公开(公告)号：US4299867A

公开(公告)日：1981-11-10

申请号：US116734

申请日：1980-01-30

申请人： William D. Emmons ,  Wayne E. Feely

发明人： William D. Emmons ,  Wayne E. Feely

IPC分类号： C08F20/00 ,  C08F20/26 ,  C08F265/04 ,  C08F290/00 ,  C08F291/00 ,  C08F299/00 ,  C09D4/06 ,  C09J4/06 ,  B05D3/02

CPC分类号： C09J4/06 ,  C08F265/04 ,  C08F291/00 ,  C09D4/06

摘要： The present invention is concerned with, as a hydrocurable composition, a mixture of an oxazolidine-functional polymer and a compound of a monomeric or polymeric character having a plurality of acryloxy groups. The first-mentioned polymer contains a plurality of pendant groups containing 2,2-dialkyl oxazolidine groups. The mixture of these two components can be stored under anhydrous conditions in a closed container without co-reaction so that a one-pot or one-package composition can be made up with many conventional ingredients of coating compositions other than aqueous components and stored without gelling until the time for application when the composition may be applied at ambient temperature and humidity whereupon reaction between the main two components mentioned above occurs in the film deposited and the film set up.

摘要翻译： 作为氢可固化组合物，本发明涉及恶唑烷官能聚合物和具有多个丙烯酰氧基的单体或聚合物的化合物的混合物。 首先提及的聚合物含有多个含有2,2-二烷基恶唑烷基的侧基。 这两种组分的混合物可以在无水条件下在密闭的容器中储存而不进行共反应，使得一锅或一个包装组合物可用许多常规成分的除含水组分以外的涂料组合物制成，并且不凝胶化 直到在环境温度和湿度下施用组合物的时间为止，因此在沉积的膜和膜的膜中发生上述主要两种组分之间的反应。

公开(公告)号：US4308356A

公开(公告)日：1981-12-29

申请号：US116693

申请日：1980-01-30

申请人： William D. Emmons ,  Wayne E. Feely

发明人： William D. Emmons ,  Wayne E. Feely

IPC分类号： C08G59/00 ,  C08F220/32 ,  C08G59/18 ,  C08G59/40 ,  C08G59/50 ,  C09D163/00 ,  C09J163/00 ,  C08G59/42

CPC分类号： C08G59/5046 ,  C08F220/32 ,  C08G59/18 ,  C08G59/50 ,  C09D163/00

摘要： Resin-forming polyepoxides are mixed with polyoxazolidinyl compounds or polymers containing pendant oxazolidinyl groups in which the carbon atom in the 2-position of the heterocyclic ring is substituted with saturated hydrocarbon groups, such as dialkyl, or with an alkylene group forming a saturated ring with the carbon atom in the 2-position of the oxazolidinyl ring to form, in the absence of water, a stable composition which can be stored in closed containers for months without undergoing gelation. When such compositions are spread into films and the films exposed to moisture at ambient temperature, e.g., to ambient air having a relative humidity of at least 20% and temperature of about 15.degree. to 25.degree. C., the polymer serves to react with and cure the polyepoxide.

摘要翻译： 将形成树脂的聚环氧化物与含有恶唑烷基基团的聚恶唑烷基化合物或含有杂环的2位上的碳原子被饱和烃基取代的侧链恶唑烷基的聚合物，例如二烷基，或与形成饱和环的亚烷基 在恶唑烷基环的2位上的碳原子在没有水的情况下形成稳定的组合物，其可以在密闭容器中储存几个月而不经历凝胶化。 当这些组合物分散在薄膜中并且膜在环境温度下暴露于水分时，例如相对湿度为至少20％和温度为约15至25℃的环境空气时，聚合物用于与 固化聚环氧化物。

公开(公告)号：US4376844A

公开(公告)日：1983-03-15

申请号：US340932

申请日：1982-01-20

申请人： William D. Emmons ,  Wayne E. Feely

发明人： William D. Emmons ,  Wayne E. Feely

IPC分类号： C08F220/32 ,  C08G59/50 ,  C09D163/00 ,  C08G59/42

CPC分类号： C08F220/32 ,  C08G59/50 ,  C08G59/5046 ,  C09D163/00

摘要： Resin-forming polyepoxides are mixed with polyoxazolidinyl compounds or polymers containing pendant oxazolidinyl groups in which the carbon atom in the 2-position of the heterocyclic ring is substituted with saturated hydrocarbon groups, such as dialkyl, or with an alkylene group forming a saturated ring with the carbon atom in the 2-position of the oxazolidinyl ring to form, in the absence of water, a stable composition which can be stored in closed containers for months without undergoing gelation. When such compositions are spread into films and the films exposed to moisture at ambient temperature, e.g., to ambient air having a relative humidity of at least 20% and temperature of about 15.degree. to 25.degree. C., the polymer serves to react with and cure the polyepoxide.

