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公开(公告)号:US06884743B2
公开(公告)日:2005-04-26
申请号:US10243669
申请日:2002-09-16
申请人: Ulrich Müller , Georg Krug , Peter Bassler , Hans-Georg Göbbel , Peter Rudolf , Joaquim Henrique Teles
发明人: Ulrich Müller , Georg Krug , Peter Bassler , Hans-Georg Göbbel , Peter Rudolf , Joaquim Henrique Teles
IPC分类号: C07D303/04 , B01J29/89 , B01J37/04 , C01B39/06 , C01B39/40 , C07B61/00 , C07D301/12 , B01J29/06
CPC分类号: C07D301/12 , B01J29/89
摘要: The present invention relates to the manufacture of solid materials or shaped bodies containing at least one zeolite and being at least partly crystalline. Furthermore, the present invention relates to the solid materials or shaped bodies as such and to the use of these materials for reactions of compounds having at least one C—C double bond with at least one hydroperoxide. Specifically, the present invention relates to a process for the manufacture of a solid material containing at least one zeolite and being at least partly crystalline, wherein the synthesis of the said solid material involves at least one partial step of contacting at least one transition metal oxide source with at least one epoxide or hydrolysate thereof prior to or during the at least partial crystallization of said solid material.
摘要翻译: 本发明涉及包含至少一种沸石并且至少部分结晶的固体材料或成形体的制造。 此外,本发明还涉及固体材料或成形体,以及这些材料用于具有至少一个C-C双键的化合物与至少一种氢过氧化物的反应的用途。 具体地说,本发明涉及制造含有至少一种沸石并且至少部分结晶的固体材料的方法,其中所述固体材料的合成涉及至少一个部分步骤,使至少一种过渡金属氧化物 来源,其在所述固体材料的至少部分结晶之前或期间具有至少一种环氧化物或水解产物。
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公开(公告)号:US09302257B2
公开(公告)日:2016-04-05
申请号:US12954802
申请日:2010-11-26
申请人: Ulrich Müller , Peter Rudolf , Georg Krug , Rainer Senk
发明人: Ulrich Müller , Peter Rudolf , Georg Krug , Rainer Senk
IPC分类号: B01J29/04 , B01J29/89 , B01J37/00 , B01J37/08 , C07D301/12
CPC分类号: B01J29/89 , B01J37/0018 , B01J37/084 , B01J2229/42 , C07D301/12
摘要: A process for the preparation of a catalyst for the use in a hydrocarbon conversion reaction, said catalyst containing a titanium zeolite and carbonaceous material, the catalyst containing said carbonaceous material in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst, the process comprising (i) preparing a catalyst containing the titanium zeolite and (ii) depositing carbonaceous material on the catalyst according to (i) in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst by contacting said catalyst, prior to using the catalyst in said hydrocarbon conversion reaction, with a fluid containing at least one hydrocarbon in an inert atmosphere, to obtain the carbonaceous material containing catalyst, wherein in (ii), the catalyst is not contacted with an oxygen containing gas.
摘要翻译: 一种用于制备用于烃转化反应的催化剂的方法,所述催化剂含有钛沸石和含碳材料,所述含碳材料的催化剂的含量为基于总重量的0.01-0.5重量% 包含在催化剂中的钛沸石,该方法包括(i)制备含有钛沸石的催化剂和(ii)根据(i)在催化剂上沉积含碳材料,其量为基于总计的0.01至0.5重量% 催化剂中含有的钛沸石的重量,在使用所述烃转化反应中的催化剂之前,使所述催化剂与在惰性气氛中含有至少一种烃的流体接触,得到含碳材料的催化剂,其中在(ii) ,催化剂不与含氧气体接触。
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公开(公告)号:US20110130579A1
公开(公告)日:2011-06-02
申请号:US12954802
申请日:2010-11-26
申请人: Ulrich MÜLLER , Peter Rudolf , Georg Krug , Rainer Senk
发明人: Ulrich MÜLLER , Peter Rudolf , Georg Krug , Rainer Senk
IPC分类号: C07D301/02 , B01J29/04 , B01J29/18 , B01J29/06
CPC分类号: B01J29/89 , B01J37/0018 , B01J37/084 , B01J2229/42 , C07D301/12
摘要: A process for the preparation of a catalyst for the use in a hydrocarbon conversion reaction, said catalyst containing a titanium zeolite and carbonaceous material, the catalyst containing said carbonaceous material in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst, the process comprising (i) preparing a catalyst containing the titanium zeolite and (ii) depositing carbonaceous material on the catalyst according to (i) in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst by contacting said catalyst, prior to using the catalyst in said hydrocarbon conversion reaction, with a fluid containing at least one hydrocarbon in an inert atmosphere, to obtain the carbonaceous material containing catalyst, wherein in (ii), the catalyst is not contacted with an oxygen containing gas.
