公开(公告)号：US06828380B2

公开(公告)日：2004-12-07

申请号：US10220707

申请日：2002-11-21

申请人： Liqing-Lee Sun ,  Eckhard Wenz ,  Herbert Eichenauer ,  Stefan Moss ,  Heinrich Alberts ,  Hans-Bernhard Hauertmann ,  Karl Zabrocki ,  Hans-Erich Gasche ,  Ulrich Jansen

发明人： Liqing-Lee Sun ,  Eckhard Wenz ,  Herbert Eichenauer ,  Stefan Moss ,  Heinrich Alberts ,  Hans-Bernhard Hauertmann ,  Karl Zabrocki ,  Hans-Erich Gasche ,  Ulrich Jansen

IPC分类号： C08L5502

CPC分类号： C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08L55/02 ,  C08L2666/14 ,  C08L2666/02

摘要： A molding composition having good surface gloss, high elongation at break and good thermoplastic processability is disclosed. The composition contains (A) a graft polymer that is obtained by free-radical polymerization of resin-forming vinyl monomers in the presence of rubber in latex form, (B) a copolymer of styrene and acrylonitrile and an optional (C) a resin selected from the group consisting of polycarbonates, polyester-carbonates, polyesters and polyamides. The preparation of the graft polymer is characterized in that (i) before the start of the grafting polymerization reaction the rubber latex is brought to a pH of 9 to 11, (ii) the redox initiator components are employed in amounts of 0.1 to 2.5 wt. % (based on the monomers metered in) and (iii) during the entire grafting polymerization reaction the pH remains constant±0.5 and in the range of 11.0 to 8.8, and (iv) the temperature difference between the start and end of the reaction is at least 10° C.

摘要翻译： 公开了具有良好的表面光泽度，高断裂伸长率和良好的热塑性加工性能的成型组合物。 该组合物含有（A）通过在胶乳形式的橡胶存在下形成树脂的乙烯基单体的自由基聚合获得的接枝聚合物，（B）苯乙烯和丙烯腈的共聚物和任选的（C）树脂选择 由聚碳酸酯，聚酯 - 碳酸酯，聚酯和聚酰胺组成。 接枝聚合物的制备的特征在于：（i）在接枝聚合反应开始之前，使橡胶胶乳的pH值达到9至11，（ii）氧化还原引发剂组分的用量为0.1至2.5重量％ 。 ％（基于计量的单体）和（iii）在整个接枝聚合反应期间，pH保持恒定±0.5且在11.0至8.8的范围内，和（iv）反应开始和结束之间的温度差为 至少10℃

公开(公告)号：US06620883B2

公开(公告)日：2003-09-16

申请号：US09965702

申请日：2001-09-26

申请人： Hans-Erich Gasche ,  Herbert Eichenauer ,  Pierre Vanhoorne ,  Ulrich Jansen ,  Eckhard Wenz ,  Stefan Moss

发明人： Hans-Erich Gasche ,  Herbert Eichenauer ,  Pierre Vanhoorne ,  Ulrich Jansen ,  Eckhard Wenz ,  Stefan Moss

IPC分类号： C08L5104

CPC分类号： C08L51/04 ,  C08F279/04 ,  C08L55/02 ,  C08L2666/02

摘要： The invention relates to a process for the preparation of graft rubber polymers of the ABS type by emulsion polymerization according to the so-called fed batch process, in which latexes having markedly reduced residual monomer contents are obtained, and to compositions containing the mentioned graft rubber polymers. The polymers so obtained have no negative effects at all on other properties

