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公开(公告)号：US08338145B2
公开(公告)日：2012-12-25
申请号：US12507008
申请日：2009-07-21
CPC分类号： C07C67/30 , C07C51/347 , C07C51/377 , C07C67/03 , C07C67/08 , C07C67/31 , C07C67/327 , C12P7/42 , C12P7/52 , C07C57/04 , C07C69/675 , C07C69/708 , C07C69/54
摘要： Preparation of derivatives of β-hydroxycarboxylic acid, including β-hydroxycarboxylic acid esters, α,β-unsaturated carboxylic acid, esters of α,β-unsaturated carboxylic acid, and alkoxy derivatives.
摘要翻译： α-羟基羧酸衍生物的制备，包括α-羟基羧酸酯，α，β-不饱和羧酸，α，β-不饱和羧酸的酯和烷氧基衍生物。
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公开(公告)号：US20090298144A1
公开(公告)日：2009-12-03
申请号：US12507008
申请日：2009-07-21
CPC分类号： C07C67/30 , C07C51/347 , C07C51/377 , C07C67/03 , C07C67/08 , C07C67/31 , C07C67/327 , C12P7/42 , C12P7/52 , C07C57/04 , C07C69/675 , C07C69/708 , C07C69/54
摘要： Preparation of derivatives of β-hydroxycarboxylic acid, including β-hydroxycarboxylic acid esters, α,β-unsaturated carboxylic acid, esters of α,β-unsaturated carboxylic acid, and alkoxy derivatives.
摘要翻译： β-羟基羧酸衍生物的制备，包括β-羟基羧酸酯，α，β-不饱和羧酸，α，β-不饱和羧酸和烷氧基衍生物的酯。
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公开(公告)号：US07126034B2
公开(公告)日：2006-10-24
申请号：US10532938
申请日：2003-10-30
IPC分类号： C07C29/136 , C07C29/14 , C07C29/141 , C07C29/143 , C07C29/147 , C07C29/149
CPC分类号： C07C29/149 , C12C11/02 , C07C31/205
摘要： Disclosed is a process for hydrogenating 3-hydroxypropionic acid, or esters thereof, or mixtures of the acid and the ester, in a liquid phase, in the presence of a ruthenium catalyst, alone, or in combination with at least one or more additional metal catalyst wherein the metal is molybdenum, tungsten, titanium, zirconium, niobium, vanadium, chromium, or mixtures of the metals.
摘要翻译： 公开了一种在钌催化剂单独或与至少一种或多种另外的金属组合的情况下在液相中氢化3-羟基丙酸或其酯，或其酸和酯的混合物的方法 催化剂，其中金属是钼，钨，钛，锆，铌，钒，铬或金属的混合物。
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公开(公告)号：US07186856B2
公开(公告)日：2007-03-06
申请号：US10476711
申请日：2002-05-07
IPC分类号： C07C69/66 , C07C69/73 , C07C51/42 , C07C59/245 , C07C59/10
CPC分类号： C07C67/08 , C07C51/02 , C07C59/08 , C07C59/255 , C07C59/06 , C07C59/265 , C07C59/01 , C07C69/675 , C07C69/68 , C07C69/40
摘要： Processes for preparing carboxylic acids and derivatives thereof in which an ammonium salt of the carboxylic acid is heated in the presence of an organic reagent to split the salt and form the acid or, where the organic reagent is an esterifying agent, the corresponding ester. Both the acid and the ester may be dehydrated to form unsaturated counterparts.
摘要翻译： 制备羧酸及其衍生物的方法，其中羧酸铵盐在有机试剂存在下被加热以分离盐并形成酸，或者其中有机试剂是酯化剂时，相应的酯。 酸和酯都可以脱水以形成不饱和的对应物。
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5.发明授权公开(公告)号：US08685118B2
公开(公告)日：2014-04-01
申请号：US11795052
申请日：2006-01-10
摘要： A wax comprises a metathesis product and/or a product that resembles, at least in part, a product which may be formed from a metathesis reaction. The wax may be used to form articles, for example, candles (container candles, votive candles, and/or a pillar candles), crayons, fire logs, or tarts. The wax commonly includes other components in addition to the metathesis product.