公开(公告)号：US4373008A

公开(公告)日：1983-02-08

申请号：US319752

申请日：1981-11-09

申请人： William D. Emmons ,  Wayne E. Feely

发明人： William D. Emmons ,  Wayne E. Feely

IPC分类号： C08F265/04 ,  C08F291/00 ,  C09D4/06 ,  C09J4/06 ,  B05D3/02

CPC分类号： C09J4/06 ,  C08F265/04 ,  C08F291/00 ,  C09D4/06 ,  Y10T428/31511 ,  Y10T428/31529 ,  Y10T428/31692 ,  Y10T428/31855

摘要： The present invention is concerned with, as a hydrocurable composition, a mixture of an oxazolidine-functional polymer and a compound of a monomeric or polymeric character having a plurality of acryloxy groups. The first-mentioned polymer contains a plurality of pendant groups containing 2,2,-dialkyl oxazolidine groups. The mixture of these two components can be stored under anhydrous conditions in a closed container without co-reaction so that a one-pot or one-package composition can be made up with many conventional ingredients of coating compositions other than aqueous components and stored without gelling until the time for application when the composition may be applied at ambient temperature and humidity whereupon reaction between the main two components mentioned above occurs in the film deposited and the film set up.

摘要翻译： 作为氢可固化组合物，本发明涉及恶唑烷官能聚合物和具有多个丙烯酰氧基的单体或聚合物的化合物的混合物。 首先提到的聚合物含有多个含有2,2'-二烷基恶唑烷基团的侧基。 这两种组分的混合物可以在无水条件下在密闭的容器中储存而不进行共反应，使得一锅或一个包装组合物可用许多常规成分的除含水组分以外的涂料组合物制成，并且不凝胶化 直到在环境温度和湿度下施用组合物的时间为止，因此在沉积的膜和膜的膜中发生上述主要两种组分之间的反应。

公开(公告)号：US4251597A

公开(公告)日：1981-02-17

申请号：US965673

申请日：1978-12-01

申请人： William D. Emmons ,  Wayne E. Feely

发明人： William D. Emmons ,  Wayne E. Feely

IPC分类号： C08F291/14 ,  C09D4/00 ,  C09D133/14 ,  C08L33/10 ,  B32B27/06 ,  C08L79/08

CPC分类号： C09D4/00 ,  C08F291/14 ,  C09D133/14 ,  Y10T428/31855 ,  Y10T428/31906 ,  Y10T428/31928

摘要： Addition polymers containing a plurality of terminal and/or pendant amine groups in which the nitrogen atom of at least some of such groups is of primary or secondary character, or aldimine or ketimine groups form the main film-forming component in compositions for coating and the like purposes, which also contain a polyfunctional acrylic monomer, such as ethylene glycol diacrylate, with or without monoethylenically unsaturated acrylic ester. Such compositions provide durable films having excellent mechanical and resistance properties even on ambient curing though baking may be used to accelerate the cure. A method of use is also claimed in which the components are mixed in suitable vehicles, e.g. dispersant or solvent media, optionally with fillers and/or pigments, as desired, and after application of the composition, such as for coating, it is cured by exposure to ambient conditions, naturally occurring or controlled, or it is cured at elevated temperatures or by applying a plurality of curing conditions in succession, e.g. first to ambient conditions and subsequently to elevated temperatures in one or more stages of baking.

