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11.发明申请OLIGOMERIC POLYOLS FROM PALM-BASED OILS AND POLYURETHANE COMPOSITIONS MADE THEREFROM 审中-公开来自棕榈油的低聚多元醇和其中的聚氨酯组合物公开(公告)号：US20100261805A1
公开(公告)日：2010-10-14
申请号：US12225650
申请日：2007-03-27
IPC分类号： C08G18/32 , C07C29/151
CPC分类号： C08G18/36 , C08G18/6696 , C08G2101/0008 , C08G2101/0083
摘要： The invention relates to oligomeric polyols that are made from palm-based oils and to polyurethane compositions comprising the oligomeric palm-based polyols. Oligomeric polyols of the invention comprise a ring-opened and oligomerized epoxidized palm-based oil composition comprising about 40% wt. or greater oligomers, a hydroxyl number of about 65 or less, a number average hydroxyl functionality (fn) of about 2.5 or less, and a viscosity at 25° C. of about 4 Pa-s or less.
摘要翻译： 本发明涉及由棕榈油和由低聚棕榈基多元醇组成的聚氨酯组合物制成的低聚多元醇。 本发明的低聚多元醇包含开环和低聚的环氧化棕榈油组合物，其包含约40重量％ 或更大的低聚物，约65或更小的羟值，约2.5或更小的数均羟基官能度（fn）和约25Pa的粘度约4Pa·s以下。
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公开(公告)号：US08338145B2
公开(公告)日：2012-12-25
申请号：US12507008
申请日：2009-07-21
CPC分类号： C07C67/30 , C07C51/347 , C07C51/377 , C07C67/03 , C07C67/08 , C07C67/31 , C07C67/327 , C12P7/42 , C12P7/52 , C07C57/04 , C07C69/675 , C07C69/708 , C07C69/54
摘要： Preparation of derivatives of β-hydroxycarboxylic acid, including β-hydroxycarboxylic acid esters, α,β-unsaturated carboxylic acid, esters of α,β-unsaturated carboxylic acid, and alkoxy derivatives.
摘要翻译： α-羟基羧酸衍生物的制备，包括α-羟基羧酸酯，α，β-不饱和羧酸，α，β-不饱和羧酸的酯和烷氧基衍生物。
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公开(公告)号：US20090298144A1
公开(公告)日：2009-12-03
申请号：US12507008
申请日：2009-07-21
CPC分类号： C07C67/30 , C07C51/347 , C07C51/377 , C07C67/03 , C07C67/08 , C07C67/31 , C07C67/327 , C12P7/42 , C12P7/52 , C07C57/04 , C07C69/675 , C07C69/708 , C07C69/54
摘要： Preparation of derivatives of β-hydroxycarboxylic acid, including β-hydroxycarboxylic acid esters, α,β-unsaturated carboxylic acid, esters of α,β-unsaturated carboxylic acid, and alkoxy derivatives.
摘要翻译： β-羟基羧酸衍生物的制备，包括β-羟基羧酸酯，α，β-不饱和羧酸，α，β-不饱和羧酸和烷氧基衍生物的酯。
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公开(公告)号：US20090264672A1
公开(公告)日：2009-10-22
申请号：US12422096
申请日：2009-04-10
申请人： Timothy W. Abraham , Hiroki Kaido , Choon Woo Lee , Richard L. Pederson , Yann Schrodi , Michael John Tupy
发明人： Timothy W. Abraham , Hiroki Kaido , Choon Woo Lee , Richard L. Pederson , Yann Schrodi , Michael John Tupy
CPC分类号： C07C67/475 , B01J31/2265 , B01J31/2278 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C67/02 , C07C67/303 , C07C67/307 , C07C67/31 , C07C67/333 , C07C2531/22 , C07C2531/24 , C07F7/1884 , C07C11/02 , C07C69/65 , C07C69/734 , C07C69/533 , C07C69/593 , C07C69/73
摘要： Described are methods of making organic compounds by metathesis chemistry. The methods of the invention are particularly useful for making industrially-important organic compounds beginning with starting compositions derived from renewable feedstocks, such as natural oils. The methods make use of a cross-metathesis step with an olefin compound to produce functionalized alkene intermediates having a pre-determined double bond position. Once isolated, the functionalized alkene intermediate can be self-metathesized or cross-metathesized (e.g., with a second functionalized alkene) to produce the desired organic compound or a precursor thereto. The method may be used to make bifunctional organic compounds, such as diacids, diesters, dicarboxylate salts, acid/esters, acid/amines, acid/alcohols, acid/aldehydes, acid/ketones, acid/halides, acid/nitriles, ester/amines, ester/alcohols, ester/aldehydes, ester/ketones, ester/halides, ester/nitriles, and the like.