公开(公告)号：US06569951B2

公开(公告)日：2003-05-27

申请号：US09967311

申请日：2001-09-28

申请人： Herbert Eichenauer ,  Hans-Erich Gasche ,  Ulrich Jansen

发明人： Herbert Eichenauer ,  Hans-Erich Gasche ,  Ulrich Jansen

IPC分类号： C08F27904

CPC分类号： C08L55/02 ,  C08F279/02 ,  C08F279/04 ,  C08L51/04 ,  C08L2666/14 ,  C08L2666/02

摘要： An elastic-thermoplastic graft polymer prepared by a multi-stage free radical polymerization is described. The elastic-thermoplastic graft polymer is prepared by polymerizing (i) one or more monomers containing vinyl groups, and (ii) at least one molecular weight regulating compound, in the presence of (iii) at least one rubber in latex form. The ratio of monomers (M) to the molecular weight regulating compound (MWR) is altered throughout the various stages of the polymerization method. The M:MWR ratio is: from 50:1 to 400:1 in the first stage; from 100:1 to 800:1 in the second stage; and from 200:1 to 2000:1 in the third stage of the polymerization. In at least one further reaction stage of the polymerization, the monomers, in the absence of the molecular weight regulating compound, are polymerized in the presence of the rubber. This further reaction stage occurs before the first stage and/or after the third stage of the polymerization. The multi-stage polymerization is conducted such that: M:MWR (first stage)≦M:MWR (second stage)

公开(公告)号：US5800527A

公开(公告)日：1998-09-01

申请号：US367298

申请日：1996-01-06

申请人： Josef Jansen ,  Ulrich Jansen

发明人： Josef Jansen ,  Ulrich Jansen

IPC分类号： A61F2/24

CPC分类号： A61F2/2412 ,  A61F2/2409 ,  A61F2/2418 ,  A61F2250/0036 ,  Y10S623/90

摘要： A support housing (1) for valve and closure members, in particular for heart valve prostheses, has a base ring (2) which carries at least two symmetrically offset posts (4/5) substantially oriented in the direction of the ring axis and linked together by curved strips (3) for securing at least two flexible webs (6/7). In order to produce with such a support housing a valve or closure member, in particular a heart valve prosthesis, which operates reliably even with different closing pressure differentials, i.e. in particular even under varying physiological stress conditions, the stent (1) is only retained in sections and with limited flexibility. For that purpose the free ends (4) of the posts have a rigid form, and/or the bases of the posts have a flexibility limited by stops, and/or the strips (3) have a flexibility limited by stops.

摘要翻译： PCT No.PCT / EP93 / 01794 Sec。 371日期1996年1月6日 102（e）日期1996年1月6日PCT提交1993年7月9日PCT公布。 公开号WO94 / 01060 日期1994年1月20日用于阀和关闭构件（尤其是用于心脏瓣膜假体）的支撑壳体（1）具有基部环（2），其具有至少两个对称偏移的柱（4/5） 环形轴线并通过弯曲的条带（3）连接在一起，用于固定至少两个柔性幅材（6/7）。 为了生产具有这样的支撑件，其容纳阀或关闭构件，特别是心脏瓣膜假体，即使在不同的闭合压力差下，即特别是甚至在变化的生理应力条件下也可以可靠地运行，支架（1）仅保留 部分且灵活性有限。 为此，柱的自由端（4）具有刚性形状，和/或柱的基部具有由止挡限制的柔性，和/或带（3）具有由止挡限制的柔性。

公开(公告)号：US5719232A

公开(公告)日：1998-02-17

申请号：US424656

申请日：1995-04-19

申请人： Adolf Schmidt ,  Herbert Eichenauer ,  Ulrich Jansen

发明人： Adolf Schmidt ,  Herbert Eichenauer ,  Ulrich Jansen

IPC分类号： C08F2/22 ,  C08L55/02

CPC分类号： C08L55/02 ,  Y10S525/902

摘要： ABS type thermoplastic moulding compounds obtainable by A) producing a rubber latex with an average particle diameter d.sub.50 of 30 to 160 nm and a gel content of 75 to 100 wt. % B) emulsion polymerization of an amount of butadiene and optionally up to 50 wt. % (with reference to the total amount of monomer in stage B) of a comonomer in the presence of the rubber obtained in stage A, such that a rubber latex (B) with an average particle diameter d.sub.50 =220 to 330 nm and a gel content of 25 to 70 wt. % is produced, C) emulsion polymerization of 40 to 95 parts by wt. of a mixture of styrene and acrylonitrile, which optionally contains up to 50 wt. % (with reference to the total amount of monomers used in stage C) of one or more comonomers, in the presence of 5 to 60 parts by wt. (with reference to the solids) of the rubber obtained in stage B by introducing the monomer in such a way that 55 to 90 wt. % of the monomers are added within the first half of the total monomer introduction time, and D) mixing the polymer obtained in stage C, preferably after first converting it into a powder, with at least one thermoplastic vinyl resin.