摘要翻译: 一种用于制备用于烃转化反应的催化剂的方法,所述催化剂含有钛沸石和含碳材料,所述含碳材料的催化剂的含量为基于总重量的0.01-0.5重量% 包含在催化剂中的钛沸石,该方法包括(i)制备含有钛沸石的催化剂和(ii)根据(i)在催化剂上沉积含碳材料,其量为基于总计的0.01至0.5重量% 催化剂中含有的钛沸石的重量,在使用所述烃转化反应中的催化剂之前,使所述催化剂与在惰性气氛中含有至少一种烃的流体接触,得到含碳材料的催化剂,其中在(ii) ,催化剂不与含氧气体接触。
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公开(公告)号:US20120197038A1
公开(公告)日:2012-08-02
申请号:US13442401
申请日:2012-04-09
申请人: Ralf Böhling , Sven Küber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
发明人: Ralf Böhling , Sven Küber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
IPC分类号: C07C263/10
CPC分类号: C07C263/10 , B01J2219/00038 , B01J2219/00869 , C07C2601/14 , C07C265/14
摘要: Process for preparing isocyanates by phosgenation of amines, wherein phosgene and amine are brought into contact in at least 2 mixing chambers connected in parallel.
摘要翻译: 通过胺的光气化制备异氰酸酯的方法,其中光气和胺在至少两个并联连接的混合室中接触。
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公开(公告)号:US20100317889A1
公开(公告)日:2010-12-16
申请号:US12446460
申请日:2007-10-18
申请人: Ralf Boehling , Sven Kueber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
发明人: Ralf Boehling , Sven Kueber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
IPC分类号: C07C263/10 , C07C263/20
CPC分类号: C07C263/10 , B01J2219/00038 , B01J2219/00869 , C07C2601/14 , C07C265/14
摘要: Process for preparing isocyanates by phosgenation of amines, wherein phosgene and amine are brought into contact in at least 2 mixing chambers connected in parallel.
摘要翻译: 通过胺的光气化制备异氰酸酯的方法,其中光气和胺在至少两个并联连接的混合室中接触。
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公开(公告)号:US08212069B2
公开(公告)日:2012-07-03
申请号:US12446460
申请日:2007-10-18
申请人: Ralf Boehling , Sven Kueber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
发明人: Ralf Boehling , Sven Kueber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
IPC分类号: C07C263/00
CPC分类号: C07C263/10 , B01J2219/00038 , B01J2219/00869 , C07C2601/14 , C07C265/14
摘要: Process for preparing isocyanates by phosgenation of amines, wherein phosgene and amine are brought into contact in at least 2 mixing chambers connected in parallel.
摘要翻译: 通过胺的光气化制备异氰酸酯的方法,其中光气和胺在至少两个并联连接的混合室中接触。
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17.
公开(公告)号:US20100015012A1
公开(公告)日:2010-01-21
申请号:US12505238
申请日:2009-07-17
申请人: Dominic Vanoppen , Frederik Van Laar , Thomas Beuermann , Georg Krug , Steffen Oehlenschlager , Ekkehard Schwab , Hartwig Voss , Konrad Morgenschweis , Ulrich Penzel , Dietrich Tittelbach-Helmrich
发明人: Dominic Vanoppen , Frederik Van Laar , Thomas Beuermann , Georg Krug , Steffen Oehlenschlager , Ekkehard Schwab , Hartwig Voss , Konrad Morgenschweis , Ulrich Penzel , Dietrich Tittelbach-Helmrich
IPC分类号: B01J19/00
CPC分类号: B01J19/0033 , B01J8/006 , B01J8/007 , B01J8/22 , B01J19/002 , B01J2208/00637 , B01J2219/002 , B01J2219/00225 , B01J2219/00263 , C07C209/36 , G01N21/31 , C07C211/51
摘要: The invention relates to a process for preparing aromatic amines by hydrogenation of nitroaromatics in the presence of catalysts, in which a fluid reaction mixture which comprises amines and from which the catalysts are separated off is formed in a reactor. After the catalysts have been separated off, a measurement of the absorption of UV/VIS radiation by the reaction mixture is carried out to determine the concentration of nitro and nitroso compounds in the reaction mixture.
