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公开(公告)号：US20120184783A1
公开(公告)日：2012-07-19
申请号：US13431308
申请日：2012-03-27
IPC分类号： C07C29/86
CPC分类号： C07C29/86 , B01J31/2409 , B01J2531/0258 , B01J2531/821 , C07C29/149 , C07C29/80 , Y02P20/52 , C07C31/202 , C07C31/205 , C07C31/207
摘要： Disclosed is a process for the purification of a mixed diol stream. The mixed diol stream comprising two-, three-, and four-carbon diols is separated into component diols by extraction with a hydrophobic solvent mixture. The diols recovered in the extractant may be removed from the extractant stream by back extraction with water or by distillation with an azeotrope-forming agent present, preferably an azeotroping agent already present in the extractant mixture.
摘要翻译： 公开了一种纯化混合二醇流的方法。 包含二，三和四碳二醇的混合二醇料流通过用疏水溶剂混合物萃取分离成组分二醇。 在萃取剂中回收的二醇可以通过用水反萃取或用存在的共沸物形成剂，优选已经存在于萃取剂混合物中的共沸剂进行蒸馏，从萃取剂流中除去。
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公开(公告)号：US07736403B2
公开(公告)日：2010-06-15
申请号：US12360125
申请日：2009-01-27
IPC分类号： C01B3/36 , C10J3/46 , C10J3/54 , B01J7/00 , H01M8/06 , F02B43/00 , F02G3/00 , F02C6/18 , B01D47/06
CPC分类号： C10J3/00 , C01B3/34 , C01B2203/0233 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/068 , C01B2203/0877 , C01B2203/0883 , C01B2203/84 , C10J3/723 , C10J2300/093 , C10J2300/0959 , C10J2300/0969 , C10J2300/0973 , C10J2300/1618 , C10J2300/165 , C10J2300/1659 , C10J2300/1665 , C10J2300/1668 , C10J2300/1671 , C10K1/002 , C10K1/004 , C10K1/005 , C10K1/007 , C10K1/04 , C10K1/101 , C10K1/12 , C10K1/122 , C10K1/143 , C10K1/16 , C10K1/20 , C10K1/32 , C10K3/04 , C10K3/06 , Y02E20/14 , Y02E20/16 , Y02E20/18 , Y02E50/11 , Y02E50/32 , Y02P20/129
摘要： Disclosed is a process for humidifying syngas to achieve a water to carbon monoxide molar ratio in the product syngas within a desired range and in which the molar ratio which can be varied over time in response to changes in downstream syngas requirements. The raw syngas is produced by reacting a carbonaceous material with oxygen, water, or carbon dioxide and can be combined with a diluent to produce a diluted syngas stream which can be cooled and contacted with liquid water to give a humidified syngas. The H2O:CO molar ratio of the humidified syngas may be adjusted in response to time-varying downstream syngas requirements by changing the amount and/or temperature of the diluent that is combined with the raw syngas stream, by adjusting quench and heat exchange conditions, or a combination thereof. The application of the process to the coproduction of chemicals and power are also disclosed.
