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    Dental materials based on ring-opening polymerizable acid monomers
    1.
    发明申请
    Dental materials based on ring-opening polymerizable acid monomers 审中-公开
    基于开环聚合酸单体的牙科材料

    公开(公告)号：US20070287792A1

    公开(公告)日：2007-12-13

    申请号：US11585280

    申请日：2006-10-24

    Applicant: Norbert Moszner ,  Jorg Angermann ,  Frank Zeuner ,  Armin de Mejere ,  Urs Karl Fischer ,  Volker Rheinberger

    Inventor： Norbert Moszner ,  Jorg Angermann ,  Frank Zeuner ,  Armin de Mejere ,  Urs Karl Fischer ,  Volker Rheinberger

    IPC: C08L31/00

    CPC classification number: A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  C08L33/00

    Abstract: Dental material which contains at least one radically polymerizable monomer according to the general formula (I): in which PG is a cyclic, ring-opening polymerizable group; X1 is absent, O, S, is an ester, amide or urethane group; X2 is absent with, O, S, is an ester, amide or urethane group; Y is absent, O, S, is an ester, amide or urethane group; R is an organic radical with a valency of (n+m), with 1 to 35 carbon atoms and 0 to 8 heteroatoms, the H atoms of which can be wholly or partially substituted by F atoms; R1 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; R2 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; n is 1, 2, 3, 4, 5 or 6; m is 1, 2 or 3; HG is —P═O(OH)2; —P═O(OH)(OR14); —O—P═O(OH)2, —O—P═O(OH)(OR15) or —SO2OH, wherein R14 is a C1-C15 alkyl radical, phenyl or benzyl radical; and R15 is a C1-C15 alkyl radical, phenyl or benzyl radical.

    Abstract translation: 含有至少一种根据通式（I）的可自由基聚合的单体的牙科材料：其中PG是环状可开环聚合基团; X 1不存在，O，S是酯，酰胺或氨基甲酸酯基; O，S不是酯，酰胺或氨基甲酸酯基; Y不存在，O，S是酯，酰胺或氨基甲酸酯基; R为化合价为（n + m），有1至35个碳原子和0至8个杂原子的有机基团，其H原子可以被F原子全部或部分取代; R 1不存在或可被O原子间断的C 1 -C 16亚烷基; R 2不存在或可被O原子间隔的C 1 -C 16亚烷基; n为1,2,3,4,5或6; m为1,2或3; HG是-P-O（OH）2; -P-O（OH）（OR 14）; -OPO（OH）2，-OPO（OH）（OR 15）或-SO 2 OH，其中R 14， CH 2是C 1 -C 15烷基，苯基或苄基; R 15是C 1 -C 15烷基，苯基或苄基。

    Self-etching dental materials based on (METH) acrylamide phosphates
    3.
    发明申请
    Self-etching dental materials based on (METH) acrylamide phosphates 有权
    基于（METH）丙烯酰胺磷酸盐的自蚀牙科材料

    公开(公告)号：US20060135719A1

    公开(公告)日：2006-06-22

    申请号：US11211938

    申请日：2005-08-25

    Applicant: Norbert Moszner ,  Iris Lamparth ,  Frank Zeuner ,  Ulrich Salz ,  Angela Mucke ,  Jorg Zimmermann ,  Jorg Angermann ,  Volker Rheinberger

    Inventor： Norbert Moszner ,  Iris Lamparth ,  Frank Zeuner ,  Ulrich Salz ,  Angela Mucke ,  Jorg Zimmermann ,  Jorg Angermann ,  Volker Rheinberger

    IPC: C08F120/54

    CPC classification number: A61K6/0017 ,  A61K6/0023 ,  A61K6/0029 ,  A61K6/083 ,  A61K6/09 ,  C08L33/26 ,  C08L33/04 ,  C08L75/04

    Abstract: Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-C10 aralkyl or a bicylic C4-C12 radical; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.

