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    Self-etching dental materials based on (METH) acrylamide phosphates
    11.
    发明授权
    Self-etching dental materials based on (METH) acrylamide phosphates 有权
    基于（METH）丙烯酰胺磷酸盐的自蚀牙科材料

    公开(公告)号：US07622538B2

    公开(公告)日：2009-11-24

    申请号：US11211938

    申请日：2005-08-25

    申请人： Norbert Moszner ,  Iris Lamparth ,  Frank Zeuner ,  Ulrich Salz ,  Angela Mucke ,  Jorg Zimmermann ,  Jorg Angermann ,  Volker M. Rheinberger

    发明人： Norbert Moszner ,  Iris Lamparth ,  Frank Zeuner ,  Ulrich Salz ,  Angela Mucke ,  Jorg Zimmermann ,  Jorg Angermann ,  Volker M. Rheinberger

    IPC分类号： C08F20/58 ,  C08F20/60

    CPC分类号： A61K6/0017 ,  A61K6/0023 ,  A61K6/0029 ,  A61K6/083 ,  A61K6/09 ,  C08L33/26 ,  C08L33/04 ,  C08L75/04

    摘要： Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-10 aralkyl or a bicylic C4-C12 radial; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p ≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.

    摘要翻译： 可聚合牙科材料，其特征在于其含有至少一种下列通式（I）的（甲基）丙烯酰胺磷酸酯：其中R1是H或CH3; R2是H或C1-C4烷基或与其键合的氮原子一起形成一个或多个属于R3或R3'杂原子的原子; R 3，R 3'彼此独立地为具有m + n或p + n价的直链或支链脂族C 1 -C 50基团，价数为m + n或p + n的芳族C 6 -C 18基团或 脂环族，芳脂族或杂环C 3 -C 18基，其价态为m + n或p + n，其中基团或基团的碳链可被O，S，CONR 4，OCONH中断，或与一个或多个原子一起形成 属于R2和氮原子，R 2与杂环结合，如果p = 0，则R3'为H，R4为H，C1-C10烷基，C6-C12芳基，C6-10芳烷基或双 C4-C12径向; 如果p = 0，则n为1,2,3或4，如果p为0，则为1或2; m为1,2,3或4; p是0，1，2，3或4; x是0或S.

    Dental materials based on multicyclic allyl sulphides
    12.
    发明授权
    Dental materials based on multicyclic allyl sulphides 有权
    基于多环烯丙基硫化物的牙科材料

    公开(公告)号：US07501457B2

    公开(公告)日：2009-03-10

    申请号：US11482164

    申请日：2006-07-07

    申请人： Jörg Angermann ,  Peter Burtscher ,  Urs Karl Fischer ,  Norbert Moszner ,  Volker M. Rheinberger

    发明人： Jörg Angermann ,  Peter Burtscher ,  Urs Karl Fischer ,  Norbert Moszner ,  Volker M. Rheinberger

    IPC分类号： A61K6/083 ,  C08F28/06

    CPC分类号： A61K6/083 ,  A61K6/0017 ,  A61K6/0023 ,  C08L33/00

    摘要： Dental materials and associated methods are described based on multicyclic allyl sulphides with general Formula (I): in which R1 is H or a C1-C10 alkyl radical; R2 is H or a C1-C10 alkyl radical; R3 is absent or is a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C6-C12 radical, a C6-C14 arylene or C7-C20 alkylene arylene radical; R4 is an n-times substituted aliphatic C2 to C20 hydrocarbon radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, an aromatic C6-C14 radical, an aliphatic-aromatic C7-C20 radical or a heterocyclic radical which can contain 4 to 20 carbon atoms and 1 to 6 heteroatoms which are selected from N, O, P and/or S atoms, or which is formed exclusively by these heteroatoms; R5 is absent or is a C1-C10 alkylene radical; X is absent or is O, S, —O—CO— or —O—CO—NH—; Y is absent or is O, S, —O—CO— or —O—CO—NH—; m is 0 or 1 and n is an integer from 3 to 6.