摘要翻译： 公开了一种用于加湿合成气以在产物合成气中达到所需范围内的水与一氧化碳摩尔比的方法，其中响应于下游合成气需求的变化可随时间变化的摩尔比。 原料合成气通过使碳质材料与氧气，水或二氧化碳反应而生成，并且可与稀释剂组合以产生稀释的合成气流，其可冷却并与液态水接触以产生加湿的合成气。 通过改变与原料合成气流合并的稀释剂的量和/或温度，可以通过调节骤冷和热交换条件来调节加湿合成气的H 2 O:CO摩尔比，以响应随时间变化的下游合成气需求， 或其组合。 还公开了该方法在化学品和电力的共同生产中的应用。
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公开(公告)号：US07538060B2
公开(公告)日：2009-05-26
申请号：US11674831
申请日：2007-02-14
申请人： Scott Donald Barnicki , Bruce LeRoy Gustafson , Zhufang Liu , Steven Thomas Perri , Paul Randolph Worsham
发明人： Scott Donald Barnicki , Bruce LeRoy Gustafson , Zhufang Liu , Steven Thomas Perri , Paul Randolph Worsham
IPC分类号： B01J35/00 , B01J37/00 , C07C29/132 , C07C29/149
CPC分类号： C07C29/149 , B01J23/868 , B01J23/8993 , B01J37/0201 , B01J37/0205 , B01J37/03 , C07C29/157 , C07C2601/14 , Y02P20/52 , C07C31/202 , C07C31/276 , C07C31/04
摘要： Disclosed are catalysts comprising copper chromite, palladium and lanthanum having hydrogenation activity. The combination of copper chromite with palladium and lanthanum enhances catalyst activity more than the presence of either palladium alone or palladium in combination with alkali or alkaline earth metals. The catalysts are useful for the preparation of methanol from carbon monoxide and hydrogen and for the hydrogenation of carbonyl compounds such as, for example, aldehydes, ketones, and esters, to their corresponding alcohols. The catalysts may be used for the preparation of cyclohexanedimethanols from dialkyl cyclohexanedicarboxylates or of ethylene glycol from alkyl glycolates.
摘要翻译： 公开了包含具有氢化活性的亚铬酸铜，钯和镧的催化剂。 亚铬酸铜与钯和镧的组合比单独的钯或钯与碱金属或碱土金属组合的存在提高了催化剂活性。 催化剂可用于从一氧化碳和氢气制备甲醇，并将羰基化合物（例如醛，酮和酯）氢化成其相应的醇。 催化剂可用于从环己烷二羧酸二烷基酯或乙二醇由烷基乙醇酸制备环己烷二甲醇。
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14.发明授权公开(公告)号：US06353121B1
公开(公告)日：2002-03-05
申请号：US09791055
申请日：2001-02-22
IPC分类号： C07D30726
CPC分类号： C07D307/28
摘要： Disclosed is a process for separating 2,5-dihydrofuran (2,5-DHF) from aqueous solution of 2,5-DHF by extractive distillation using certain organic liquids as the extraction agent.
摘要翻译： 公开了一种通过使用某些有机液体作为萃取剂的萃取蒸馏从2,5-DHF水溶液中分离2,5-二氢呋喃（2,5-DHF）的方法。
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15.发明授权Process for the removal of carbon dioxide from 3,4-epoxy-1-butene process recycle streams 失效从3,4-环氧-1-丁烯工艺回收物流中除去二氧化碳的方法公开(公告)号：US06270739B1
公开(公告)日：2001-08-07
申请号：US09596246
申请日：2000-06-16
申请人： Scott Donald Barnicki , John Robert Monnier , Jerome Leonard Stavinoha, Jr. , Robert Sterling Kline , Gary Wayne Hartley
发明人： Scott Donald Barnicki , John Robert Monnier , Jerome Leonard Stavinoha, Jr. , Robert Sterling Kline , Gary Wayne Hartley
IPC分类号： C01B3120
CPC分类号： C07D301/32
摘要： Disclosed is a process for the efficient removal of carbon dioxide from a gas recycle system generated in an epoxidation process wherein 1,3-butadiene is selectively oxidized to 3,4-epoxy-1-butene. Carbon dioxide at low partial pressure is absorbed into an alkanolamine solution from a low pressure recycle gas stream containing high levels of oxygen. Also disclosed is a means for reclaiming the alkanolamine from a solution of a carbon dioxide-alkanolamine salt or adduct formed in the carbon dioxide removal process.
