公开(公告)号：US5719205A

公开(公告)日：1998-02-17

申请号：US372665

申请日：1995-01-13

Applicant: Toshio Yoshihara

Inventor： Toshio Yoshihara

IPC: G02B1/11 ,  B05D5/06 ,  B05D7/24 ,  C08F8/42 ,  C09D5/00 ,  C09D5/02 ,  C09D133/06 ,  C09D183/00 ,  C09D183/02 ,  C09D185/00 ,  C09D201/02 ,  G02B1/111 ,  G02B1/14 ,  C08K9/00

CPC classification number: C08F8/42 ,  C09D133/066

Abstract: Synthetic resin particles having a hydrogen bond forming group are swollen, at least one metallic compound capable of forming a hydrogen bond is introduced into the synthetic resin particles, and the metallic compound is hydrolyzed and condensed within the synthetic resin particles and on and in the vicinity of the surface of the synthetic resin particles. An inorganic component is grown by this reaction, and at least part of the grown inorganic component 3 is fixed through a reaction with a hydrogen bond forming group present within the synthetic resin particles 1 and on and in the vicinity of the surface of the synthetic resin particles 1 to prepare a coating composition. The coating composition is coated on the surface of a substrate, and the resulting coating is dried at a temperature of the lowest film forming temperature or above to form a coating.

Abstract translation: 具有氢键形成基团的合成树脂颗粒溶胀，至少一种能够形成氢键的金属化合物被引入合成树脂颗粒中，并且金属化合物在合成树脂颗粒内和附近水解和缩合 的合成树脂颗粒的表面。 通过该反应生长无机成分，将生长的无机成分3的至少一部分与合成树脂粒子1内存在的氢键形成基团和合成树脂的表面附近反应而固定 颗粒1以制备涂料组合物。 将涂料组合物涂布在基材的表面上，将得到的涂料在最低成膜温度以上的温度下干燥，形成涂膜。

公开(公告)号：US4791054A

公开(公告)日：1988-12-13

申请号：US939236

申请日：1986-12-08

Applicant: Eiichi Hamada ,  Toshio Yoshihara ,  Atushi Nakashima ,  Jun Kamo

Inventor： Eiichi Hamada ,  Toshio Yoshihara ,  Atushi Nakashima ,  Jun Kamo

IPC: A61M1/16 ,  B01D63/02 ,  F28F21/06 ,  A61M1/14

CPC classification number: F28F21/062 ,  A61M1/1625 ,  A61M1/1627 ,  A61M1/1629 ,  A61M1/1698 ,  B01D63/02 ,  B01D63/024 ,  B01D2313/38 ,  Y10S128/03

Abstract: The present invention provides a heat exchanger using hollow fibers formed of an organic polymer as the heat transfer tubes; a blood oxygenating device comprising a blood oxygenator combined with the aforesaid heat exchanger; and a small-sized and lightweight blood oxygenator which comprises a blood oxygenator of the hollow-fiber membrane type having the aforesaid heat exchanger incorporated thereinto to form an integral unit, and hence has excellent gas exchange and heat exchange performance.

Abstract translation: 本发明提供一种使用由有机聚合物形成的中空纤维作为传热管的热交换器; 一种血液充氧装置，包括与上述热交换器组合的血液充氧器; 以及包含具有上述热交换器的中空纤维膜类型的血液充氧器以形成整体单元的小型轻型血液充氧器，因此具有优异的气体交换和热交换性能。