摘要翻译： ABS型热塑性成型化合物，其可通过以下方法得到：A）制备平均粒径d50为30〜160nm，凝胶含量为75〜100重量％的橡胶胶乳。 B）一定量的丁二烯的乳液聚合和任选的至多50wt。 在阶段A中获得的橡胶存在下，共聚单体的％（相对于阶段B中的单体的总量），使得平均粒径d 50 = 220〜330nm的橡胶胶乳（B）和凝胶 含量为25〜70wt。 产生％，C）乳液聚合40〜95重量份。 的苯乙烯和丙烯腈的混合物，其任选地含有至多50重量％ 在5至60重量份存在下，一种或多种共聚单体的％（相对于阶段C中使用的单体的总量）。 （相对于固体），通过以55〜90重量％的比例引入单体，得到阶段B中得到的橡胶。 在全部单体引入时间的前半部分内加入％的单体，和D）将在阶段C中获得的聚合物，优选在首先将其转化为粉末之后，与至少一种热塑性乙烯基树脂混合。

公开(公告)号：US5741853A

公开(公告)日：1998-04-21

申请号：US651454

申请日：1996-05-22

申请人： Herbert Eichenauer ,  Ulrich Jansen ,  Karl-Erwin Piejko ,  Edgar Leitz

发明人： Herbert Eichenauer ,  Ulrich Jansen ,  Karl-Erwin Piejko ,  Edgar Leitz

IPC分类号： C08L25/12 ,  C08F279/02 ,  C08F279/04 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02

CPC分类号： C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08L55/02

摘要： Thermoplastic moulding compositions of the ABS type of I) at least one graft copolymer which is obtainable by emulsion polymerization of styrene and acrylonitrile in the weight ratio 90:10 to 50:50, wherein styrene and/or acrylonitrile can be completely or partly replaced by .alpha.-methylstyrene, methyl methacrylate or N-phenylmaleimide, in the presence of at least two butadiene polymer latices of types (A) and (B), which each contain, copolymerized, 0 to 50 wt. % of a further vinyl monomer, and wherein the weight ratio of monomers used to butadiene polymers used is 25:75 to 70:30, and II) at least one copolymer of styrene and acrylonitrile in the weight ratio 90:10 to 50:50, wherein styrene and/or acrylonitrile can be completely or partly replaced by .alpha.-methylstyrene, methyl methacrylate or N-phenylmaleimide, characterized in that the butadiene polymer latex (A) has a particle diameter d.sub.50 .ltoreq.320 nm, a width of the particle size distribution (measured as d.sub.90 -d.sub.10 from the integral particle size distribution) of 30 to 100 nm, and a gel content.ltoreq.70 wt. % and the butadiene polymer latex (B) has a particle diameter d.sub.50 .gtoreq.370 nm, a width of the particle size distribution (measured as d.sub.90 -d.sub.10 from the integral particle size distribution) of 50 to 500 nm and a gel content.gtoreq.70 wt. %.