摘要翻译： 蜡包括复分解产物和/或类似于至少部分类似于可由复分解反应形成的产物的产物。 蜡可以用于形成制品，例如蜡烛（容器蜡烛，献色蜡烛和/或支柱蜡烛），蜡笔，火记录或挞。 除了复分解产物之外，蜡通常还包括其它组分。
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公开(公告)号：US08440783B2
公开(公告)日：2013-05-14
申请号：US12226696
申请日：2007-04-27
申请人： Timothy W. Abraham , Jeff Malsam , Xiuguang A. Guo , Milhail Ionescu , Ivan J. Javni , Zoran S. Petrovic
发明人： Timothy W. Abraham , Jeff Malsam , Xiuguang A. Guo , Milhail Ionescu , Ivan J. Javni , Zoran S. Petrovic
IPC分类号： C08G69/28
CPC分类号： C08G18/36 , C08G18/7621 , C08G2101/00
摘要： Enhanced oligomeric polyols are reported. The enhanced oligomeric polyols may be prepared by a method comprising the steps of: (a) providing an oligomeric polyol that comprises at least one glycerol fatty acid ester having at least one glycerol fatty acid ester bond; wherein at least 5% of the ethyldenyl groups (*C═C*) in the glycerol fatty acid ester are substituted with a bonding structure selected from the group consisting of: C-*C—C*-C; O-*C—C*-O; C=*C—C*-C, and mixtures thereof, where * is used to denote the original carbon atoms in the ethylidenyl group; and (b) cleaving at least a portion of the glycerol fatty acid ester bonds to form the enhanced oligomeric polyol. The enhanced oligomeric polyols are useful in making polymers such as polyurethanes.
摘要翻译： 报道了增强低聚多元醇。 增强的低聚多元醇可以通过包括以下步骤的方法制备：（a）提供包含至少一种具有至少一种甘油脂肪酸酯键的甘油脂肪酸酯的低聚多元醇; 其中所述甘油脂肪酸酯中的至少5％的乙烯基（* C = C *）被选自以下的键合结构取代：C- * C-C * -C; O- * C-C * -O; C = * C-C * -C及其混合物，其中*用于表示亚乙基中的原始碳原子; 和（b）切割甘油脂肪酸酯键的至少一部分以形成增强的低聚多元醇。 增强的低聚多元醇可用于制备聚合物如聚氨酯。
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7.发明申请OLIGOMERIC POLYOLS FROM PALM-BASED OILS AND POLYURETHANE COMPOSITIONS MADE THEREFROM 审中-公开来自棕榈油的低聚多元醇和其中的聚氨酯组合物公开(公告)号：US20100261805A1
公开(公告)日：2010-10-14
申请号：US12225650
申请日：2007-03-27
IPC分类号： C08G18/32 , C07C29/151
CPC分类号： C08G18/36 , C08G18/6696 , C08G2101/0008 , C08G2101/0083
摘要： The invention relates to oligomeric polyols that are made from palm-based oils and to polyurethane compositions comprising the oligomeric palm-based polyols. Oligomeric polyols of the invention comprise a ring-opened and oligomerized epoxidized palm-based oil composition comprising about 40% wt. or greater oligomers, a hydroxyl number of about 65 or less, a number average hydroxyl functionality (fn) of about 2.5 or less, and a viscosity at 25° C. of about 4 Pa-s or less.
摘要翻译： 本发明涉及由棕榈油和由低聚棕榈基多元醇组成的聚氨酯组合物制成的低聚多元醇。 本发明的低聚多元醇包含开环和低聚的环氧化棕榈油组合物，其包含约40重量％ 或更大的低聚物，约65或更小的羟值，约2.5或更小的数均羟基官能度（fn）和约25Pa的粘度约4Pa·s以下。
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公开(公告)号：US08206955B2
公开(公告)日：2012-06-26
申请号：US10969245
申请日：2004-10-21
申请人： Sara C. McFarlan , Paula M. Hicks , Mary Jo Zidwick , Fernando A. Sanchez-Riera , Douglas C. Cameron , Mervyn L. deSouza , John Rosazza , Steven J. Gort , Timothy W. Abraham
发明人： Sara C. McFarlan , Paula M. Hicks , Mary Jo Zidwick , Fernando A. Sanchez-Riera , Douglas C. Cameron , Mervyn L. deSouza , John Rosazza , Steven J. Gort , Timothy W. Abraham
CPC分类号： C12N9/88 , C12P17/10 , Y02P20/582
摘要： Methods and compositions that can be used to make monatin or salt thereof from glucose, tryptophan, indole-3-lactic acid, indole-3-pyruvate, and 2-hydroxy 2-(indol-3-ylmethyl)-4-keto glutaric acid, are provided. Methods are also disclosed for producing the indole-3-pyruvate and 2-hydroxy 2-(indol-3-ylmethyl)-4-keto glutaric acid intermediates. Compositions provided include nucleic acid molecules, polypeptides, chemical structures, and cells. Methods include in vitro and in vivo processes, and the in vitro methods include chemical reactions.