公开(公告)号：US4636908A

公开(公告)日：1987-01-13

申请号：US662295

申请日：1984-10-01

Applicant: Toshio Yoshihara ,  Ichiro Kikuchi

Inventor： Toshio Yoshihara ,  Ichiro Kikuchi

IPC: H01G4/12 ,  H01L41/187 ,  H01G4/10 ,  C04B35/46

CPC classification number: H01L41/187 ,  H01G4/1236 ,  H01G4/1263

Abstract: A thin-film dielectric comprising a conductive substrate having formed thereon a thin layer of lead titanate (PT), lead titanate zirconate (PZT), third components type lead titanate zirconate prepared by adding an ingredient represented by the formula Pb(M'.sub.1/3 M".sub.2/3)O.sub.3 (wherein M' represents a divalent transition metal, and M" represents Ta or Nb), as a third component to lead titanate zirconate (PZT) to form a solid solution, or lanthanum-containing lead titanate zirconate (PLZT). The total film thickness of the dielectric composition is 0.1 to 100 .mu.m.The thin-film dielectric is produced by coating the substrate with an organic solvent solution of .beta.-diketone or the like as a precursor for said dielectric in a uniform thickness, prebaking at a temperature higher than the decomposition temperature of the organic component contained in the coating thin-film of precursor and lower than the crystallization temperature of the dielectric in an oxygen-containing stream, repeating the coating-prebaking procedure, and then fully baking at a temperature higher than the crystallization temperature of the dielectric composition; or repeating the coating with the precursor solution and the full baking procedure.

Abstract translation: PCT No.PCT / JP84 / 00027 Sec。 371日期1984年10月1日 102（e）日期1984年10月1日PCT提交1984年1月31日PCT公布。 出版物WO84 / 03003 日本1984年8月2日。一种薄膜电介质，包括其上形成有钛酸铅（PT）的薄层，锆钛酸铅（PZT），第三组分型钛酸铅锆酸盐的导电基材，其通过将由 作为用于形成固体的钛酸锆酸盐（PZT）的第三成分，通式Pb（M'1 / 3M'2 / 3）O3（其中M'表示二价过渡金属，M“表示Ta或Nb） 溶液或含镧钛酸铅锆酸盐（PLZT）。 电介质组合物的总膜厚为0.1〜100μm。 该薄膜电介质是通过用β-二酮等的有机溶剂溶液作为均匀厚度的所述电介质的前体涂布基板来制备的，在高于所述电介质中所含有机组分的分解温度的温度下预烘烤 在含氧流中涂覆前体的薄膜并低于电介质的结晶温度，重复涂布预烘烤程序，然后在高于电介质组合物的结晶温度的温度下完全烘烤; 或者用前体溶液重复涂覆和完全烘烤过程。

公开(公告)号：US4188690A

公开(公告)日：1980-02-19

申请号：US945471

申请日：1978-09-25

Applicant: Seigi Suzuki ,  Toshio Yoshihara ,  Masayoshi Fujizaki, deceased

Inventor： Seigi Suzuki ,  Toshio Yoshihara ,  Masayoshi Fujizaki, deceased

IPC: D04H1/46 ,  D04H1/06

CPC classification number: D04H1/49

Abstract: A nonwoven fabric having no pattern and composed of 100% synthetic fibers, wherein individual fibers are held together by three-dimensional entanglement into a stabilized sheet form without being subjected to any bonding treatment, which nonwoven fabric has a structure characterized by a specific volume of the nonwoven fabric of 3.5 cm.sup.3 /g or less, a bending index (in terms of R) of individual fibers of 4.0 or more, and a strength efficiency (in terms of S) of the nonwoven fabric of 90% or more. Such a nonwoven fabric has excellent properties which are comparable to conventional woven fabrics in not only hand but also practical performance characteristics. This nonwoven fabric is manufactured by a method which comprises placing on a substantially smooth supporting member a web, 35 to 170 gm/m.sup.2 in basis weight, composed of highly shrinkable synthetic fibers having a potential heat shrinkage of 50% or more, exposing said web to the impact of fine jet streams of water discharged under a pressure of 10 to 35 kg/cm.sup.2, whereby allowing individual fibers to entangle one another, thereafter subjecting the web to wet heat treatment at free length conditions to allow the web to shrink by 50% or more in area, drying the shrunk web at a temperature at which no change takes place in the shape and internal structure of individual fibers, and then subjecting the dried web to heat setting under an applied pressure of 200 g/cm.sup.2 or more.