摘要翻译： 含有多个末端和/或侧胺基团的加成聚合物，其中至少一些这样的基团的氮原子具有伯或仲的特征，或醛亚胺或酮亚胺基形成涂料组合物中的主要成膜组分， 其还含有多官能丙烯酸单体，例如具有或不具有单烯属不饱和丙烯酸酯的乙二醇二丙烯酸酯。 这样的组合物即使在环境固化时也提供具有优异的机械和电阻性能的耐用膜，尽管可以使用烘烤来加速固化。 还要求一种使用方法，其中组分在合适的载体中混合，例如。 分散剂或溶剂介质，任选地含有填料和/或颜料，如果需要，并且在施用组合物之后，例如涂覆，它通过暴露于天然存在或控制的环境条件下固化，或者在升高的温度下固化 通过连续施加多个固化条件，例如， 首先到环境条件，随后在一个或多个烘烤阶段升高温度。

公开(公告)号：US4331793A

公开(公告)日：1982-05-25

申请号：US245297

申请日：1981-03-19

申请人： William D. Emmons ,  Wayne E. Feely

发明人： William D. Emmons ,  Wayne E. Feely

IPC分类号： C08F220/32 ,  C08G59/50 ,  C09D163/00 ,  C08F24/00 ,  C08F26/06

CPC分类号： C09D163/00 ,  C08F220/32 ,  C08G59/50 ,  C08G59/5046

摘要： Resin-forming polyepoxides are mixed with polyoxazolidinyl compounds or polymers containing pendant oxazolidinyl groups in which the carbon atom in the 2-position of the heterocyclic ring is substituted with saturated hydrocarbon groups, such as dialkyl, or with an alkylene group forming a saturated ring with the carbon atom in the 2-position of the oxazolidinyl ring to form, in the absence of water, a stable composition which can be stored in closed containers for months without undergoing gelation. When such compositions are spread into films and the films exposed to moisture at ambient temperature, e.g., to ambient air having a relative humidity of at least 20% and temperature of about 15.degree. to 25.degree. C., the polymer serves to react with and cure the polyepoxide.

摘要翻译： 将形成树脂的聚环氧化物与含有恶唑烷基基团的聚恶唑烷基化合物或含有杂环的2位上的碳原子被饱和烃基取代的侧链恶唑烷基的聚合物，例如二烷基，或与形成饱和环的亚烷基 在恶唑烷基环的2位上的碳原子在没有水的情况下形成稳定的组合物，其可以在密闭容器中储存几个月而不经历凝胶化。 当这些组合物分散在薄膜中并且膜在环境温度下暴露于水分时，例如相对湿度为至少20％和温度为约15至25℃的环境空气时，聚合物用于与 固化聚环氧化物。

公开(公告)号：US4303563A

公开(公告)日：1981-12-01

申请号：US99673

申请日：1979-12-03

申请人： William D. Emmons ,  Wayne E. Feely

发明人： William D. Emmons ,  Wayne E. Feely

IPC分类号： C08F291/14 ,  C09D133/14 ,  C08F18/24 ,  C08F26/08

CPC分类号： C08F291/14 ,  C09D133/14

摘要： Addition polymers containing a plurality of terminal and/or pendant amine groups in which the nitrogen atom of at least some of such groups is of primary or secondary character, or aldimine or ketimine groups form the main film-forming component in compositions for coating and the like purposes, which also contain a polyfunctional acrylic monomer, such as ethylene glycol diacrylate, with or without monoethylenically unsaturated acrylic ester. Such compositions provide durable films having excellent mechanical and resistance properties even on ambient curing though baking may be used to accelerate the cure. A method of use is also disclosed in which the components are mixed in suitable vehicles, e.g. dispersant or solvent media, optionally with fillers and/or pigments, as desired, and after application of the composition, such as for coating, it is cured by exposure to ambient conditions, naturally occurring or controlled, or it is cured at elevated temperatures or by applying a plurality of curing conditions in succession, e.g. first to ambient conditions and subsequently to elevated temperatures in one or more stages of baking.

摘要翻译： 含有多个末端和/或侧胺基团的加成聚合物，其中至少一些这样的基团的氮原子具有伯或仲的特征，或醛亚胺或酮亚胺基形成涂料组合物中的主要成膜组分， 其还含有多官能丙烯酸单体，例如具有或不具有单烯属不饱和丙烯酸酯的乙二醇二丙烯酸酯。 这样的组合物即使在环境固化时也提供具有优异的机械和电阻性能的耐用膜，尽管可以使用烘烤来加速固化。 还公开了一种使用方法，其中组分在合适的载体中混合，例如 分散剂或溶剂介质，任选地含有填料和/或颜料，如果需要，并且在施用组合物之后，例如涂覆，它通过暴露于天然存在或控制的环境条件下固化，或者在升高的温度下固化 通过连续施加多个固化条件，例如， 首先到环境条件，随后在一个或多个烘烤阶段升高温度。

