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11.发明授权Alkoxylation using modified Group IIIB metal-containing bimetallic or polymetallic catalysts 失效使用改性IIIB族金属包含双金属或多金属催化剂的烷氧化
公开(公告)号：US5118650A
公开(公告)日：1992-06-02
申请号：US251436
申请日：1988-09-30
申请人： Stephen W. King
发明人： Stephen W. King
IPC分类号： B01F17/42 , B01J31/04 , B01J31/12 , B01J31/22 , B01J31/26 , C07B41/04 , C07B61/00 , C07C41/03 , C07C43/11 , C07F5/00
CPC分类号： C07C41/03 , B01J31/223 , B01J2531/37
摘要： This invention relates to modified Group IIIB metal-containing bimetallic or polymetallic catalysts and the use thereof in the preparation of alkoxylation products, i.e., condensation reaction products of alkylene oxides and organic compounds having at least one active hydrogen. In another aspect of this invention, processes are provided for preparing the modified Group IIIB metal-containing bimetallic or polymetallic catalysts for alkoxylation using a Group IIIB metal or a Group IIIB metal-containing compound as sources for the catalytically-active Group IIIB metal. In a further aspect of this invention, processes are provided for preparing alkoxylation products that have beneficial, narrow molecular weight ranges using the modified Group IIIB metal-containing bimetallic or polymetallic catalysts.
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12.发明授权Processes for separating one or more amine byproducts from one or more desired amines 有权从一种或多种所需胺分离一种或多种胺副产物的方法公开(公告)号：US08895785B2
公开(公告)日：2014-11-25
申请号：US13996997
申请日：2011-12-06
IPC分类号： C07C209/84 , C07C209/86
CPC分类号： C07C209/84 , C07C209/86 , C07C211/10
摘要： The present invention relates to separating one or more amine byproducts from one or more desired amines. More particularly, the invention involves forming a byproduct component with one or more amine byproducts and a first adjuvant component. The byproduct component has an enhanced separation characteristic relative to separating the amine byproducts from the desired amines in the absence of an adjuvant. Preferably, the byproduct component is separated in the presence of a second adjuvant component that preferably has a boiling point less than the boiling point of the first adjuvant component.
摘要翻译： 本发明涉及从一种或多种所需胺分离一种或多种胺副产物。 更具体地，本发明涉及用一种或多种胺副产物和第一佐剂组分形成副产物组分。 相对于在没有佐剂的情况下将胺副产物与所需胺分离，副产物组分具有增强的分离特性。 优选地，副产物组分在第二佐剂组分存在下分离，其优选的沸点低于第一助剂组分的沸点。
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公开(公告)号：US08853459B2
公开(公告)日：2014-10-07
申请号：US13876388
申请日：2011-09-13
IPC分类号： C07C209/84
CPC分类号： C07C209/84 , C07C211/14
摘要： The present invention provides methods that are used to decolorize compositions containing one or more amines in the presence of one or more weak acids. Significantly, the weak acids, particularly organic acids such as glacial acetic acid, when used in combination with a heat treatment produce dramatically less by-products than do the stronger mineral acids, making heat treatments and subsequent separation techniques more effective while producing less waste. In some modes of practice, the weak acids do not need to be neutralized, eliminating neutralizing steps and waste streams associated with neutralization. Low color products can be obtained easily at very high yield as a consequence.
摘要翻译： 本发明提供了用于在一种或多种弱酸存在下使包含一种或多种胺的组合物脱色的方法。 重要的是，弱酸，特别是有机酸，如冰醋酸，当与热处理相结合使用时，产生的副产物比较强的无机酸显着减少，使热处理和随后的分离技术更有效，同时产生更少的废物。 在某些实践模式中，弱酸不需要中和，消除了与中和相关的中和步骤和废物流。 因此，可以以非常高的产率容易地获得低颜色产品。
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公开(公告)号：US08618108B2
公开(公告)日：2013-12-31
申请号：US12587338
申请日：2009-10-06
IPC分类号： A61K31/50 , A61K31/501 , A61K31/497 , C07D241/04 , C07D295/00
CPC分类号： C07D295/13 , C07D241/04
摘要： The present invention provides strategies for making cyclic triamines. Reactant media including certain precursors and/or certain types of catalysts can be converted into cyclic triamines with improved conversion and selectivity. The strategies can be incorporated into reactions that involve transamination schemes and/or reductive amination schemes. In the case of transamination, for instance, using transamination to cause ring closure of higher amines in the presence of a suitable catalyst leads to desired cyclic triamines with notable conversion and yield. In the case of reductive amination, reacting suitable polyfunctional precursors in the presence of a suitable catalyst also yields cyclic triamines via ring closure with notable selectivity and conversion. Both transamination and reductive amination methodologies can be practiced under much milder temperatures than are used when solely acid catalysts are used. Preferred embodiments can produce reaction mixtures that are generally free of salt by-products.
