Tetraketone porphyrin monomers and the porphyrin-based polymers thereof
    12.
    发明授权
    Tetraketone porphyrin monomers and the porphyrin-based polymers thereof 失效
    四酮卟啉单体及其卟啉类聚合物

    公开(公告)号:US5091502A

    公开(公告)日:1992-02-25

    申请号:US491747

    申请日:1990-03-12

    Abstract: The present invention relates to a tetraketone of the structure ##STR1##wherein M is a metal atom and R is selected from phenyl, alkyl substituted phenyl or halogen substituted phenyl. The process to prepare this tetraketone is disclosed. The present invention also relates to a process to produce the tetraketone structure(I). The present invention also relates to the novel polymer of the structure: ##STR2##and to the process to produce this novel polymer. R is as defined hereinabove, and Ar is a tetraamine substituted organic moiety having at least one aromatic ring. These polymers are useful as liquid crystals and in non-linear optical devices.

    Abstract translation: 本发明涉及结构式I或(Ⅰ)的四酮,其中M是金属原子,R选自苯基,烷基取代的苯基或卤素取代的苯基。 公开了制备该四酮的方法。 本发明还涉及生产四酮结构(I)的方法。 本发明还涉及以下结构的新型聚合物:< IMAGE>和制备该新型聚合物的方法。 R如上所定义,Ar是具有至少一个芳环的四胺取代的有机部分。 这些聚合物可用作液晶和非线性光学器件。

    Direct deposition of palladium
    13.
    发明授权
    Direct deposition of palladium 失效
    直接沉积钯

    公开(公告)号:US5894038A

    公开(公告)日:1999-04-13

    申请号:US808302

    申请日:1997-02-28

    CPC classification number: C23C18/08 H05K3/105

    Abstract: The present invention is directed to a process for forming a layer of palladium on a substrate, comprising:preparing a solution of a palladium precursor, wherein the palladium precursor consists ofPd(OOCR.sup.1).sub.m (OOCR.sup.2).sub.nwhereinR.sup.1 is hydrogen, alkyl, alkenyl, alkynyl, --R.sup.3 COOH, alkyl from 1 to 5 carbons substituted with one or two hydroxyl groups,R.sup.2 is hydrogen, alkyl, alkenyl, alkynyl, --R.sup.3 COOH, alkyl from 1 to 5 carbon atoms substituted with one or two hydroxyl groups, --CHO,R.sup.3 is alkyl, and alkyl groups from 1 to 5 carbon atoms substituted with one or two hydroxyl groupsm and n are real numbers or fractions, and m+n=2;applying the palladium precursor to the surface of the substrate;decomposing the palladium precursor by subjecting the precursor to heat.

    Abstract translation: 本发明涉及一种在基底上形成钯层的方法,包括:制备钯前体溶液,其中钯前体由Pd(OOCR1)m(OOCR2)n组成,其中R1是氢,烷基,烯基, 炔基,-R3COOH,被一个或两个羟基取代的1至5个碳的烷基,R2是氢,烷基,烯基,炔基,-R3COOH,被一个或两个羟基取代的1至5个碳原子的烷基,-CHO, R3是烷基,被一个或两个羟基取代的1至5个碳原子的烷基m和n是实数或分数,m + n = 2; 将钯前体施加到基底的表面; 通过使前体受热来分解钯前体。

    Direct deposition of a gold layer
    14.
    发明授权
    Direct deposition of a gold layer 失效
    直接沉积金层

    公开(公告)号:US5846615A

    公开(公告)日:1998-12-08

    申请号:US808376

    申请日:1997-02-28

    CPC classification number: C23C18/08 H05K3/105

    Abstract: A process for forming a layer of gold on a substrate, comprising: preparing a solution of a gold precursor wherein the gold precursor consists of Au(OH).sub.p (OOCR.sup.1).sub.q (OOCR.sup.2).sub.r wherein R.sup.1 is selected from the group of hydrogen, alkyl, alkenyl, and alkynyl, and R.sup.2 is selected from the group of hydrogen, alkyl from 2 to 10 carbon atoms, alkenyl, or alkynyl, and p+q+r=3. Applying the solution of the gold precursor to the surface of the substrate. Decomposing the gold precursor by subjecting the gold precursor to heat.

    Abstract translation: 一种在基底上形成金层的方法,包括:制备金前体溶液,其中金前体由Au(OH)p(OOCR1)q(OOCR2)r组成,其中R 1选自氢,烷基, 烯基和炔基,R 2选自氢,2至10个碳原子的烷基,烯基或炔基,p + q + r = 3。 将金前体的溶液施加到基材的表面。 通过使金前体受热来分解金前体。

    Metal ion porphyrin-containing poly(azine)
    16.
    发明授权
    Metal ion porphyrin-containing poly(azine) 失效
    含金属离子卟啉的聚(吖嗪)

    公开(公告)号:US5252698A

    公开(公告)日:1993-10-12

    申请号:US960487

    申请日:1992-10-09

    Abstract: The present invention relates to porphyrin and metal ion-containing monomers and polymers. The monomers ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently selected from H, alkyl having 1 to 6 carbon atoms, phenyl or phenyl substituted with 1 to 3 alkyl groups each having 1 to 6 carbons or with 1 to 3 halogen atoms and A is a metal atom, are used with a diamine or a dialdehyde respectively to produce a porphyrin polymer or a metal ion containing porphyrin polymer. These polymers are useful as electrical conductors and as liquid crystal polymers.