    Abstract translation: 可聚合的牙科材料，其特征在于它含有至少一种下列通式（I）的（甲基）丙烯酰胺磷酸酯：其中R 1是H或CH 3; R 2是H或C 1 -C 4烷基，或与其键合的氮原子一起形成一个或多个 属于R 3或R 3'杂原子的杂原子; R 3，R 3，R 3'彼此独立地是直链或支链的脂族C 1 -C 50 - 基团 具有m + n或p + n的化合价，m + n或p + n的芳族C 6 -C 18 - 基团，或脂环族基团， 芳烷基或杂环C 3 -C 18 - 基团，其价态为m + n或p + n，其中基团或基团的碳链可以被O， S，CONR 4，OCONH，或与一个或多个属于R 2的原子和氮原子一起形成，R 2 O 2 >键合杂环，如果p = 0，则R 3'为H，R 4为H，C 1 -C 3 C 10 -C 12烷基，C 6 -C 12芳基，C 6 -C 10芳烷基或C 6 -C 12烷基 二元C 4 -C 12 - 基团; 如果p = 0，则n为1,2,3或4，如果p <0，则为1或2; m为1,2,3或4; p是0，1，2，3或4; x是0或S.

    SELF-ETCHING DENTAL MATERIALS BASED ON (METH)ACRYLAMIDE PHOSPHATES
    6.
    发明申请
    SELF-ETCHING DENTAL MATERIALS BASED ON (METH)ACRYLAMIDE PHOSPHATES 审中-公开
    基于（甲基）丙烯酰胺磷酸盐的自我蚀刻牙科材料

    公开(公告)号：US20100041790A1

    公开(公告)日：2010-02-18

    申请号：US12605079

    申请日：2009-10-23

    Applicant: Norbert MOSZNER ,  Iris LAMPARTH ,  Frank ZEUNER ,  Ulrich SALZ ,  Angela MUCKE ,  Jorg ZIMMERMANN ,  Jorg ANGERMANN ,  Volker M. RHEINBERGER

    Inventor： Norbert MOSZNER ,  Iris LAMPARTH ,  Frank ZEUNER ,  Ulrich SALZ ,  Angela MUCKE ,  Jorg ZIMMERMANN ,  Jorg ANGERMANN ,  Volker M. RHEINBERGER

    IPC: A61K6/00 ,  C07F9/08

    CPC classification number: A61K6/0017 ,  A61K6/0023 ,  A61K6/0029 ,  A61K6/083 ,  A61K6/09 ,  C08L33/26 ,  C08L33/04 ,  C08L75/04

    Abstract: Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-C10 aralkyl or a bicyclic C4-C12 radical; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.

    Abstract translation: 可聚合牙科材料，其特征在于其含有至少一种下列通式（I）的（甲基）丙烯酰胺磷酸酯：其中R1是H或CH3; R2是H或C1-C4烷基或与其键合的氮原子一起形成一个或多个属于R3或R3'杂原子的原子; R 3，R 3'彼此独立地为具有m + n或p + n价的直链或支链脂族C 1 -C 50基团，价数为m + n或p + n的芳族C 6 -C 18基团或 脂环族，芳脂族或杂环C 3 -C 18基，其价态为m + n或p + n，其中基团或基团的碳链可被O，S，CONR 4，OCONH中断，或与一个或多个原子一起形成 它们属于R2和氮原子，R 2与杂环结合，如果p = 0，则R3'为H，R4为H，C1-C10烷基，C6-C12芳基，C6-C10芳烷基或双环 C4-C12基; 如果p = 0，则n为1,2,3或4，如果p≠0，则为1或2; m为1,2,3或4; p是0，1，2，3或4; x是0或S.