公开(公告)号：US5204225A

公开(公告)日：1993-04-20

申请号：US690195

申请日：1991-04-23

申请人： Wayne E. Feely

发明人： Wayne E. Feely

IPC分类号： G03F7/029 ,  G03F7/038

CPC分类号： G03F7/038 ,  G03F7/0295

摘要： Selected photosensitive compounds activated by deep ultraviolet radiation or x-rays and capable of being employed at very low concentrations in photosensitive compositions are provided for producing thermally stable and aqueously developable, negative images on surfaces. The selected photosensitive compounds are halogenated organic compounds, including 1,1-bis[p-chlorophenyl]-2,2,2-trichloroethane, which generate an inorganic halogen acid upon exposure to deep UV or other short wavelength radiations. They may be used at concentrations of less than 5 weight percent of the total solids content of the photosensitive composition to produce aqueously developable negative images using deep UV exposure.

摘要翻译： 提供了通过深紫外线辐射或X射线激活且能够以非常低的浓度在感光组合物中使用的所选择的光敏化合物用于在表面上产生热稳定和可显影的负像。 选择的光敏化合物是卤化有机化合物，包括1,1-双[对氯苯基] -2,2,2-三氯乙烷，其在暴露于深紫外或其它短波长辐射时产生无机卤酸。 它们可以以小于光敏组合物的总固体含量的5重量％的浓度使用，以使用深紫外线曝光产生可显影的负像。

公开(公告)号：US5391465A

公开(公告)日：1995-02-21

申请号：US511890

申请日：1990-04-19

申请人： Wayne E. Feely

发明人： Wayne E. Feely

IPC分类号： G03F7/004 ,  G03F7/038 ,  G03F7/26 ,  G03F7/38 ,  G03F7/30 ,  G03F7/40

CPC分类号： G03F7/038 ,  Y10S430/121 ,  Y10S430/123 ,  Y10S430/126 ,  Y10S430/127

摘要： A method is provided for using selected photoactive compounds in acid hardening photoresists to produce thermally stable, high resolution images with near ultraviolet exposing radiation. These photoactive compounds can be used as photosensitizers for halogen-containing photoacid generators which by themselves do not otherwise generate sufficient acid upon exposure to near ultraviolet radiation to catalyze the crosslinking of acid hardening resins. The photoactive compounds are selected from the group consisting of phenothiazine, derivatives of phenothiazine, and phenoxazine.

摘要翻译： 提供了一种在酸硬化光致抗蚀剂中使用选择的光活性化合物以产生具有近紫外曝光辐射的热稳定的高分辨率图像的方法。 这些光敏化合物可用作含卤素的光酸产生剂的光敏剂，其本身在暴露于近紫外辐射下本身不产生足够的酸以催化酸硬化树脂的交联。 光活性化合物选自吩噻嗪，吩噻嗪衍生物和吩恶嗪。

公开(公告)号：US5344748A

公开(公告)日：1994-09-06

申请号：US524683

申请日：1990-05-16

申请人： Wayne E. Feely

发明人： Wayne E. Feely

IPC分类号： H01L21/30 ,  B29C35/08 ,  B29L31/34 ,  C23F1/00 ,  G03F7/00 ,  G03F7/029 ,  G03F7/26 ,  H01L21/027 ,  G03C5/00

CPC分类号： G03F7/00 ,  G03F7/0295

摘要： Thermally stable microplastic structures and methods for their manufacture are provided. The microplastic structures are prepared from crosslinkable photosensitive compositions using a specially designed radiation attenuating photomask which permits preselection of the size, length, width and thickness of the desired structure. The microplastic structures are stable at temperatures in excess of 200.degree. C. and can be used as components in miniature electrical, mechanical, chemical and optical devices, such as smart sensors integral to a silicon chip device.

摘要翻译： 提供了热稳定的微塑性结构及其制造方法。 使用专门设计的辐射衰减光掩模可交联的光敏组合物制备微塑性结构，其允许预选所需结构的尺寸，长度，宽度和厚度。 微型塑料结构在超过200℃的温度下是稳定的，并且可以用作微型电气，机械，化学和光学器件中的组件，例如与硅芯片器件集成的智能传感器。