摘要翻译： 描述的是通过复分解化学制备有机化合物的方法。 本发明的方法特别可用于制备工业上重要的有机化合物，起始于可再生原料如天然油的组合物。 该方法利用与烯烃化合物的交叉复分解步骤来制备具有预定双键位置的官能化烯烃中间体。 一旦分离，官能化的烯烃中间体可以是自我化的或交叉的（例如用第二官能化的烯烃）产生所需的有机化合物或其前体。 该方法可用于制备双官能有机化合物，例如二酸，二酯，二羧酸盐，酸/酯，酸/胺，酸/醇，酸/醛，酸/酮，酸/卤化物，酸/腈，酯/ 胺，酯/醇，酯/醛，酯/酮，酯/卤化物，酯/腈等。
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15.发明申请公开(公告)号：US20090217568A1
公开(公告)日：2009-09-03
申请号：US11795052
申请日：2006-01-10
IPC分类号： C11C5/00
摘要： A wax comprises a metathesis product and/or a product that resembles, at least in part, a product which may be formed from a metathesis reaction. The wax may be used to form articles, for example, candles (container candles, votive candles, and/or a pillar candles), crayons, fire logs, or tarts. The wax commonly includes other components in addition to the metathesis product.
摘要翻译： 蜡包括复分解产物和/或类似于至少部分类似于可由复分解反应形成的产物的产物。 蜡可以用于形成制品，例如蜡烛（容器蜡烛，献色蜡烛和/或支柱蜡烛），蜡笔，火记录或挞。 除了复分解产物之外，蜡通常还包括其它组分。
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16.发明申请公开(公告)号：US20110065821A1
公开(公告)日：2011-03-17
申请号：US12992518
申请日：2009-05-13
CPC分类号： C08G18/36 , C08G18/6696 , C08G18/7621 , C08G2101/00 , C08G2101/0083 , C11C3/006 , C11C3/12
摘要： A method is disclosed for making a polyol comprising: fully-epoxidizing a partially hydrogenated vegetable oil to obtain a fully-epoxidized vegetable oil derivative having an iodine value less than 4 g I2/100 gram, an EOC of from 4.0 to 5.7% and a Gardner color value of 2 or less; and then reacting the fully-epoxidized vegetable oil derivative with a ring opener to form a polyol having a hydroxyl number from 40 to 80 mg KOH/gram, a number average molecular weight of at least 1500 Daltons, a dynamic viscosity less than 10 pascal-seconds, and an EOC below 3.0 wt %.
摘要翻译： 公开了一种制备多元醇的方法，该方法包括：将部分氢化植物油完全环氧化，得到碘值小于4g I2 / 100g，EOC为4.0-5.7％的全环氧化植物油衍生物， 加德纳色值2以下; 然后使全环氧化植物油衍生物与开环剂反应，形成羟值为40〜80mg KOH / g，数均分子量为1500道尔顿，动态粘度小于10帕斯卡 - 秒，EOC低于3.0重量％。
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公开(公告)号：US20100217022A1
公开(公告)日：2010-08-26
申请号：US12226696
申请日：2007-04-27
申请人： Timothy W. Abraham , Jeff Malsam , Xiuguang A. Guo , Milhail Ionescu , Ivan J. Javni , Zoran S. Petrovic
发明人： Timothy W. Abraham , Jeff Malsam , Xiuguang A. Guo , Milhail Ionescu , Ivan J. Javni , Zoran S. Petrovic
IPC分类号： C11C3/00
CPC分类号： C08G18/36 , C08G18/7621 , C08G2101/00
摘要： Enhanced oligomeric polyols are reported. The enhanced oligomeric polyols may be prepared by a method comprising the steps of: (a) providing an oligomeric polyol that comprises at least one glycerol fatty acid ester having at least one glycerol fatty acid ester bond; wherein at least 5% of the ethyldenyl groups (*C═C*) in the glycerol fatty acid ester are substituted with a bonding structure selected from the group consisting of: C—*C—C*—C; O—*C—C*—O; C═*C—C*—C, and mixtures thereof, where * is used to denote the original carbon atoms in the ethylidenyl group; and (b) cleaving at least a portion of the glycerol fatty acid ester bonds to form the enhanced oligomeric polyol. The enhanced oligomeric polyols are useful in making polymers such as polyurethanes.