摘要翻译： 本发明提供了制备环状三胺的策略。 包括某些前体和/或某些类型的催化剂的反应介质可以转化为具有改进的转化率和选择性的环状三胺。 这些策略可纳入涉及转氨酶和/或还原胺化方案的反应中。 在转氨酶的情况下，例如，在合适的催化剂存在下，使用氨基转移引发高级胺的闭环，导致期望的环状三胺具有显着的转化率和产率。 在还原胺化的情况下，在合适的催化剂存在下使合适的多官能前体反应也通过环闭合产生环状三胺，具有明显的选择性和转化率。 氨基转移和还原胺化方法都可以在比仅使用酸性催化剂时使用的温度更温和的温度下实施。 优选的实施方案可以产生通常不含盐副产物的反应混合物。
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15.发明申请PROCESSES FOR SEPARATING ONE OR MORE AMINE BYPRODUCTS FROM ONE OR MORE DESIRED AMINES 有权从一个或多个所需的氨基酸分离一个或多个氨基酸的方法公开(公告)号：US20130274522A1
公开(公告)日：2013-10-17
申请号：US13996997
申请日：2011-12-06
IPC分类号： C07C209/84
CPC分类号： C07C209/84 , C07C209/86 , C07C211/10
摘要： The present invention relates to separating one or more amine byproducts from one or more desired amines. More particularly, the invention involves forming a byproduct component with one or more amine byproducts and a first adjuvant component. The byproduct component has an enhanced separation characteristic relative to separating the amine byproducts from the desired amines in the absence of an adjuvant. Preferably, the byproduct component is separated in the presence of a second adjuvant component that preferably has a boiling point less than the boiling point of the first adjuvant component.
摘要翻译： 本发明涉及从一种或多种所需胺分离一种或多种胺副产物。 更具体地，本发明涉及用一种或多种胺副产物和第一佐剂组分形成副产物组分。 相对于在没有佐剂的情况下将胺副产物与所需胺分离，副产物组分具有增强的分离特性。 优选地，副产物组分在第二佐剂组分存在下分离，其优选的沸点低于第一助剂组分的沸点。
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16.发明授权Process to selectively manufacture diethylenetriamine (DETA) or other desirable ethyleneamines via continuous transamination of ethylenediamine (EDA), and other ethyleneamines over a heterogeneous catalyst system 有权通过在多相催化剂体系上连续氨基乙二胺（EDA）和其它亚乙基胺选择性地制备二亚乙基三胺（DETA）或其它所需的亚乙基胺的方法公开(公告)号：US08383860B2
公开(公告)日：2013-02-26
申请号：US12587372
申请日：2009-10-06
IPC分类号： C07C209/00
CPC分类号： C07C209/64 , C07C211/14
摘要： The present invention reacts ethylenediamine with one or more additional ethyleneamines in the presence of a transamination catalyst to provide a different, preferably more desirable product mix of one or more ethyleneamines.
摘要翻译： 本发明在氨基转移催化剂存在下使乙二胺与一种或多种另外的乙撑胺反应，以提供不同的，优选更理想的一种或多种亚乙基胺的产物混合物。
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公开(公告)号：US08273884B2
公开(公告)日：2012-09-25
申请号：US12587380
申请日：2009-10-06
IPC分类号： C07D241/04 , C07D295/00
CPC分类号： C07D295/13 , C07D241/04
摘要： The present invention provides strategies for making cyclic triamines. Reactant media including certain precursors and/or certain types of catalysts can be converted into cyclic triamines with improved conversion and selectivity. The strategies can be incorporated into reactions that involve transamination schemes and/or reductive amination schemes. In the case of transamination, for instance, using transamination to cause ring closure of higher amines in the presence of a suitable catalyst leads to desired cyclic triamines with notable conversion and yield. In the case of reductive amination, reacting suitable polyfunctional precursors in the presence of a suitable catalyst also yields cyclic triamines via ring closure with notable selectivity and conversion. Both transamination and reductive amination methodologies can be practiced under much milder temperatures than are used when solely acid catalysts are used. Preferred embodiments can produce reaction mixtures that are generally free of salt by-products.