摘要翻译： ABS型I型热塑性成型组合物）至少一种接枝共聚物，其可通过苯乙烯和丙烯腈的重量比90:10至50:50的乳液聚合获得，其中苯乙烯和/或丙烯腈可以完全或部分地被 α-甲基苯乙烯，甲基丙烯酸甲酯或N-苯基马来酰亚胺，在至少两种类型（A）和（B）的丁二烯聚合物胶乳的存在下，它们各自含有0至50wt。 ％的另外的乙烯基单体，并且其中使用的单体与丁二烯聚合物的重量比为25:75至70:30，和II）至少一种苯乙烯和丙烯腈的共聚物，其重量比为90:10至50:50 其中苯乙烯和/或丙烯腈可以被α-甲基苯乙烯，甲基丙烯酸甲酯或N-苯基马来酰亚胺完全或部分替代，其特征在于丁二烯聚合物胶乳（A）的粒径d50 <320nm， 粒度分布（从整体粒度分布以d90-d10测量）为30至100nm，凝胶含量为70wt。 ％，丁二烯聚合物胶乳（B）的粒径d50≥370nm，粒度分布的宽度（以积分粒度分布测定为d90-d10）为50〜500nm，凝胶含量> / = 70wt。 ％。

公开(公告)号：US5727100A

公开(公告)日：1998-03-10

申请号：US685876

申请日：1996-07-24

申请人： Franz Grajewski ,  Werner Stieb ,  Zbigniew Wielgolaski ,  Ulrich Jansen ,  Rudolf Buchwadd

发明人： Franz Grajewski ,  Werner Stieb ,  Zbigniew Wielgolaski ,  Ulrich Jansen ,  Rudolf Buchwadd

IPC分类号： G02B6/44 ,  H02G15/10 ,  G02B6/36

CPC分类号： G02B6/4471 ,  G02B6/4422 ,  H02G15/10

摘要： A device is described for connecting two electric aerial cables. Each aerial cable has tube, containing optical fibers, which is cabled with electric conductors and strength member. Means are provided for the mechanical and electrically conductive joining of the electric conductors and strength members of the two cables. A sealed splice carrier for receiving the spliced connections of the optical fibers comprises two concentric tubes (7, 9) with a annular gap between them. The annular gap is sealed at both ends. The optical fibers are inserted into the annular gap through apertures in the end seals (8). The spliced connections and a length of optical fibers are stored in the annular gap. The splice carrier (5) surrounds the means (21, 3) for the mechanical and electrically conductive joining and is attached to the electrically conductive joining means (3) or to the aerial cables (1).

摘要翻译： 描述了一种用于连接两根电缆架空电缆的装置。 每根架空电缆都有管，其中包含光纤，电缆与电线和强度元件连接。 提供了用于两个电缆的电导体和强度构件的机械和导电接合的装置。 用于接收光纤的接合连接的密封接合载体包括两个在它们之间具有环形间隙的同心管（7,9）。 环形间隙在两端密封。 光纤通过端部密封件（8）中的孔插入到环形间隙中。 接合连接和一段光纤被存储在环形间隙中。 接头承载件（5）围绕用于机械和导电接合的装置（21,3），并连接到导电接合装置（3）或架空电缆（1）。