Abstract translation: 一种无图案的无纺织物，由100％的合成纤维组成，其中单个纤维通过三维缠结保持在稳定的片状而不进行任何粘合处理，该无纺织物的特征在于体积比 3.5cm 3 / g以下的无纺布，单纤维的弯曲指数（以R计）为4.0以上，无纺布的强度效率（以S计）为90％以上。 这种非织造布具有优异的性能，与传统的机织织物相比，不仅手工而且具有实用的性能特性。 该非织造织物通过以下方法制造：将基本平滑的支撑构件放置在基重为35〜170gm / m 2的纤维网上，所述幅材由潜热收缩率为50％以上的高收缩性合成纤维构成， 对于在10〜35kg / cm 2的压力下排出的细水喷射流的影响，由此允许单个纤维彼此缠结，然后在自由长度条件下对幅材进行湿热处理，以使幅材收缩50 ％以上的面积，在单个纤维的形状和内部结构不发生变化的温度下干燥收缩纤维网，然后在200g / cm 2以上的施加压力下使干燥的纸幅进行热定型。

公开(公告)号：US4172172A

公开(公告)日：1979-10-23

申请号：US771803

申请日：1977-02-24

Applicant: Seigi Suzuki ,  Toshio Yoshihara ,  Masayoshi Fujizaki, deceased

Inventor： Seigi Suzuki ,  Toshio Yoshihara ,  Masayoshi Fujizaki, deceased

IPC: D04H1/46 ,  D04H1/492 ,  D04H13/00

CPC classification number: D04H1/492 ,  Y10T428/26 ,  Y10T428/2922 ,  Y10T442/635

Abstract: A nonwoven fabric having no pattern and composed of 100% synthetic fibers, wherein individual fibers are held together by three-dimensional entanglement into a stabilized sheet form without being subjected to any bonding treatment, which nonwoven fabric has a structure characterized by a specific volume of the nonwoven fabric of 3.5 cm.sup.3 /g or less, a bending index (in terms of R) of individual fibers of 4.0 or more, and a strength efficiency (in terms of S) of the nonwoven fabric of 90% or more. Such a nonwoven fabric has excellent properties which are comparable to conventional woven fabrics in not only hand but also practical performance characteristics. This nonwoven fabric is manufactured by a method which comprises placing on a substantially smooth supporting member a web, 35 to 170 g/m.sup.2 in basis weight, composed of highly shrinkable synthetic fibers having a potential heat shrinkage of 50% or more, exposing said web to the impact of fine jet streams of water discharged under a pressure of 10 to 35 kg/cm.sup.2, whereby allowing individual fibers to entangle one another, thereafter subjecting the web to wet heat treatment at free length conditions to allow the web to shrink by 50% or more in area, drying the shrunk web at a temperature at which no change takes place in the shape and internal structure of individual fibers, and then subjecting the dried web to heat setting under an applied pressure of 200 g/cm.sup.2 or more.

Abstract translation: 一种无图案的无纺织物，由100％的合成纤维组成，其中单个纤维通过三维缠结保持在稳定的片状而不进行任何粘合处理，该无纺织物的特征在于体积比 3.5cm 3 / g以下的无纺布，单纤维的弯曲指数（以R计）为4.0以上，无纺布的强度效率（以S计）为90％以上。 这种非织造布具有优异的性能，与传统的机织织物相比，不仅手工而且具有实用的性能特性。 该无纺织物通过以下方法制造：将基本平滑的支撑构件放置在基重为35〜170g / m 2的纤维网上，所述纤维网由具有50％以上的潜热收缩率的高收缩性合成纤维构成， 对于在10〜35kg / cm 2的压力下排出的细水喷射流的影响，由此允许单个纤维彼此缠结，然后在自由长度条件下对幅材进行湿热处理，以使幅材收缩50 ％以上的面积，在单个纤维的形状和内部结构不发生变化的温度下干燥收缩纤维网，然后在200g / cm 2以上的施加压力下使干燥的纸幅进行热定型。