    Self-etching dental materials based on (METH) acrylamide phosphates
    9.
    发明授权
    Self-etching dental materials based on (METH) acrylamide phosphates 有权
    基于（METH）丙烯酰胺磷酸盐的自蚀牙科材料

    公开(公告)号：US07622538B2

    公开(公告)日：2009-11-24

    申请号：US11211938

    申请日：2005-08-25

    Applicant: Norbert Moszner ,  Iris Lamparth ,  Frank Zeuner ,  Ulrich Salz ,  Angela Mucke ,  Jorg Zimmermann ,  Jorg Angermann ,  Volker M. Rheinberger

    Inventor： Norbert Moszner ,  Iris Lamparth ,  Frank Zeuner ,  Ulrich Salz ,  Angela Mucke ,  Jorg Zimmermann ,  Jorg Angermann ,  Volker M. Rheinberger

    IPC: C08F20/58 ,  C08F20/60

    CPC classification number: A61K6/0017 ,  A61K6/0023 ,  A61K6/0029 ,  A61K6/083 ,  A61K6/09 ,  C08L33/26 ,  C08L33/04 ,  C08L75/04

    Abstract: Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-10 aralkyl or a bicylic C4-C12 radial; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p ≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.

    Abstract translation: 可聚合牙科材料，其特征在于其含有至少一种下列通式（I）的（甲基）丙烯酰胺磷酸酯：其中R1是H或CH3; R2是H或C1-C4烷基或与其键合的氮原子一起形成一个或多个属于R3或R3'杂原子的原子; R 3，R 3'彼此独立地为具有m + n或p + n价的直链或支链脂族C 1 -C 50基团，价数为m + n或p + n的芳族C 6 -C 18基团或 脂环族，芳脂族或杂环C 3 -C 18基，其价态为m + n或p + n，其中基团或基团的碳链可被O，S，CONR 4，OCONH中断，或与一个或多个原子一起形成 属于R2和氮原子，R 2与杂环结合，如果p = 0，则R3'为H，R4为H，C1-C10烷基，C6-C12芳基，C6-10芳烷基或双 C4-C12径向; 如果p = 0，则n为1,2,3或4，如果p为0，则为1或2; m为1,2,3或4; p是0，1，2，3或4; x是0或S.

    DENTAL MATERIALS WITH SURFACE-FUNCTIONALIZED FILLERS
    10.
    发明申请
    DENTAL MATERIALS WITH SURFACE-FUNCTIONALIZED FILLERS 审中-公开
    具有表面官能化填料的牙科材料

    公开(公告)号：US20090186960A1

    公开(公告)日：2009-07-23

    申请号：US12275700

    申请日：2008-11-21

    Applicant: Norbert MOSZNER ,  Jorg ANGERMANN ,  Simone KLAPDOHR

    Inventor： Norbert MOSZNER ,  Jorg ANGERMANN ,  Simone KLAPDOHR

    IPC: A61K6/093 ,  C08G77/14 ,  C07F5/06 ,  C07F7/18 ,  C07F5/00

    CPC classification number: A61K6/0008 ,  A61K6/0017 ,  A61K6/0023 ,  A61K6/0088 ,  A61K6/093 ,  C08L83/10

    Abstract: The invention relates to a polymerizable composition which is characterized in that it contains at least one filler that is surface-functionalized with groups of formula (I), wherein groups of formula (I) (A)a-Z-Y—R2—SiR13−m—(O—)m   (I), are bonded to the filler via at least one oxygen atom that is bound to the silicon atom of the group of formula (I). The invention also relates to a process for the preparation of the composition according to the invention and its use in particular as a dental material.

    Abstract translation: 本发明涉及一种可聚合组合物，其特征在于其含有至少一种用式（I）的基团表面官能化的填料，其中式（I）的基团<？在线公式描述=“In- （A）aZY-R2-SiR13-m-（O-）m（I），<？在线公式描述=“在线公式”end =“tail” α'通过与式（I）的基团的硅原子结合的至少一个氧原子键合到填料上。 本发明还涉及制备根据本发明的组合物及其用途，特别是牙科材料的方法。

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