摘要翻译： 本发明提供了制备环状三胺的策略。 包括某些前体和/或某些类型的催化剂的反应物介质可以转化为具有改进的转化率和选择性的环状三胺。 这些策略可纳入涉及转氨酶和/或还原胺化方案的反应中。 在转氨酶的情况下，例如，在合适的催化剂存在下，使用氨基转移引发高级胺的闭环，导致期望的环状三胺具有显着的转化率和产率。 在还原胺化的情况下，在合适的催化剂存在下使合适的多官能前体反应也通过环闭合产生环状三胺，具有明显的选择性和转化率。 氨基转移和还原胺化方法都可以在比仅使用酸性催化剂时使用的温度更温和的温度下实施。 优选的实施方案可以产生通常不含盐副产物的反应混合物。
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18.发明申请PROCESS FOR MAKING ETHERS FROM ALKOXIDE ANIONS OR PRECURSORS OF ALKOXIDE ANIONS 有权来自烷氧化物阴离子或碱性阴离子前体的制备方法公开(公告)号：US20100280277A1
公开(公告)日：2010-11-04
申请号：US12680022
申请日：2008-09-22
IPC分类号： C07C43/11
摘要： Improved methods for making ethers. In particular, an alkoxide can be more effectively converted into an ether by reaction with a hydrocarbyl halide in the presence of a substantial excess of a hygroscopic base such as NaOH. When present in such an unconventional excess, the base serves multiple functions. As a consequence, the alkoxide is extensively converted to the desired ether rapidly at excellent yields. The reaction environment also aids later product isolation. The use of the NaOH rather than Na metal allows the ether product to be separated from water soluble impurities such as salt products, left over base, left over hydrocarbyl halide, formates, etc. by liquid-liquid extraction among aqueous and organic phases.
摘要翻译： 改进制备醚的方法。 特别地，在大量过量的吸湿性碱如NaOH的存在下，通过与烃基卤化物反应，可以更有效地将醇盐转化为醚。 当这种非常规的超量存在时，该基座具有多种功能。 因此，醇盐以极好的收率快速地转化为所需的醚。 反应环境还有助于后期产品分离。 使用NaOH而不是Na金属允许醚产物与水溶性杂质如盐产物分离，残留在碱，残留在烃基卤化物，甲酸盐等上，通过液相萃取在水相和有机相中。
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19.发明申请Low metal loaded, alumina supported, catalyst compositions and amination process 有权低金属负载，氧化铝负载，催化剂组合物和胺化方法公开(公告)号：US20100137642A1
公开(公告)日：2010-06-03
申请号：US12587355
申请日：2009-10-06
申请人： Stephen W. King , Stefan K. Mierau
发明人： Stephen W. King , Stefan K. Mierau
IPC分类号： C07C209/66 , B01J21/08 , B01J23/75 , B01J23/10 , B01J21/04 , B01J21/06 , B01J23/755 , B01J23/72
CPC分类号： B01J23/70 , B01J21/12 , B01J23/755 , C07C209/64 , C07C211/14
摘要： The present invention provides catalyst compositions useful for transamination reactions. The catalyst compositions have a catalyst support that includes transitional alumina, use a low metal loading (for example, less than 25 wt. %), and do not require the presence of rhenium. The catalyst compositions are able to advantageously promote transamination of a reactant product (such as the transamination of EDA to DETA) with excellent activity and selectivity, and similar to transaminations promoted using a precious metal-containing catalyst.
摘要翻译： 本发明提供了可用于氨基转移反应的催化剂组合物。 催化剂组合物具有包括过渡氧化铝的催化剂载体，使用低的金属负载（例如，小于25重量％），并且不需要存在铼。 催化剂组合物能够以优异的活性和选择性有利地促进反应物产物的转氨基反应（如EDA的转氨酶），并且类似于使用贵金属的催化剂促进的转氨酶。
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20.发明申请Low metal loaded, catalyst compositions including acidic mixed metal oxide as support 有权低金属负载的催化剂组合物，包括作为载体的酸性混合金属氧化物公开(公告)号：US20100087682A1
公开(公告)日：2010-04-08
申请号：US12587351
申请日：2009-10-06
申请人： Stephen W. King , Stefan K. Mierau
发明人： Stephen W. King , Stefan K. Mierau
IPC分类号： C07C209/00 , B01J21/04 , B01J23/10 , B01J21/10 , B01J21/02 , B01J23/888 , B01J21/06
CPC分类号： B01J23/8896 , B01J21/12 , B01J35/008 , B01J35/1014 , B01J35/1019 , B01J37/0201 , C07C209/00
摘要： The invention provides a catalyst composition composed of a support portion and a catalyst portion. The support portion includes an acidic mixed metal oxide including a transitional alumina and a second metal oxide. The transitional alumina can comprise delta or theta alumina, in combination with other transitional phases, or an alpha or gamma alumina. The second metal oxide has a weight percentage that is less than the weight percentage of alumina. The catalyst portion is 25 weight percent or less of the catalyst composition and is composed of nickel and rhenium. The catalyst portion includes nickel in an amount in the range of 2 to 20 weight percent, based upon total catalyst composition weight, and there is no boron in the catalyst portion.
摘要翻译： 本发明提供一种由支撑部分和催化剂部分组成的催化剂组合物。 支撑部分包括包含过渡氧化铝和第二金属氧化物的酸性混合金属氧化物。 过渡氧化铝可以包含与其它过渡相结合的δ或θ氧化铝，或α或γ氧化铝。 第二金属氧化物的重量百分比小于氧化铝的重量百分数。 催化剂部分为催化剂组合物的25重量％以下，由镍和铼构成。 催化剂部分包括基于总催化剂组合物重量的2-20重量％范围内的量的镍，并且在催化剂部分中不存在硼。
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