公开(公告)号：US3968306A

公开(公告)日：1976-07-06

申请号：US380560

申请日：1973-07-19

Applicant: Toshio Yoshihara ,  Keisuke Yoshihara ,  Tuneo Ikeda ,  Yasuyuki Yamasaki ,  Akira Oshima ,  Naoyuki Fukabori

Inventor： Toshio Yoshihara ,  Keisuke Yoshihara ,  Tuneo Ikeda ,  Yasuyuki Yamasaki ,  Akira Oshima ,  Naoyuki Fukabori

IPC: B05D7/24 ,  C08F2/00 ,  C08J7/04 ,  C08J7/12 ,  B32B27/06 ,  B32B27/36

CPC classification number: C08J7/047 ,  C08J2433/00 ,  Y10S524/911 ,  Y10T428/265 ,  Y10T428/31511 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/3192 ,  Y10T428/31928 ,  Y10T428/31935 ,  Y10T428/31938

Abstract: A plastic article having improved surface characteristics comprises a plastic body having adhered thereon a cross-linked film of a composition comprising (A) 10 to 90 parts by weight of a cross-linking unsaturated compound having a molecular weight of M and containing in the molecule N polymerizable ethylenically unsaturated radicals (N being an integer of 2 or more), the ratio of said molecular weight, M, to said number, N, of ethylenically unsaturated radicals (M/N) being about 49 to about 600, (B) 90 to 10 parts by weight of an unsaturated monomer containing in the molecule at least one radical copolymerizable with said component (A) and at least one acid radical, and (C) up to 20 parts by weight of other copolymerizable unsaturated compounds, the total of (A), (B) and (C) being 100 parts by weight, at least a part of the acid radicals contained in the film having been converted into alkali salts thereof, said cross-linked film having a thickness of 5 to 500 .mu.. The above plastic article is produced by forming on the surface of a plastic body a cross-linked film of the composition comprising the components (A), (B) and (C) and then treating the cross-linked film with a base to convert the acid radical into its alkali salt.

Abstract translation: 具有改善的表面特性的塑料制品包括粘附有组合物的交联膜的塑料体，所述组合物包含（A）10至90重量份的分子量为M且在分子中含有的交联不饱和化合物 N可聚合烯键式不饱和基团（N为2以上的整数），所述分子量M与烯键式不饱和基团（M / N）的数目N的比例为约49〜约600，（B） 90〜10重量份在分子中含有至少一个可与所述组分（A）和至少一个酸基共聚的自由基的不饱和单体，和（C）至多20重量份的其它可共聚的不饱和化合物， （A），（B）和（C）为100重量份，所述膜中所含的酸基的至少一部分已转化为碱金属盐，所述交联膜的厚度为5〜500 亩 上述塑料制品通过在塑料体的表面上形成包含组分（A），（B）和（C）的组合物的交联膜，然后用碱处理交联膜来转化 将酸根转变为其碱性盐。

公开(公告)号：US08597780B2

公开(公告)日：2013-12-03

申请号：US12672556

申请日：2008-08-08

Applicant: Emi Shimano ,  Toshio Yoshihara

Inventor： Emi Shimano ,  Toshio Yoshihara

IPC: B32B5/16

CPC classification number: G02B1/14 ,  C09D5/006 ,  C09D7/62 ,  G02B1/105 ,  Y10T428/2438 ,  Y10T428/25 ,  Y10T428/256

Abstract: A hard coat film excellent in abrasion resistance and saponification resistance. A hard coat layer includes a cured product of a curable resin composition containing a reactive inorganic fine particle having an average particle diameter of 5 nm to 30 nm, and has a skin layer, wherein the reactive inorganic fine particles are localized, in its surface region being an interface and its vicinity on a side opposite to a transparent substrate film side of the hard coat layer. Alternatively, the reactive inorganic fine particle has an average particle diameter of 30 nm to 100 nm, and has density distribution in a thickness direction of the hard coat layer lowest at an interface on a side opposite to a transparent substrate film side of the hard coat layer while the density is highest at an interface and its vicinity on the transparent substrate film side of the hard coat layer.