摘要翻译： 公开了一种从在环氧化方法中产生的气体循环系统有效地除去二氧化碳的方法，其中1,3-丁二烯被选择性氧化成3,4-环氧-1-丁烯。 低分压下的二氧化碳由含有高氧气的低压循环气流吸收到链烷醇胺溶液中。 还公开了一种用于从二氧化碳去除方法中形成的二氧化碳 - 烷醇胺盐或加合物的溶液回收链烷醇胺的方法。
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公开(公告)号：US5821384A
公开(公告)日：1998-10-13
申请号：US826451
申请日：1997-03-27
申请人： Joseph Robert Zoeller , Donald Wayne Lane , Eleanor Hawkins Cwirko , Dewey Wayne Fuller, Jr. , Scott Donald Barnicki
发明人： Joseph Robert Zoeller , Donald Wayne Lane , Eleanor Hawkins Cwirko , Dewey Wayne Fuller, Jr. , Scott Donald Barnicki
CPC分类号： C07C67/00 , Y02P20/127
摘要： Disclosed is a process for making vinyl carboxylate esters such as vinyl acetate and vinyl propionate, by a reactive distillation process comprising a reaction zone wherein a vinyl carboxylate ester is formed from a carbonyl compound selected from aliphatic aldehydes and ketones and an anhydride of an aliphatic carboxylic acid and a distillation zone from which the vinyl carboxylate ester is recovered and substantially separated from other compounds contained within the column. The process requires significantly less equipment than known, analogous processes and thus the cost of constructing a plant for the operation of the present process is substantially reduced.
摘要翻译： 公开了一种通过反应蒸馏方法制备乙烯基羧酸酯如乙酸乙烯酯和丙酸乙烯酯的方法，该方法包括反应区，其中乙烯基羧酸酯由选自脂族醛和酮的羰基化合物和脂族羧酸的酐形成 酸和蒸馏区，从其中回收羧酸乙烯酯，并与塔内的其它化合物基本上分离。 该方法需要比已知的类似方法少得多的设备，因此大大减少了用于本方法操作的构建设备的成本。
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17.发明授权公开(公告)号：US09040748B2
公开(公告)日：2015-05-26
申请号：US13491954
申请日：2012-06-08
申请人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
发明人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
IPC分类号： C07C51/12 , C07C27/04 , C07C29/149
CPC分类号： C07C51/12 , C07C29/149 , C07C59/06 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of aqueous formaldehyde. The water in the hydrocarboxylation zone is reduced via reaction with the ester bonds in a recycle stream comprising glycolic acid oligomers and/or methyl glycolate oligomers.
摘要翻译： 公开了通过甲醛水解羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 在包含乙醇酸低聚物和/或乙醇酸甲酯低聚物的再循环料流中，通过与酯键的反应来还原加氢羧化区中的水。
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18.发明授权Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst 有权在丙酸和均相催化剂存在下，将二丙酸亚丙基酯加氢羧化公开(公告)号：US08927766B2
公开(公告)日：2015-01-06
申请号：US13431402
申请日：2012-03-27
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C67/08 , C07C67/36 , C07C59/06 , C07C69/24 , C07C69/675 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a homogeneous acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the propionic acid is readily removed from the glycolic acid and the propionic acid is recycled.
摘要翻译： 公开了一种在均相酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。 均匀的酸催化剂容易从加氢羧化反应流出物中分离并再循环，丙酸容易从乙醇酸中除去，丙酸被再循环。
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19.发明授权Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst 有权在丙酸和非均相催化剂存在下，二丙酸亚丙基酯的加氢羧化作用公开(公告)号：US08703999B2
公开(公告)日：2014-04-22
申请号：US13431386
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
IPC分类号： C07C51/42
CPC分类号： C07C51/09 , C07C67/00 , C07C67/36 , C07C59/06 , C07C53/122 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a solid acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the propionic acid stream is readily removed from the glycolic acid and the propionic acid is recycled.
摘要翻译： 公开了一种在固体酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的乙醇酸分离，其中丙酸流容易从乙醇酸中除去，丙酸被再循环。
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20.发明申请公开(公告)号：US20130261333A1
公开(公告)日：2013-10-03
申请号：US13431358
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
IPC分类号： C07C51/12
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C51/48 , C07C51/493 , C07C67/08 , C07C67/36 , C07C67/58 , Y02P20/52 , C07C59/06 , C07C31/202 , C07C69/675 , C07C69/67
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a solid acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the glycolic acid stream is readily removed from the carboxylic acid and the carboxylic acid is recycled.
摘要翻译： 公开了一种在固体酸催化剂和羧酸存在下通过甲醛羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的乙醇酸分离，其中乙醇酸流容易地从羧酸中除去并且羧酸被再循环。
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