Ester of Michael addition homopolymers of acrylic acid
    15.
    发明授权
    Ester of Michael addition homopolymers of acrylic acid 失效
    迈克尔酯的酯加成丙烯酸的均聚物

    公开(公告)号:US5243069A

    公开(公告)日:1993-09-07

    申请号:US668352

    申请日:1991-03-11

    申请人: William D. Emmons

    发明人: William D. Emmons

    IPC分类号: C08F20/28

    CPC分类号: C08F20/28

    摘要: There is described the preparation of esters of an acid having the structure CH.sub.2 .dbd.CHCO.sub.2 (CH.sub.2 CH.sub.2 CO.sub.2).sub.n H (AOnPA herein) and their use to form polymers, as reactive diluents and modifiers and as crosslinkers. In the above formula n has a value above 0.1. The polymers and the compositions are useful as coatings, binders and adhesives. The compositions are low in volatile components and toxicity.

    摘要翻译: 描述了具有CH 2 = CHCO 2(CH 2 CH 2 CO 2)n H(本文中为AOnPA)结构的酸的酯的制备及其用作形成聚合物,作为反应性稀释剂和改性剂以及作为交联剂的用途。 在上述公式中,n具有大于0.1的值。 聚合物和组合物可用作涂料,粘合剂和粘合剂。 组合物挥发性组分低,毒性低。

    In situ cyclopolymerized vinyl anhydride in polyepoxide
    16.
    发明授权
    In situ cyclopolymerized vinyl anhydride in polyepoxide 失效
    聚环氧化物中的原位环化聚乙烯基酐

    公开(公告)号:US4946875A

    公开(公告)日:1990-08-07

    申请号:US294711

    申请日:1989-01-09

    IPC分类号: C08G59/17 C08G59/18 C08L63/00

    摘要: A B stageable thermosettable composition containing at least one polyepoxide and at least one linear anhydride monomer capable of forming a cyclopolymer in situ and processes for the formation of the B stage intermediate and final thermoset having a high service temperature is provided. The composition is useful in a two stage process; first to form a storage stable, flowable thermoplastic B stage intermediate by the free radical initiated vinyl polymerization of the linear anhydride in the liquid composition to a cyclic polymer and secondly to react the cyclic polymer with the poly epoxide to form a crosslinked high service temperature theremoset useful in the preparation of laminates, such as printed circuit boards, adhesives, and encapsulants.

    B stageable high service temperature epoxy thermosets
    17.
    发明授权
    B stageable high service temperature epoxy thermosets 失效
    B可阶段高使用温度环氧热固性材料

    公开(公告)号:US4814398A

    公开(公告)日:1989-03-21

    申请号:US109687

    申请日:1987-12-28

    摘要: A B stageable thermosettable composition containing at least one polyepoxide and at least one linear anhydride monomer capable of forming a cyclopolymer in situ and processes for the formation of the B stage intermediate and final thermoset having a high service temperature is provided. The composition is useful in a two stage process; first to form a storage stable, flowable thermoplastic B stage intermediate by the free radical initiated vinyl polymerization of the linear anhydride in the liquid composition to a cyclic polymer and secondly to react the cyclic polymer with the poly epoxide to form a crosslinked high service temperature thermoset useful in the preparation of laminates, such as printed circuit boards, adhesives and encapsulants.

    摘要翻译: 提供了含有至少一种聚环氧化物和能够原位形成环状聚合物的至少一种线性酸酐单体的B可阶段热固性组合物,以及用于形成具有高使用温度的B阶段中间体和最终热固性材料的方法。 该组合物在两步法中是有用的; 首先通过在液体组合物中的线性酸酐的自由基引发的乙烯基聚合到环状聚合物形成储存稳定的可流动的热塑性B阶段中间体,其次使环状聚合物与聚环氧化物反应形成交联的高使用温度的热固性 可用于制备层压板,例如印刷电路板,粘合剂和密封剂。

    Acrylic polymer concrete compositions
    18.
    发明授权
    Acrylic polymer concrete compositions 失效
    丙烯酸聚合物混凝土组合物