Abstract translation: 耐磨损性和耐皂化性优异的硬涂膜。 硬涂层包括含有平均粒径为5nm〜30nm的反应性无机细颗粒的固化性树脂组合物的固化物，并且在其表面区域具有表面层，其中反应性无机微粒定位 作为与硬涂层的透明基板膜侧相反的一侧的界面及其附近。 或者，反应性无机微粒的平均粒径为30nm〜100nm，并且在硬涂层的与硬涂层的透明基底膜侧相反的一侧的界面处的硬涂层的厚度方向上的密度分布 层，同时在硬涂层的透明基板膜侧的界面及其附近的密度最高。

公开(公告)号：US08512801B2

公开(公告)日：2013-08-20

申请号：US13177676

申请日：2011-07-07

Applicant: Toshio Yoshihara ,  Tomoyuki Horio

Inventor： Toshio Yoshihara ,  Tomoyuki Horio

IPC: B05D5/06

CPC classification number: G02B1/111 ,  Y10T428/249971 ,  Y10T428/26 ,  Y10T428/31504 ,  Y10T428/31663

Abstract: There are provided an antireflection film for use primarily in displays such as LCDs, which exhibits both antifouling properties and mar-proofness, as well as a process for its production, the antireflection film comprising at least one functional layer and a low refractive index layer laminated in that order on a transparent base material, wherein the at least one functional layer contains leveling agent A in contact with the low refractive index layer, the low refractive index layer containing in addition to leveling agent B, the leveling agent A that has migrated from the at least one functional layer, further wherein the migrated leveling agent A and leveling agent B are uniformly distributed at the surface of the low refractive index layer, and the process for its production including: coating a functional layer-forming composition containing leveling agent A onto a transparent base material or a functional layer preformed thereover; half-curing it to form a functional layer in contact with the low refractive index layer; further coating the half-cured functional layer with a low refractive index layer-forming composition containing leveling agent B; and then completing the curing to form a low refractive index layer, whereby the leveling agent A migrates into the surface of the low refractive index layer, resulting in uniform distribution of the leveling agent A and leveling agent B at the surface of the low refractive index layer.

Abstract translation: 提供了主要用于显示器，例如具有防污性和防污性的LCD的防反射膜及其制造方法，该抗反射膜包括至少一个功能层和低折射率层层压 其中所述至少一个功能层包含与所述低折射率层接触的流平剂A，所述低折射率层除了流平剂B以外还含有所述流平剂A，所述流平剂A从所述透明基材 所述至少一个功能层，其中所述迁移的流平剂A和流平剂B均匀分布在所述低折射率层的表面，并且其生产方法包括：涂覆含有流平剂A的功能层形成组合物 在其上预先形成的透明基材或功能层上; 半固化以形成与低折射率层接触的功能层; 用含有流平剂B的低折射率层形成组合物进一步涂覆半固化的功能层; 然后完成固化以形成低折射率层，由此流平剂A迁移到低折射率层的表面，导致流平剂A和流平剂B在低折射率表面上的均匀分布 层。

