摘要:
New phenoxypyridylmethyl esters of the general formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given in the description andR represents the radical ##STR2## wherein R.sup.4 and R.sup.5 have the meaning given in the description, and represents the radical ##STR3## wherein R.sup.6 and R.sup.7 have the meaning given in the description, are obtained by a process in which carboxylic acids of the general formulaR--COOH (II)wherein R has the meaning given previously, or reactive derivatives of these acids, are reacted with phenoxypyridyl alcohols of the general formula ##STR4## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given above, or with reactive derivatives of these alcohols, if appropriate in the presence of acid acceptors, if appropriate in the presence of catalysts and if appropriate in the presence of diluents. The new phenoxypyridylmethyl esters of the formula (I) are distinguished by a high pesticidal, particularly insecticidal and acardicidal activity.
摘要:
2-Phenyl-alk-1-enyl-cyclopropane-carboxylic acid esters of the formula ##STR1## in which R each independently ishydrogen, halogen, cyano, nitro and, in each case optionally halogen-substituted, alkyl, alkoxy, alkylenedioxy or alkylthio,R.sup.1 is optionally halogen-substituted alkyk, andR.sup.2 is a radical customary in the alcohol part of pyrethroidswhich exhibit insecticidal and acaricidal activity. They are made from the corresponding alkyl esters which are new and made by novel processes.
摘要:
2-Phenyl-alk-1-enyl-cyclopropane-carboxylic acid esters of the formula ##STR1## in which R each independently is hydrogen, halogen, cyano, nitro and, in each case optionally halogen-substituted, alkyl, alkoxy, alkylenedioxy or alkylthio,R.sup.1 is optionally halogen-substituted alkyk, andR.sup.2 is a radical customary in the alcohol part of pyrethroidswhich exhibit insecticidal and acaricidal activity. They are made from the corresponding alkyl esters which are new and made by novel processes.
摘要:
2,2-Dimethyl-3-(2-bromo-2-phenyl-vinyl)-cyclopropanecarboxylic acid 3-phenoxybenzyl ester of the formula ##STR1## which possess arthropodicidal properties. In addition, the new intermediate of the formula ##STR2## is produced by reacting an .alpha.-bromo-benzyl-phosphonic acid ester of the formula ##STR3## in which R.sup.6 each independently is alkyl or phenyl, or the two radicals R.sup.6 together are alkanediyl, with a 3-formyl-2,2-dimethyl-cyclopropanecarboxylic acid ester and saponifying. Also the compounds of the formula ##STR4## which are new when R.sup.1 is not alkyl, are produced by reacting triphenylphosphine and bromine to form dibromo-triphenylphosphorane, and reacting the dibromo-triphenylphosphorane without isolation with an .alpha.-hydroxy-benzyl-phosphonic acid ester of the formula ##STR5##
摘要:
3-Phenoxy-fluoro-benzyl carboxylic acid esters of the formula ##STR1## in which R.sup.2 is hydrogen, cyano or ethynyl,R.sup.3 is ##STR2## R.sup.4 and R.sup.5 represent chlorine, bromine or methyl, and R.sup.6 is phenyl or phenyl substituted with halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, nitro or methylenedioxy,which possess arthropodicidal properties. The alcohols are also new.
摘要:
Substituted phenyl-cyclopropanecarboxylic acid esters of the formula ##STR1## in which R.sup.1 represents an alkoxy or alkylthio radical which is monosubstituted or polysubstituted by identical or different halogen substituents,R.sup.2 represents a hydrogen or halogen atom, orR.sup.1 and R.sup.2 together represent an alkylenedioxy radical which is monosubstituted or polysubstituted by identical or different halogen substituents,R.sup.3 represents a hydrogen atom, a cyano group or an alkyl, alkenyl or alkinyl radicals which is optionally monosubstituted or polysubstituted by identical or different halogen substituents,Y represents a nitrogen atom or a methinyl radical, andR.sup.4 and R.sup.5 are identical or different and represent a hydrogen or halogen atom,which possess pesticidal properties, plus novel intermediates therefor.
摘要:
A 3-phenoxy-fluorobenzyl alcohol of the formula ##STR1## in which R.sup.2 is hydrogen, cyano or ethynyl.The compounds can be esterified with pyrethroid-type carboxylic acids to give highly active insecticides.
摘要:
Fluorine-containing phenylacetic acid esters of the formula ##STR1## in which R represents the radical of an alcohol customary in the case of pyrethroids,R.sup.1 represents C.sub.2-4 -alkyl, C.sub.2-4 -alkenyl or cyclopropyl,X represents H, halogen, alkyl, alkoxy, OCHF.sub.2, SCHF.sub.2, SCClF.sub.2 or SCF.sub.3 andX.sup.1 can vary widely or form a fused ring with X, the overall compound necessarily containing a fluorine atom, which compounds possess arthropodicidal properties. Intermediates therefor and an overall synthesis from an alcohol of the formula ROH and a toluene of the formula ##STR2## are also shown.
摘要:
2,2,3,3-Tetramethylcyclopropanecarboxylic acid fluorine-substituted-benzyl esters of the formula ##STR1## in which R.sup.1 is hydrogen, cyano, or alkyl, alkenyl or alkynyl each with up to 4 carbon atoms, andR.sup.2 is a phenyl radical which is substituted by halogen and/or by optionally halogen-substituted phenoxy, with the proviso that the radical R.sup.2 in total contains at least one fluorine substituent,which possess insecticidal and acaricidal properties.
摘要:
3-Phenoxybenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates of the formula ##STR1## in which R, R.sup.1 and R.sup.2 each independently is hydrogen or halogen,R.sup.3 is phenyl, phenylthio, or phenyl or phenylthio carrying at least one alkyl group or halogen atom,Y is hydrogen or cyano,n is 1, 2, 3, 4 or 5, andm is 1, 2, 3 or 4,which possess arthropodicidal properties.