    摘要翻译： 基于具有通式（I）的多环烯丙基硫化物描述牙科材料和相关方法：其中R1是H或C1-C10烷基; R2是H或C1-C10烷基; R3不存在或是可被O或S间隔的C 1 -C 20亚烷基，脂环族C 4 -C 12基，双环C 6 -C 12基，C 6 -C 14亚芳基或C 7 -C 20亚烷基亚芳基; R4是可被O或S间隔的n次取代的脂族C 2 -C 20烃基，脂环族C 4 -C 12基团，芳族C 6 -C 14基团，脂族 - 芳族C 7 -C 20基团或杂环基团，其可以 含有4至20个碳原子和1至6个选自N，O，P和/或S原子的杂原子，或仅由这些杂原子形成的杂原子; R5不存在或是C1-C10亚烷基; X不存在或为O，S，-O-CO-或-O-CO-NH-; Y不存在或为O，S，-O-CO-或-O-CO-NH-; m为0或1，n为3至6的整数。

    Dental materials based on multicyclic allyl sulphides
    13.
    发明申请
    Dental materials based on multicyclic allyl sulphides 有权
    基于多环烯丙基硫化物的牙科材料

    公开(公告)号：US20070203256A1

    公开(公告)日：2007-08-30

    申请号：US11482164

    申请日：2006-07-07

    申请人： Jorg Angermann ,  Peter Burtscher ,  Urs Karl Fischer ,  Norbert Moszner ,  Volker M. Rheinberger

    发明人： Jorg Angermann ,  Peter Burtscher ,  Urs Karl Fischer ,  Norbert Moszner ,  Volker M. Rheinberger

    IPC分类号： A61K6/08

    CPC分类号： A61K6/083 ,  A61K6/0017 ,  A61K6/0023 ,  C08L33/00

    摘要： Dental materials and associated methods are described based on multicyclic allyl sulphides with general Formula (I): in which R1 is H or a C1-C10 alkyl radical; R2 is H or a C1-C10 alkyl radical; R3 is absent or is a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C6-C12 radical, a C6-C14 arylene or C7-C20 alkylene arylene radical; R4 is an n-times substituted aliphatic C2 to C20 hydrocarbon radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, an aromatic C6-C14 radical, an aliphatic-aromatic C7-C20 radical or a heterocyclic radical which can contain 4 to 20 carbon atoms and 1 to 6 heteroatoms which are selected from N, O, P and/or S atoms, or which is formed exclusively by these heteroatoms; R5 is absent or is a C1-C10 alkylene radical; X is absent or is O, S, —O—CO— or —O—CO—NH—; Y is absent or is O, S, —O—CO— or —O—CO—NH—; m is 0 or 1 and n is an integer from 3 to 6.

    摘要翻译： 牙科材料和相关方法基于通式（I）的多环烯丙基硫化物来描述：其中R 1是H或C 1 -C 10烷基， 烷基; R 2是H或C 1 -C 10烷基; R 3不存在或是可以被O或S中断的C 1 -C 20亚烷基，脂环族C 1 -C 20烷基， 4个-C 12 - 基团，双环C 6 -C 12 - 基团，C 6 - -C 14亚芳基或C 7 -C 20亚烷基亚芳基; R 4是可以被O或S间隔的n 20取代的C 20烃基C 2〜C 20烃基， 芳族C 6 -C 14 - 基团，脂族 - 芳族C 1 -C 12烷基，芳基C 6 -C 14 - 或者可以含有4至20个碳原子和1至6个选自N，O，P和/或S原子的杂原子的杂环基团，或其中 完全由这些杂原子形成; R 5不存在或者是C 1 -C 10亚烷基; X不存在或为O，S，-O-CO-或-O-CO-NH-; Y不存在或为O，S，-O-CO-或-O-CO-NH-; m为0或1，n为3至6的整数。

    Photopolymerizable dental materials with bisacylphosphine oxides as initiators
    16.
    发明授权
    Photopolymerizable dental materials with bisacylphosphine oxides as initiators 有权
    具有双酰基氧化膦作为引发剂的光聚合牙科材料

    公开(公告)号：US07714034B2

    公开(公告)日：2010-05-11

    申请号：US11385058

    申请日：2006-03-21

    申请人： Norbert Moszner ,  Volker M. Rheinberger ,  Ulrich Salz ,  Heinrich Gruber ,  Robert Liska ,  Beate Ganster ,  Gerald Ullrich

    发明人： Norbert Moszner ,  Volker M. Rheinberger ,  Ulrich Salz ,  Heinrich Gruber ,  Robert Liska ,  Beate Ganster ,  Gerald Ullrich

    IPC分类号： C08F2/50 ,  A61K6/00 ,  A61K6/083

    CPC分类号： A61K6/083 ,  A61K6/0023 ,  C08L33/00

    摘要： Polymerizable dental material which contains at least one radically-polymerizable monomer and at least one bisacylphosphine oxide of the Formula I, in which R1 is a linear or branched C2 to C14 alkyl residue, which can be interrupted by one or more O atoms, PG-Y—R2—X— or a substituted or unsubstituted, aromatic C6 to C14 radical; R2 is absent or a linear or branched C1 to C20 alkylene radical, which can be interrupted by one or more O atoms; R3 is H, a linear or branched C1 to C6 alkyl residue or PG-Y—R2—X—; R4 is a linear or branched C1-C6 alkyl or —O—C1-C6 alkyl residue; R5 is H or PG-Y—R2—X—; R6 is H or PG-Y—R213 X—; PG is a polymerizable group; X is absent, O or S; Y is absent, O, S, an ester, amide or urethane group; the bisacylphosphine oxide having at least one PG-Y—R2—X group and X and/or Y being absent if R2 is absent.