摘要翻译： 可用于从葡萄糖，色氨酸，吲哚-3-乳酸，吲哚-3-丙酮酸和2-羟基2-（吲哚-3-基甲基）-4-酮戊二酸制备莫纳甜或其盐的方法和组合物 ，提供。 还公开了制备吲哚-3-丙酮酸和2-羟基2-（吲哚-3-基甲基）-4-酮戊二酸中间体的方法。 提供的组合物包括核酸分子，多肽，化学结构和细胞。 方法包括体外和体内过程，体外方法包括化学反应。
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公开(公告)号：US20090264672A1
公开(公告)日：2009-10-22
申请号：US12422096
申请日：2009-04-10
申请人： Timothy W. Abraham , Hiroki Kaido , Choon Woo Lee , Richard L. Pederson , Yann Schrodi , Michael John Tupy
发明人： Timothy W. Abraham , Hiroki Kaido , Choon Woo Lee , Richard L. Pederson , Yann Schrodi , Michael John Tupy
CPC分类号： C07C67/475 , B01J31/2265 , B01J31/2278 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C67/02 , C07C67/303 , C07C67/307 , C07C67/31 , C07C67/333 , C07C2531/22 , C07C2531/24 , C07F7/1884 , C07C11/02 , C07C69/65 , C07C69/734 , C07C69/533 , C07C69/593 , C07C69/73
摘要： Described are methods of making organic compounds by metathesis chemistry. The methods of the invention are particularly useful for making industrially-important organic compounds beginning with starting compositions derived from renewable feedstocks, such as natural oils. The methods make use of a cross-metathesis step with an olefin compound to produce functionalized alkene intermediates having a pre-determined double bond position. Once isolated, the functionalized alkene intermediate can be self-metathesized or cross-metathesized (e.g., with a second functionalized alkene) to produce the desired organic compound or a precursor thereto. The method may be used to make bifunctional organic compounds, such as diacids, diesters, dicarboxylate salts, acid/esters, acid/amines, acid/alcohols, acid/aldehydes, acid/ketones, acid/halides, acid/nitriles, ester/amines, ester/alcohols, ester/aldehydes, ester/ketones, ester/halides, ester/nitriles, and the like.
摘要翻译： 描述的是通过复分解化学制备有机化合物的方法。 本发明的方法特别可用于制备工业上重要的有机化合物，起始于可再生原料如天然油的组合物。 该方法利用与烯烃化合物的交叉复分解步骤来制备具有预定双键位置的官能化烯烃中间体。 一旦分离，官能化的烯烃中间体可以是自我化的或交叉的（例如用第二官能化的烯烃）产生所需的有机化合物或其前体。 该方法可用于制备双官能有机化合物，例如二酸，二酯，二羧酸盐，酸/酯，酸/胺，酸/醇，酸/醛，酸/酮，酸/卤化物，酸/腈，酯/ 胺，酯/醇，酯/醛，酯/酮，酯/卤化物，酯/腈等。
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10.发明申请公开(公告)号：US20090217568A1
公开(公告)日：2009-09-03
申请号：US11795052
申请日：2006-01-10
IPC分类号： C11C5/00
摘要： A wax comprises a metathesis product and/or a product that resembles, at least in part, a product which may be formed from a metathesis reaction. The wax may be used to form articles, for example, candles (container candles, votive candles, and/or a pillar candles), crayons, fire logs, or tarts. The wax commonly includes other components in addition to the metathesis product.
摘要翻译： 蜡包括复分解产物和/或类似于至少部分类似于可由复分解反应形成的产物的产物。 蜡可以用于形成制品，例如蜡烛（容器蜡烛，献色蜡烛和/或支柱蜡烛），蜡笔，火记录或挞。 除了复分解产物之外，蜡通常还包括其它组分。
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