    Abstract translation: 本发明涉及卟啉和含金属离子的单体和聚合物。 单体“IMAGE”或“IMAGE”,其中R 1,R 2,R 3和R 4独立地选自H,具有1至6个碳原子的烷基,苯基或被1至3个各自具有1至6个碳的烷基取代的苯基或与 1〜3个卤素原子,A为金属原子,分别与二胺或二醛一起使用,生成卟啉聚合物或含有卟啉聚合物的金属离子。 这些聚合物可用作电导体和液晶聚合物。

    Tetrasulfonated metal phthalocyanine doped electrically conducting
electrochromic poly(dithiophene) polymers
    17.
    发明授权
    Tetrasulfonated metal phthalocyanine doped electrically conducting electrochromic poly(dithiophene) polymers 失效
    四磺基金属酞菁掺杂的导电电致变色聚(二噻吩)聚合物

    公开(公告)号:US5151224A

    公开(公告)日:1992-09-29

    申请号:US190540

    申请日:1988-05-05

    CPC classification number: C08G61/126 C09K9/02 H01B1/127

    Abstract: The present invention relates to a process of manufacture of an essentially smooth texture-free conductive polymer comprising poly(dithiophene) which is subsequently doped with a dopant comprising an organometallic compound, preferably an optionally substituted metal phthalocyanine. Specifically, the process relates to a process to produce a smooth, texture-free conductive polymer comprising poly(dithiophene) and an organometallic compound which process comprises:A. contacting a solution itself comprising:(a) dithiophene is present in between about 0.01 and 0.001 M concentration;(b) a water-soluble salt of an optionally substituted organometallic wherein the metal is selected from iron, copper, cobalt or nickel, at a concentration of between about 0.01 and 10 mM;(c) in a solution of acetonitrile/water in a ratio of between about 30:70 and 10:90 percent by volume with a cycling potential of between about 0.1 volts and 10 volts at between about 0.degree. and 95.degree. C. for between about (0.1 and 60 minutes) with an electrode selected from one of a second metal, wherein the second metal is selected from platinum, palladium, indium, gold or mixtures thereof or from an indium-tin oxide covered glass; andB. recovering the electrically conductive polymer. The materials are useful in the manufacture of electrochromic displays.

    Abstract translation: 本发明涉及一种制造基本上光滑的无纹理导电聚合物的方法,其包括聚(二噻吩),其随后掺杂有包含有机金属化合物,优选任选取代的金属酞菁的掺杂剂。 具体地说,该方法涉及产生包含聚(二噻吩)和有机金属化合物的光滑,无质感的导电聚合物的方法,该方法包括:A.将溶液本身接触,其包含:(a)二噻吩存在于约0.01和 0.001M浓度; (b)任选取代的有机金属盐的水溶性盐,其中所述金属选自铁,铜,钴或镍,浓度为约0.01至10mM; (c)在约30:70至10:90体积比之间的乙腈/水的溶液中,在约0至95℃之间的循环电位介于约0.1伏和10伏之间,在 大约(0.1和60分钟)与选自第二金属之一的电极,其中所述第二金属选自铂,钯,铟,金或其混合物或来自氧化铟锡覆盖玻璃; 和B.回收导电聚合物。 这些材料在电致变色显示器的制造中是有用的。

    Fabrication of electrodes and devices containing electrodes
    19.
    发明授权
    Fabrication of electrodes and devices containing electrodes 失效
    包含电极的电极和器件的制造

    公开(公告)号:US06168885A

    公开(公告)日:2001-01-02

    申请号:US09226558

    申请日:1999-01-05

    Abstract: Electrodes are manufactured using a fire-retardant solvent and a polymerizable monomer. Electrodes according to the present invention are contemplated to find applicability in substantially any electrode containing device, including batteries. A preferred class of fire-retardant solvents includes solvents that generate a fire-retardant gas upon decomposition. One subclass includes compositions that produce carbon dioxide upon decomposition. Other subclasses include species that generate non-CO2 gases upon decomposition, such as CO, SO2, SO3, NO, N2O, NO2, or N2. A second preferred class of fire-retardant solvents include solvents that are fire-retardant without generating a fire-retardant gas upon decomposition, and are electrochemically inactive. Subclasses here include the many phosphates, phosphazenes, borates, siloxanes, fluorinated carbonates and fluorinated ethers that are already known to be included in a fire-retardant electrolyte. It is contemplated that the same solvent may be used in both an electrode paste and an electrolyte. It is also contemplated that the same polymer may be used in both an electrode paste and an electrolyte. An exemplary polymer for this purpose is polyvinylidene fluoride (PVDF). In one or both such cases, an electrolyte may advantageously be applied directly to the porous electrode surface, providing excellent interlayer adhesion and thus low interfacial resistance.

    Abstract translation: 电极使用阻燃溶剂和可聚合单体制造。 考虑到根据本发明的电极可用于基本上任何包含电池的电极容纳装置中的适用性。 优选的阻燃溶剂类包括在分解时产生阻燃气体的溶剂。 一个子类包括在分解时产生二氧化碳的组合物。 其他子类包括在分解时产生非二氧化碳气体的物质,如CO,SO2,SO3,NO,N2O,NO2或N2。 阻燃溶剂的第二优选类别包括在分解时不产生阻燃气体而具有阻燃性并且是电化学惰性的溶剂。 这里的子类包括许多已知包含在阻燃电解质中的磷酸盐,磷腈,硼酸盐,硅氧烷,氟化碳酸盐和氟化醚。 预期在电极浆料和电解质中都可以使用相同的溶剂。 还可以设想,电极浆料和电解质中都可以使用相同的聚合物。 用于此目的的示例性聚合物是聚偏二氟乙烯(PVDF)。 在一种或两种这样的情况下,可以有利地将电解质直接施加到多孔电极表面,从而提供优异的层间粘合性,从而降低界面抗性。

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