摘要翻译： 报道了增强低聚多元醇。 增强的低聚多元醇可以通过包括以下步骤的方法制备：（a）提供包含至少一种具有至少一种甘油脂肪酸酯键的甘油脂肪酸酯的低聚多元醇; 其中甘油脂肪酸酯中的至少5％的乙烯基（* C = C *）被选自以下的键合结构取代：C- * C-C * -C; O- * C-C * -O; C≡C-C * -C及其混合物，其中*用于表示亚乙基中的原始碳原子; 和（b）切割甘油脂肪酸酯键的至少一部分以形成增强的低聚多元醇。 增强的低聚多元醇可用于制备聚合物如聚氨酯。
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公开(公告)号：US07960599B2
公开(公告)日：2011-06-14
申请号：US10542167
申请日：2004-01-13
IPC分类号： C07C5/22
CPC分类号： C07C67/333 , C07C6/04 , C07C11/02 , C07C11/167 , C07C51/353 , C07C2531/22 , C07C2531/24 , C11C3/14 , C12P5/026 , C12P7/62 , C12P7/6409 , C12P7/649 , Y02E50/13 , C07C57/03 , C07C69/533
摘要： A process for producing industrially important chemicals from renewable resources is disclosed. This “biobased” process employs readily available, renewable resources comprising fatty acids rather than exploiting fossil sources, such as coal and petroleum. In one embodiment of the process 1-octene, along with methyl-9-decenoate and butadiene, is produced from linoleic acid via an enzymemediated isomerization reaction, followed by a metathesis reaction with ethylene. Linoleic acid can be isolated from vegetable oils, such as soybean oil.
摘要翻译： 公开了从可再生资源生产工业上重要的化学品的过程。 这种“生物基”方法采用包含脂肪酸的易于获得的可再生资源，而不是利用化石源，如煤和石油。 在该方法的一个实施方案中，1-辛烯以及9-癸烯酸甲酯和丁二烯通过酶促异构化反应由亚油酸生产，随后与乙烯进行复分解反应。 亚油酸可以从植物油中分离出来，如大豆油。
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公开(公告)号：US07126034B2
公开(公告)日：2006-10-24
申请号：US10532938
申请日：2003-10-30
IPC分类号： C07C29/136 , C07C29/14 , C07C29/141 , C07C29/143 , C07C29/147 , C07C29/149
CPC分类号： C07C29/149 , C12C11/02 , C07C31/205
摘要： Disclosed is a process for hydrogenating 3-hydroxypropionic acid, or esters thereof, or mixtures of the acid and the ester, in a liquid phase, in the presence of a ruthenium catalyst, alone, or in combination with at least one or more additional metal catalyst wherein the metal is molybdenum, tungsten, titanium, zirconium, niobium, vanadium, chromium, or mixtures of the metals.
摘要翻译： 公开了一种在钌催化剂单独或与至少一种或多种另外的金属组合的情况下在液相中氢化3-羟基丙酸或其酯，或其酸和酯的混合物的方法 催化剂，其中金属是钼，钨，钛，锆，铌，钒，铬或金属的混合物。
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公开(公告)号：US09120742B2
公开(公告)日：2015-09-01
申请号：US12422096
申请日：2009-04-10
申请人： Timothy W. Abraham , Hiroki Kaido , Choon Woo Lee , Richard L. Pederson , Yann Schrodi , Michael John Tupy
发明人： Timothy W. Abraham , Hiroki Kaido , Choon Woo Lee , Richard L. Pederson , Yann Schrodi , Michael John Tupy
IPC分类号： C07C69/52 , C07C57/13 , C07C67/333 , B01J31/22 , C07C6/04 , C07C67/307 , C07C67/31 , C07C67/475
CPC分类号： C07C67/475 , B01J31/2265 , B01J31/2278 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C67/02 , C07C67/303 , C07C67/307 , C07C67/31 , C07C67/333 , C07C2531/22 , C07C2531/24 , C07F7/1884 , C07C11/02 , C07C69/65 , C07C69/734 , C07C69/533 , C07C69/593 , C07C69/73
摘要： Described are methods of making organic compounds by metathesis chemistry. The methods of the invention are particularly useful for making industrially-important organic compounds beginning with starting compositions derived from renewable feedstocks, such as natural oils. The methods make use of a cross-metathesis step with an olefin compound to produce functionalized alkene intermediates having a pre-determined double bond position. Once isolated, the functionalized alkene intermediate can be self-metathesized or cross-metathesized (e.g., with a second functionalized alkene) to produce the desired organic compound or a precursor thereto. The method may be used to make bifunctional organic compounds, such as diacids, diesters, dicarboxylate salts, acid/esters, acid/amines, acid/alcohols, acid/aldehydes, acid/ketones, acid/halides, acid/nitriles, ester/amines, ester/alcohols, ester/aldehydes, ester/ketones, ester/halides, ester/nitriles, and the like.
摘要翻译： 描述的是通过复分解化学制备有机化合物的方法。 本发明的方法特别可用于制备工业上重要的有机化合物，起始于可再生原料如天然油的组合物。 该方法利用与烯烃化合物的交叉复分解步骤来制备具有预定双键位置的官能化烯烃中间体。 一旦分离，官能化的烯烃中间体可以是自我化的或交叉的（例如用第二官能化的烯烃）产生所需的有机化合物或其前体。 酸/酸，酸/酮，酸/卤化物，酸/腈，酯/酯，酸/ 胺，酯/醇，酯/醛，酯/酮，酯/卤化物，酯/腈等。
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