    公开(公告)号:US4400413A

    公开(公告)日:1983-08-23

    申请号:US283091

    申请日:1981-07-16

    摘要: There are disclosed polymer concrete compositions of essentially anhydrous character comprising (1) an inert inorganic particulate material, such as sand, crushed stone or rock, and mixtures thereof, mixed with (2) a monomer blend of (a) dicyclopentenyloxyalkyl methacrylate or acrylate and (b) hydroxyalkyl methacrylate to form a paste or slurry suitable upon addition thereto of (3) a polymerization catalyst of (a) an organic peroxide and an aromatic amine accelerator, or (b) a polyvalent metal salt or complex and an organic hydroperoxide, or (c) mixtures of (a) and 0.0005% to 2% by weight, based on total amount of monomers, of a polyvalent metal salt or complex, or (d) mixtures of (a) and (b), to be used to form or to patch previously formed or laid, concrete floors and road pavements or as a coating for a variety of substrates such as metal and plastic sheet.

    摘要翻译: 公开了基本上无水性的聚合物混凝土组合物,其包含(1)惰性无机颗粒材料,例如砂,粉碎的石头或岩石及其混合物,与(2)单体混合物(a)甲基丙烯酸二环戊烯甲基氧基烷基酯或丙烯酸酯的单体共混物和 (b)甲基丙烯酸羟烷基酯以形成适于加入(3)聚合催化剂(a)有机过氧化物和芳族胺促进剂的聚合催化剂或(b)多价金属盐或络合物和有机氢过氧化物的浆料或浆料, 或(c)基于单体的总量,(a)和0.0005重量%至2重量%的多价金属盐或络合物的混合物,或(d)待使用的(a)和(b)的混合物 以形成或修补先前形成或铺设的混凝土地板和道路路面,或者作为用于各种基底例如金属和塑料片的涂层。

    Ambient hydrocurable coating compositions
    19.
    发明授权
    Ambient hydrocurable coating compositions 失效
    环境水溶性涂料组合物

    公开(公告)号:US4373008A

    公开(公告)日:1983-02-08

    申请号:US319752

    申请日:1981-11-09

    摘要: The present invention is concerned with, as a hydrocurable composition, a mixture of an oxazolidine-functional polymer and a compound of a monomeric or polymeric character having a plurality of acryloxy groups. The first-mentioned polymer contains a plurality of pendant groups containing 2,2,-dialkyl oxazolidine groups. The mixture of these two components can be stored under anhydrous conditions in a closed container without co-reaction so that a one-pot or one-package composition can be made up with many conventional ingredients of coating compositions other than aqueous components and stored without gelling until the time for application when the composition may be applied at ambient temperature and humidity whereupon reaction between the main two components mentioned above occurs in the film deposited and the film set up.

    摘要翻译: 作为氢可固化组合物,本发明涉及恶唑烷官能聚合物和具有多个丙烯酰氧基的单体或聚合物的化合物的混合物。 首先提到的聚合物含有多个含有2,2'-二烷基恶唑烷基团的侧基。 这两种组分的混合物可以在无水条件下在密闭的容器中储存而不进行共反应,使得一锅或一个包装组合物可用许多常规成分的除含水组分以外的涂料组合物制成,并且不凝胶化 直到在环境温度和湿度下施用组合物的时间为止,因此在沉积的膜和膜的膜中发生上述主要两种组分之间的反应。

    Autoxidizable compositions
    20.
    发明授权
    Autoxidizable compositions 失效
    可自动氧化成分

    公开(公告)号:US4311624A

    公开(公告)日:1982-01-19

    申请号:US165878

    申请日:1980-07-02

    摘要: Disclosed is an improved autoxidizable coating and/or impregnating composition containing (1) a reactive non-volatile diluent monomer system of a mixture of dicyclopentenyloxyalkyl esters of polymerizable ethylenically unsaturated carboxylic acids and methacryloxyalkyl esters of drying or semi-drying oil fatty acids (2) a film-forming component which contains autoxidizable functionality, (3) a polyvalent metal containing salt or complex that catalyzes the autoxidative curing of (1) and (2), and, optionally, (4) a volatile oxime stabilizer.

    摘要翻译: 公开了一种改进的可自动氧化涂层和/或浸渍组合物,其包含(1)可聚合烯属不饱和羧酸的二环戊烯基氧基烷基酯和干燥或半干性油脂肪酸的甲基丙烯酰氧基烷基酯的混合物的反应性非挥发性稀释剂单体体系(2) 含有可自动氧化功能的成膜组分,(3)催化(1)和(2)的自氧化固化的多价金属盐或络合物,和任选的(4)挥发性肟稳定剂。