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公开(公告)号：US20170233362A1
公开(公告)日：2017-08-17
申请号：US15502870
申请日：2015-08-13
Applicant: SHELL OIL COMPANY
IPC: C07D307/50 , C13K13/00
CPC classification number: C07D307/50 , C07D307/48 , C13K13/002
Abstract: Methods and processes for the production of valuable organic products and alcohols from biomass using a single-step dehydration extraction process having numerous advantages over prior production methods are described.
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公开(公告)号：US20170233360A1
公开(公告)日：2017-08-17
申请号：US15502808
申请日：2015-08-13
Applicant: SHELL OIL COMPANY
IPC: C07D307/50
CPC classification number: C07D307/50 , C07D307/48
Abstract: Methods and processes for the production of valuable organic products and alcohols from biomass material using a closed-loop process having numerous advantages over prior production methods are described. In the process, the biomass is subjected to acid-catalyzed digestion, followed by a separation of the digestion product stream into a solid product stream and a liquid product stream, the liquid product stream thereafter undergoing acid-catalyzed dehydration in the presence of an organic solvent, and thereafter separating the organic products in the organic layer from the aqueous layer. During the process, aqueous and organic fluid streams are fed back into various portions of the production process to increase the concentration of active portions and maximize product recovery.
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公开(公告)号：US20220298089A1
公开(公告)日：2022-09-22
申请号：US17638316
申请日：2020-09-25
Applicant: SHELL OIL COMPANY
Inventor： Jean Paul Andre Marie Joseph Ghislain LANGE , Pieter HUIZENGA , Evert VAN DER HEIDE , Thimo Daniel Jozef TE MOLDER
IPC: C07C29/60
Abstract: A process for preparing glycols from a lignocellulosic solid biomass involves contacting the biomass with an organic solvent comprising a low boiling point alcohol and a pre-treatment acid at a temperature in a range from 80 to 220° C. and a pressure in a range from 1 to 50 bara. The resulting mixture, having less than wt. % water, is separated into a pre-treated solid residue comprising cellulose and a liquid stream comprising dissolved lignin. The pre-treated solid residue is subjected to a hydrogenolysis reaction. generating a glycols stream, a lights stream, comprising a first portion of organic solvent, and a heavies stream. At least part of the liquid stream is separated to produce a second portion of organic solvent and a lignin stream. At least part of the first and second portions of organic solvent is recycled to the contacting step.
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公开(公告)号：US20200270190A1
公开(公告)日：2020-08-27
申请号：US16062158
申请日：2016-12-15
Applicant: SHELL OIL COMPANY
Inventor： Dionysius Jacobus Maria DE VLIEGER , Jean Paul Andre Marie Joseph Ghislain LANGE , Smita EDULJI , Hendrik Albertus COLIJN
IPC: C07C29/141 , B01J23/46 , B01J23/28 , B01J23/30
Abstract: A process for the hydrogenation or hydrogenolysis of an oxygenate is disclosed. The process takes place in a reactor in the presence of a catalyst, hydrogen and liquid water and the catalyst comprises one or more elements from Groups 8 to 11 of the periodic table dispersed on a hydrothermally stable oxide support.
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公开(公告)号：US20200010400A1
公开(公告)日：2020-01-09
申请号：US16470462
申请日：2017-12-18
Applicant: SHELL OIL COMPANY
Abstract: The invention relates to an integrated process for the production of ethylene and vinyl acetate (VAM), comprising contacting in a first reaction zone a gas stream comprising ethane and optionally ethylene with an oxygen-containing gas stream in the presence of a oxydehydrogenation catalyst under oxidative dehydrogenation conditions to produce a first product stream comprising ethane, ethylene, acetic acid and water, and optionally other compounds, separating said first product stream in a vapor permeation unit into a second stream comprising water and a third stream comprising ethane, ethylene, acetic acid, and optionally other gaseous compounds, contacting in a second reaction zone all or at least a portion of said third stream with a stream comprising concentrated acetic acid and with an oxygen-containing gas stream in the presence of a VAM catalyst, to produce a fourth product stream comprising vinyl acetate, acetic acid, ethane, ethylene, water, carbon dioxide, and optionally other compounds, separating said fourth product stream in a vinyl acetate separation zone into a fifth stream comprising vinylacetate, acetic acid, water and optionally other condensable compounds, and a sixth stream comprising ethylene, ethane, carbon dioxide and optionally other gaseous compounds, and recovering vinyl acetate from said fifth stream. The invention further relates to a reaction system for carrying out the process.