公开(公告)号：US5674940A

公开(公告)日：1997-10-07

申请号：US660467

申请日：1996-06-07

申请人： Herbert Eichenauer ,  Ulrich Jansen ,  Karl-Erwin Piejko

发明人： Herbert Eichenauer ,  Ulrich Jansen ,  Karl-Erwin Piejko

IPC分类号： C08F2/22 ,  C08F279/02 ,  C08F279/04 ,  C08L51/04 ,  C08L55/02

CPC分类号： C08F279/04 ,  C08F279/02 ,  C08L51/04 ,  C08L55/02

摘要： Thermoplastic molding compounds of the ABS type of A) at least one graft polymer obtainable by emulsion polymerization of styrene and acrylonitrile in a ratio by weight of 90:10 to 50:50, the styrene and/or acrylonitrile being completely or partly replaceable by .alpha.-methyl styrene, methyl methacrylate or N-phenyl maleic imide, in the presence of at least two butadiene polymer latices of type (A) and (B), of which each contains 0 to 50% by weight of another vinyl monomer in copolymerized form, the ratio by weight of the monomers used to the butadiene polymers used being 25:75 to 70:30, and B) at least one copolymer of styrene and acrylonitrile in a ratio by weight of 90:10 to 50:50, the styrene and/or acrylonitrile being completely or partly replaceable by .alpha.-methyl styrene, methyl methacrylate or N-phenyl maleic imide, characterized in that the butadiene polymer latex (A) has a particle diameter d.sub.50 of .ltoreq.250 nm, a width of the particle size distribution (measured as d.sub.90 -d.sub.10 from the integral particle size distribution) of 500 to 1000 nm and a gel content of .ltoreq.70% by weight, the butadiene polymer latex (B) has a particle diameter d.sub.50 of .gtoreq.300 nm, a width of the particle size distribution (measured as d.sub.90 -d.sub.10 from the integral particle size distribution) of 50 to 500 nm and a gel content of .gtoreq.70% by weight and the graft polymerization is carried out by addition of the monomers to the mixture of butadiene polymer latices (A) and (B) in such a way that 55 to 90% by weight of the monomers are added in the first half of the monomer addition time.

摘要翻译： ABS型的热塑性成型化合物A）至少一种可通过苯乙烯和丙烯腈的重量比为90:10至50:50的乳液聚合而获得的接枝聚合物，苯乙烯和/或丙烯腈可完全或部分地被α 甲基苯乙烯，甲基丙烯酸甲酯或N-苯基马来酰亚胺，在至少两种类型（A）和（B）的丁二烯聚合物胶乳的存在下，其各自含有0至50重量％的共聚形式的另一个乙烯基单体 所用的丁二烯聚合物的单体重量比为25:75至70:30，B）苯乙烯和丙烯腈的至少一种共聚物的重量比为90:10至50:50，苯乙烯 和/或丙烯腈由α-甲基苯乙烯，甲基丙烯酸甲酯或N-苯基马来酰亚胺完全或部分替代，其特征在于丁二烯聚合物胶乳（A）的粒径d50为<250nm，宽度为 粒度分布（以d90-d10测量） m的整体粒度分布）为500〜1000nm，凝胶含量为70重量％，丁二烯聚合物胶乳（B）的粒径d50> 300nm，粒径 分布（从整体粒度分布测定为d90-d10）为50〜500nm，凝胶含量≥70重量％，接枝聚合通过将单体加入到丁二烯聚合物胶乳 （A）和（B），使得在单体添加时间的前半部分中加入55〜90重量％的单体。

公开(公告)号：US5047480A

公开(公告)日：1991-09-10

申请号：US131091

申请日：1987-12-10

申请人： Edgar Leitz ,  Ulrich Jansen ,  Hans-Jurgen Kress ,  Horst Peters ,  Jochen Schoeps ,  Leo Morbitzer

发明人： Edgar Leitz ,  Ulrich Jansen ,  Hans-Jurgen Kress ,  Horst Peters ,  Jochen Schoeps ,  Leo Morbitzer

IPC分类号： C08L25/16 ,  C08L25/00 ,  C08L33/04 ,  C08L33/12 ,  C08L35/00 ,  C08L35/06

CPC分类号： C08L33/12 ,  C08L35/06 ,  C08L25/16

摘要： Thermoplastic molding compositions containinga. from 1 to 99 parts by weight of a thermoplastic copolymer offrom 40 to 70 parts by weight methyl methacrylate, from 20 to 50 parts by weight .alpha.-methyl styrene and from 5 to 15 parts by weight acrylonitrile,b. from 1 to 99 parts by weight of a statistical, thermoplastic copolymer offrom 70 to 95 parts by weight styrene and from 5 to 30 parts by weight maleic acid anhydride.

摘要翻译： 含有热塑性成型组合物 b为1〜99重量份的40〜70重量份甲基丙烯酸甲酯，20〜50重量份α-甲基苯乙烯和5〜15重量份丙烯腈的热塑性共聚物，b。 1至99重量份的统计性热塑性共聚物，其为70至95重量份的苯乙烯和5至30重量份的马来酸酐。