公开(公告)号：US20130122311A1

公开(公告)日：2013-05-16

申请号：US13697428

申请日：2011-05-12

Applicant: Toshio Yoshihara ,  Tomoyuki Horio ,  Mayu Youki

Inventor： Toshio Yoshihara ,  Tomoyuki Horio ,  Mayu Youki

IPC: C09D133/10 ,  G02B1/08 ,  G02B1/04

CPC classification number: C09D133/10 ,  C08F290/067 ,  C08G18/672 ,  C08L33/14 ,  C09D4/06 ,  C09D133/14 ,  C09D175/16 ,  G02B1/04 ,  G02B1/08 ,  G02B1/105 ,  G02B1/14 ,  G02B1/16 ,  Y10T428/31591 ,  Y10T428/31786 ,  Y10T428/31891 ,  Y10T428/31935 ,  Y10T428/31971 ,  C08L75/14

Abstract: The present invention provides an optical layered body having excellent antistatic properties, optical characteristics, hardness, adhesion, and interference fringe prevention performance, which can be produced at a low cost.An optical layered body having a hard coat layer provided on a triacetylcellulose substrate, wherein a resin composition used for forming the hard coat layer contains a quaternary ammonium salt-containing polymer, a binder resin, and a solvent; the quaternary ammonium salt-containing polymer has a higher hydrophilicity than the binder resin; and the binder resin contains two or more resin components having different hydrophilicities.

Abstract translation: 本发明提供一种能够以低成本制造的抗静电性，光学特性，硬度，粘合性和干涉条纹防止性能优异的光学层叠体。 一种光学层叠体，其具有设置在三乙酰纤维素基材上的硬涂层，其中用于形成所述硬涂层的树脂组合物含有含季铵盐的聚合物，粘合剂树脂和溶剂; 所述含季铵盐的聚合物具有比粘合剂树脂更高的亲水性; 粘合剂树脂含有两种以上具有不同亲水性的树脂成分。

公开(公告)号：US08080309B2

公开(公告)日：2011-12-20

申请号：US10591888

申请日：2005-03-03

Applicant: Seiji Shinohara ,  Takahiro Niimi ,  Toshio Yoshihara

Inventor： Seiji Shinohara ,  Takahiro Niimi ,  Toshio Yoshihara

IPC: B32B7/02

CPC classification number: G02B1/111 ,  C01G23/002 ,  C01G23/047 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2006/60 ,  C03C17/34 ,  C03C17/42 ,  C03C2217/445 ,  C03C2217/477 ,  C03C2217/732 ,  C04B35/62805 ,  C04B35/62813 ,  C04B2235/3232 ,  C04B2235/3275 ,  C04B2235/3284 ,  C04B2235/449 ,  C08K3/22 ,  C08K9/02 ,  C09C1/0084 ,  C09C1/3653 ,  C09C1/3661 ,  C09C1/3669 ,  C09D7/62 ,  C09D7/67 ,  G02F1/133345 ,  G02F1/133502 ,  Y10T428/24942 ,  Y10T428/256 ,  Y10T428/2933 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2995 ,  Y10T428/2998

Abstract: A coating composition forms a coating film having an eliminated or reduced photocatalytic action-derived deterioration, and forms a coating film having a lowered haze value, excellent dispersibility and dispersion stability in a coating liquid form, excellent storage stability, and also excellent coatability. The coating composition includes at least the following four components: titanium dioxide fine particles with eliminated or reduced photocatalytic activity which is obtained by surface treating titanium dioxide fine particles doped with cobalt capable of capturing free electrons and/or holes, with a zinc chelate compound capable of capturing free electrons and/or holes; a binder component; a dispersant; and an organic solvent.

Abstract translation: 涂料组合物形成具有消除或降低的光催化作用导致的劣化的涂膜，并且形成具有降低的雾度值，优异的涂布液形式的分散性和分散稳定性，优异的储存稳定性和优异的涂布性的涂膜。 涂料组合物至少包括以下四种组分：具有消除或降低的光催化活性的二氧化钛细颗粒，其通过用能够捕获游离电子和/或空穴的钴表面处理二氧化钛细颗粒与具有锌螯合物的能力而获得 捕获自由电子和/或孔; 粘合剂成分; 分散剂; 和有机溶剂。