摘要:
Provided are a ring-opening metathesis polymer and a hydrogenated product thereof that are useful as materials for an optical component, and a method for preparation thereof. The present invention relates to a ring-opening metathesis polymer comprising at least repeating structural units [A] represented by the following General Formula [1] and repeating structural units [B] represented by the following General Formula [2] at a constitutional molar ratio [A]/[B] of 0.1/99.9 to 100/0. The present invention relates to a ring-opening metathesis polymer comprising at least repeating structural units [A] represented by the following General Formula [1] and repeating structural units [B] represented by the following General Formula [2] at a constitutional molar ratio [A]/[B] of 0.1/99.9 to 100/0.
摘要:
Disclosed is a method for purifying a polymer in which a solution containing a cyclic olefin polymer having at least a repeating structural unit [A] represented by the general formula (1) and a metal component is brought into contact with an organic compound having a basic functional group and an acidic functional group, and then the resulting solution is brought into contact with a basic adsorbent to remove the metal component contained in the solution.
摘要:
A process for synthesizing an organic transition metal complex compound with an atom group having an electron-donor ability, in an industrially and economically advantageous manner, without a compound having a proton-donor ability being a metal salt, and a metathesis catalyst produced with the use of the above process, are provided. A process for producing an organic transition metal complex compound in which an atom group having an electron-withdrawing ability can be converted into an atom group having a stronger electron-donor ability, by contacting an compound having a proton-donor ability with the organic transition metal complex compound with an atom group having an electron-withdrawing ability, in the presence of an basic compound, and a metathesis catalyst of which the content of an alkali metal is reduced, and which is obtainable with the use of the above process, are provided.
摘要:
A hydrogenated ring-opening metathesis polymer containing at least structural units of the general formula [3] and/or the general formula [4] and the weight-average molecular weight Mw to the number-average molecular weight Mn (Mw/Mn) is more than 2.0 and less than 5.0: wherein R8 to R11 and R13 to R16 represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, X2s and X3s are the same or different and represent —O— or —CR122— wherein R12 represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, one of Y1 and y2 represents —(C═O)— and the other of Y1 and y2 represents —CR182— wherein R18 represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, and m and n represent an integer of 0 or 1 to 3.
摘要:
A favorably processable polyimide which has recurring structural units represented by the formula (I): ##STR1## wherein R is a tetravalent radical having from 2 to 27 carbon atoms and is selected from the group consisting of an aliphatic radical, alicyclic radical, monoaromatic radical, condensed polyaromatic radical and noncondensed aromatic radical connected to each other with a direct bond or a bridge member, and is blocked at the polymer chain end with aromatic dicarboxylic anhydride represented by the formula (II): ##STR2## wherein X is a divalent radical selected from the group consisting of a monoaromatic radical having from 6 to 27 carbon atoms, condensed polyaromatic radical and noncondensed aromatic radical connected to each other with a direct bond or a bridge member.
摘要翻译:具有由式(I)表示的重复结构单元的有利的可加工聚酰亚胺:(*化学结构*)(I)其中R是具有2至27个碳原子的四价基团,并且选自脂族基团 ,脂环族基团,单芳族基团,缩合多芳族基团和非缩合芳族基团,其与直接键合或桥连构件相互连接,并且在聚合物链端用由式(II)表示的芳族二羧酸酐封闭:(* CHEMICAL 结构*)(II)其中X是选自具有6至27个碳原子的单芳族基团的二价基团,缩合的多芳族基团和未缩合的芳香基团彼此直接连接或桥接成员。
摘要:
The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C1 to C10 alkyl group directly bonded to the aromatic ring and/or an alkylene group having 1 to 3 carbon atoms in the main chain in which at least one carbon atom directly bonded to the aromatic ring bonds to hydrogen, and a carbonyl group, or a carbon-carbon double bond or triple bond. The aromatic resins such as aromatic polyethers, aromatic polyamides, aromatic polyimides, aromatic polyamideimides, aromatic polyazoles, etc., which contain such a crosslinkable group, are preferred as the crosslinkable aromatic resins having a protonic acid group and a crosslinkable group.
摘要:
A thermoplastic resin composition comprise 99.9.about.50 parts by weight of one or more thermoplastic resin selected from the group consisting of aromatic polyimide, aromatic polyetherimide, aromatic polyamideimide, aromatic polyethersulfone and aromatic polyether ketone and 0.1.about.50 parts by weight of one or more liquid crystal type aromatic polyimide having recurring structural units represented by the formula (1): ##STR1## wherein R.sub.1 .about.R.sub.5 is a hydrogen atom, fluorine atom, trifluoromethyl, methyl, ethyl or cyano and may be the same or different, and R is a tetravalent radical having 6.about.27 carbon atoms and being selected from the group consisting of a monoaromatic radical, condensed polyaromatic radical and noncondensed aromatic radical connected each other with a direct bond or a bridge member.The present invention can provide thermoplastic resin compositions which have remarkably good processability and excellent thermal stability in addition to essentially excellent properties of each resin.
摘要:
An interior lamp can achieve both an excellent illumination function and an excellent illumination effect (providing a comfortable environment) and may possibly provide high merchandizability characteristics. The interior lamp can include an LED light source unit having a substrate and a plurality of white LED lamps and colored LED lamps mounted on the substrate. A cover case can be provided to serve as a light illumination unit. The light illumination unit can include a double-layer structure having a light diffusion layer and a light transmission layer. The light diffusion layer can have a plurality of penetrating holes. The light transmission layer can have a plurality of convex lens portions. The center axes of the penetrating holes and the corresponding lens portions can coincide with corresponding optical axes of the white LED lamps, respectively. The white light from the white LED lamps can be converged by the respective lens portions of the light transmission layer to be radiated outside as spot light(s). The colored light from the colored LED lamps can be diffused through the light diffusion layer to be radiated outside as diffused light.
摘要:
An interior lamp can achieve both an excellent illumination function and an excellent illumination effect (providing a comfortable environment) and may possibly provide high merchandizability characteristics. The interior lamp can include an LED light source unit having a substrate and a plurality of white LED lamps and colored LED lamps mounted on the substrate. A cover case can be provided to serve as a light illumination unit. The light illumination unit can include a double-layer structure having a light diffusion layer and a light transmission layer. The light diffusion layer can have a plurality of penetrating holes. The light transmission layer can have a plurality of convex lens portions. The center axes of the penetrating holes and the corresponding lens portions can coincide with corresponding optical axes of the white LED lamps, respectively. The white light from the white LED lamps can be converged by the respective lens portions of the light transmission layer to be radiated outside as spot light(s). The colored light from the colored LED lamps can be diffused through the light diffusion layer to be radiated outside as diffused light.
摘要:
A sliding material and a heat resistant filament which primarily comprises a liquid crystal polyimide, a liquid crystal polyamide or a liquid crystal polyamide-imide copolymer having at least one recurring structural unit selected from the formula (1) and the formula (2) and is excellent in heat resistance, mechanical characteristics and other fundamental properties of polyimides, and relates to significant improvement of heat-resistance by heat-treating the sliding material, the filament and the molded items. The liquid crystal polyamide-imide copolymer which comprises in a polymer molecule 0.05.about.0.95 mole ratio of the recurring structural units of the formula (1) and 0.95.about.0.05 mole ratio of recurring structural units of the formula (2) has excellent processing ability ##STR1##