[5.2.1.0 2,6]癸烯转化为3（4） ，8（9） - 二甲基三环[5.2.1.0 2,6]癸烷

    Quaternary ammonium salts of sulfonated triarylphosphines and process for the production thereof
    18.
    发明授权
    Quaternary ammonium salts of sulfonated triarylphosphines and process for the production thereof 失效
    磺化三芳基膦的季铵盐及其制备方法

    公开(公告)号：US4673535A

    公开(公告)日：1987-06-16

    申请号：US738868

    申请日：1985-05-29

    Applicant: Helmut Bahrmann ,  Boy Cornils ,  Wolfgang Lipps ,  Peter Lappe ,  Helmut Springer

    Inventor： Helmut Bahrmann ,  Boy Cornils ,  Wolfgang Lipps ,  Peter Lappe ,  Helmut Springer

    IPC: B01J31/24 ,  C07F9/50 ,  C07C87/30

    CPC classification number: C07F9/5022

    Abstract: The invention relates to new quaternary ammonium salts of di and trisulfonated triarylphosphines as well as a process for their preparation. The salts are of Formula I ##STR1## wherein Ar.sub.1, Ar.sub.2, and Ar.sub.3 are each independently an aryl; X.sup.1, X.sup.2, and X.sup.3 are each independently a sulfo group; y.sup.1, y.sup.2, and y.sup.3 are each independently 0 or 1, provided that their sum is at least 1; A is an alkyl, hydroxyalkyl, aralkyl, or aryl having 6-25 carbon atoms; B, C, and D are straight chain or branched alkyl having 1-4 carbons; and n is a whole number of 1-3.

    Abstract translation: 本发明涉及二和三磺化三芳基膦的新季铵盐及其制备方法。 该盐具有式I的化合物，其中Ar 1，Ar 2和Ar 3各自独立地为芳基; X 1，X 2和X 3各自独立地为磺基; y1，y2和y3各自独立地为0或1，条件是它们的和为至少1; A是具有6-25个碳原子的烷基，羟基烷基，芳烷基或芳基; B，C和D是具有1-4个碳的直链或支链烷基; n为1-3的整数。

    Process for the preparation of sulfonated aryl phosphine
    19.
    发明授权
    Process for the preparation of sulfonated aryl phosphine 失效
    磺化芳基膦的制备方法

    公开(公告)号：US4483802A

    公开(公告)日：1984-11-20

    申请号：US534089

    申请日：1983-09-20

    Applicant: Roderich Gartner ,  Boy Cornils ,  Helmut Springer ,  Peter Lappe

    Inventor： Roderich Gartner ,  Boy Cornils ,  Helmut Springer ,  Peter Lappe

    IPC: C07F9/50 ,  C07C143/24

    CPC classification number: C07F9/5054 ,  C07F9/5095

    Abstract: A process for the preparation of mono, di or trisulfonated aryl phosphines whereby triaryl phosphine is sulfonated with oleum at 0.degree. to 40.degree. C. After dilution of the reaction product with water, the sulfonated triaryl phosphine is extracted with an amine dissolved in an organic solvent; both the amine and organic solvent being insoluble in water. From the organic phase the sulfonated phosphine is transferred to the aqueous phase by treatment with an aqueous solution of a base.

    Abstract translation: 一种制备单，二或三磺化芳基膦的方法，其中三芳基膦在0-40℃下用发烟硫酸磺化。在用水稀释反应产物后，将磺化的三芳基膦用溶解在有机物中的胺萃取 溶剂; 胺和有机溶剂都不溶于水。 从有机相中，通过用碱的水溶液处理将磺化膦转移到水相中。

    Process for preparing TCD-monenal
    20.
    发明授权
    Process for preparing TCD-monenal 失效
    制备TCD- monenal的方法

    公开(公告)号：US07122706B2

    公开(公告)日：2006-10-17

    申请号：US10968760

    申请日：2004-10-19

    Applicant: Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    Inventor： Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    IPC: C07C45/50

    CPC classification number: C07C47/445 ,  C07C45/50 ,  C07C45/82

    Abstract: A process for selectively hydroformylating dicyclopentadiene to 8(9)-formyltricyclo-[5.2.1.02,6]dec-3-ene in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus(III) compounds in complex-bound form, of group VIII of the Periodic Table of the Elements, wherein the water-soluble organic phosphorus(III) compounds are alkali metal or alkaline earth metal salts of sulfonated arylphosphines and aryldiphosphines.

    Abstract translation: 使用含水的过渡金属化合物的水溶液在非均相反应体系中选择性地将二环戊二烯加氢甲酰化为8（9） - 甲酰基三环[5.2.1.0 2,6]癸-3-烯的方法 其中水溶性有机磷（III）化合物是磺化芳基膦和芳基二膦的碱金属或碱土金属盐，它们是复合结合形式的元素周期表第Ⅷ族的可溶性有机磷（III）化合物。

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