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Patent Agency Ranking
公开(公告)号：US20190241744A1
公开(公告)日：2019-08-08
申请号：US16341952
申请日：2017-10-13
Applicant: SHELL OIL COMPANY
CPC classification number: C08L95/00 , C08H8/00 , C08J5/045 , C08J2395/00 , C08J2497/02 , C08L1/02 , C08L2205/16 , C08L97/02
Abstract: A reinforced composite material comprises a blend of a thermoplastic matrix and cellulosic fibers, wherein the thermo-plastic matrix comprises a tarry residue fraction from a lignocellulosic biomass liquefaction process. A process for the manufacture of the reinforced composite material comprises subjecting a lignocellulosic biomass to liquefaction in the presence of a liquefaction solvent to form a liquefaction product and a tarry residue; separating the tarry residue from the liquefaction product; and blending the tarry residue with cellulosic fibers to form a recyclable reinforced thermoplastic composite material.
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公开(公告)号：US20190047929A1
公开(公告)日：2019-02-14
申请号：US16075935
申请日：2017-02-06
Applicant: SHELL OIL COMPANY
Inventor： Dionysius Jacobus Maria DE VLIEGER , Pieter HUIZENGA , Evert VAN DER HEIDE , Smita EDULJI , Jean Paul Andre Marie Joseph Ghislain LANGE
IPC: C07C29/141 , C07C45/60
Abstract: The invention provides a process for the selective hydrogenation of glycolaldehyde in a process stream comprising glycolaldehyde and one or more monosaccharide in a solvent, said process comprising contacting the process stream with hydrogen in the presence of a hydrogenation catalyst composition at a temperature of no more than 150° C. and for a residence time of no more than 90 minutes.
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公开(公告)号：US20180345256A1
公开(公告)日：2018-12-06
申请号：US15777096
申请日：2016-11-17
Applicant: SHELL OIL COMPANY
Inventor： Reinhard GEYER , Henri PREISING , Dionysius Jacobus Maria DE VLIEGER , Smita EDULJI , Evert VAN DER HEIDE , Jean Paul Andre Marie Joseph Ghislain LANGE
IPC: B01J27/188 , B01J25/02 , B01J35/00 , C07C29/141 , C07C31/20
CPC classification number: B01J27/188 , B01J21/063 , B01J21/066 , B01J21/08 , B01J23/30 , B01J23/40 , B01J23/462 , B01J23/70 , B01J25/02 , B01J35/0006 , B01J2231/643 , B01J2523/69 , C07C29/132 , C07C29/141 , C07C31/202 , Y02P20/52
Abstract: The invention provides a catalyst system comprising: a) one or more Group 1 metal phosphotungstate-containing species; and b) one or more catalytic species suitable for hydrogenation; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor in the presence of a solvent and said catalyst system.
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公开(公告)号：US20170152237A1
公开(公告)日：2017-06-01
申请号：US15129856
申请日：2015-03-26
Applicant: SHELL OIL COMPANY
IPC: C07D307/36
CPC classification number: C07D307/36
Abstract: The present invention provides a process for the treatment of a liquid first furan stream comprising furan and carbon monoxide, said process comprising the steps of: i) contacting said first furan stream with a CO-lean first gaseous stream; and ii) stripping at least a portion of the carbon monoxide in the first furan stream into the first gaseous stream to produce a second furan stream comprising less carbon monoxide than the first furan stream and a CO-enriched second gaseous stream.
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公开(公告)号：US20170137395A1
公开(公告)日：2017-05-18
申请号：US15129863
申请日：2015-03-26
Applicant: SHELL OIL COMPANY
IPC: C07D307/36
CPC classification number: C07D307/36
Abstract: The present invention provides a process for the production of furan, said process comprising the steps of: i) contacting furfural with a decarbonylation catalyst in a decarbonylation reactor to produce a gaseous decarbonylation reaction product stream comprising furan and carbon monoxide; ii) contacting said gaseous decarbonylation reaction product stream with a solvent stream comprising furfural; iii) absorbing at least a portion of the furan present in the gaseous decarbonylation reaction product stream into the solvent stream to provide a furan-containing solvent stream and a gaseous stream comprising carbon monoxide; iv) separating the furan from the furan containing solvent stream by distillation to provide a first furan stream; and v) using at least a portion of the remaining solvent stream comprising furfural as at least a portion of the furfural provided to the decarbonylation reactor.
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