    摘要翻译： 含有至少一种可自由基聚合的单体和至少一种式I的双酰基氧化膦的可聚合的牙科材料，其中R 1是可被一个或多个O原子间隔的直链或支链C 2至C 14烷基残基，PG- Y-R2-X或取代或未取代的芳族C 6至C 14基; R2不存在或可被一个或多个O原子中断的直链或支链C1至C20亚烷基; R3是H，直链或支链C1至C6烷基残基或PG-Y-R2-X-; R4是直链或支链C1-C6烷基或-O-C1-C6烷基残基; R5是H或PG-Y-R2-X-; R6是H或PG-Y-R213 X-; PG是可聚合基团; X不存在，O或S; Y不存在，O，S，酯，酰胺或氨基甲酸酯基; 如果R2不存在，则具有至少一个PG-Y-R2-X基团的双酰基氧化膦和X和/或Y不存在。

    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides
    18.
    发明申请
    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides 有权
    基于可自由基聚合的N，O-官能化丙烯酸羟基酰胺的材料

    公开(公告)号：US20080234405A1

    公开(公告)日：2008-09-25

    申请号：US11898338

    申请日：2007-09-11

    申请人： Norbert Moszner ,  Iris Lamparth ,  Urs Karl Fischer ,  Frank Zeuner ,  Armin de Meijere ,  Volker M. Rheinberger

    发明人： Norbert Moszner ,  Iris Lamparth ,  Urs Karl Fischer ,  Frank Zeuner ,  Armin de Meijere ,  Volker M. Rheinberger

    IPC分类号： A61K6/083 ,  C07C233/02 ,  C08F20/58 ,  A61L27/16 ,  A61L27/34 ,  C07F9/08 ,  C07F9/38

    CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  C08L33/26 ,  C08L33/14

    摘要： A material contains at least a polymerizable N,O-functionalized acrylic acid hydroxyamide of the Formula (I) in which A is an n+m-valent linear or branched aliphatic C1 to C50 radical, in which the carbon chain can be interrupted by O, S, —CO—O—, CO—NH, O—CO—NH or NH—CO—NH, an n+m-valent aromatic C6 to C18 radical or an n+m-valent cycloaliphatic or heterocyclic C3 to C18 radical, wherein the radicals can carry one or more substituents, Y is not present, or is O, S, an ester, amide or urethane group, R1 is hydrogen, an aliphatic C1 to C20 alkyl or C3 to C8 cycloalkyl radical which can carry one or more substituents, R2 is H or a C1 to C10 alkyl radical, R3 is not present or is a C1 to C16 alkylene radical which can be interrupted by O, HG is not present, is —COOH, —P═O(OH)2; —P═O(OH)(OR4); —O—P═O(OH)2, —SO2OH or —O—P═O(OH)(OR4), R4 is a C1 to C15 alkyl radical, phenyl or benzyl radical and n is a number from 1 to 5 and m a number from 0 to 3.

    摘要翻译： 材料至少含有式（I）的可聚合的N，O-官能化丙烯酸羟基酰胺，其中A是n + m价的直链或支链脂肪族C 1至C 50 其中碳链可被O，S，-CO-O-，CO-NH，O-CO-NH或NH-CO-NH中断，n + m价芳族C < C 6至C 18或C 14环烷基或杂环C 3〜C 18 - 基团，其中 基团可以携带一个或多个取代基，Y不存在，或者是O，S，酯，酰胺或氨基甲酸酯基，R 1是氢，脂族C 1 C 20 -C 20烷基或C 3至C 8环烷基，其可以携带一个或多个取代基R 2 O / 是H或C 1至C 10烷基，R 3不存在或者是C 1〜 可以被O，HG中断的C 16 -C 16亚烷基，不存在，是-COOH，-PO（OH）2。 -P-O（OH）（OR 4）; -OPO（OH）2，-SO 2 OH或-OPO（OH）（OR 4），R 4， SUP>是C 15 -C 15烷基，苯基或苄基，n是1至5的数和0至3的数。