摘要翻译: 本发明涉及通过在催化剂存在下氢化硝基芳族化合物来制备芳族胺的方法,其中在反应器中形成包含胺并在其中分离催化剂的流体反应混合物。 催化剂分离后,进行反应混合物对UV / VIS辐射吸收的测定,以确定反应混合物中硝基和亚硝基化合物的浓度。
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公开(公告)号:US08772535B2
公开(公告)日:2014-07-08
申请号:US13442401
申请日:2012-04-09
申请人: Ralf Boehling , Sven Kueber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
发明人: Ralf Boehling , Sven Kueber , Stefan Maixner , Eckhard Stroefer , Jochem Henkelmann , Georg Krug , Werner Bolz
IPC分类号: C07C263/00
CPC分类号: C07C263/10 , B01J2219/00038 , B01J2219/00869 , C07C2601/14 , C07C265/14
摘要: Process for preparing isocyanates by phosgenation of amines, wherein phosgene and amine are brought into contact in at least 2 mixing chambers connected in parallel.
摘要翻译: 通过胺的光气化制备异氰酸酯的方法,其中光气和胺在至少两个并联连接的混合室中接触。
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公开(公告)号:US20080146848A1
公开(公告)日:2008-06-19
申请号:US11816658
申请日:2006-02-22
申请人: Dominic Vanoppen , Frederik van Laar , Thomas Beuemann , Georg Krug , Steffen Oehlenschlager , Ekkehard Schwab , Hartwig Voss , Konrad Morgenschweis , Ulrich Penzel , Dietrich Tittelbach-Helmrich
发明人: Dominic Vanoppen , Frederik van Laar , Thomas Beuemann , Georg Krug , Steffen Oehlenschlager , Ekkehard Schwab , Hartwig Voss , Konrad Morgenschweis , Ulrich Penzel , Dietrich Tittelbach-Helmrich
IPC分类号: C07C211/50 , B01J14/00
CPC分类号: B01J19/0033 , B01J8/006 , B01J8/007 , B01J8/22 , B01J19/002 , B01J2208/00637 , B01J2219/002 , B01J2219/00225 , B01J2219/00263 , C07C209/36 , G01N21/31 , C07C211/51
摘要: The invention relates to a process for preparing aromatic amines by hydrogenation of nitroaromatics in the presence of catalysts, in which a fluid reaction mixture which comprises amines and from which the catalysts are separated off is formed in a reactor. After the catalysts have been separated off, a measurement of the absorption of UV/VIS radiation by the reaction mixture is carried out to determine the concentration of nitro and nitroso compounds in the reaction mixture.
摘要翻译: 本发明涉及通过在催化剂存在下氢化硝基芳族化合物来制备芳族胺的方法,其中在反应器中形成包含胺并在其中分离催化剂的流体反应混合物。 催化剂分离后,进行反应混合物对UV / VIS辐射吸收的测定,以确定反应混合物中硝基和亚硝基化合物的浓度。
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公开(公告)号:US07595424B2
公开(公告)日:2009-09-29
申请号:US11816658
申请日:2006-02-22
申请人: Dominic Vanoppen , Frederik Van Laar , Thomas Beuermann , Georg Krug , Steffen Oehlenschlaeger , Ekkehard Schwab , Hartwig Voss , Konrad Morgenschweis , Ulrich Penzel , Dietrich Tittelbach-Helmrich
发明人: Dominic Vanoppen , Frederik Van Laar , Thomas Beuermann , Georg Krug , Steffen Oehlenschlaeger , Ekkehard Schwab , Hartwig Voss , Konrad Morgenschweis , Ulrich Penzel , Dietrich Tittelbach-Helmrich
IPC分类号: C07C209/36
CPC分类号: B01J19/0033 , B01J8/006 , B01J8/007 , B01J8/22 , B01J19/002 , B01J2208/00637 , B01J2219/002 , B01J2219/00225 , B01J2219/00263 , C07C209/36 , G01N21/31 , C07C211/51
摘要: The invention relates to a process for preparing aromatic amines by hydrogenation of nitroaromatics in the presence of catalysts, in which a fluid reaction mixture which comprises amines and from which the catalysts are separated off is formed in a reactor. After the catalysts have been separated off, a measurement of the absorption of UV/VIS radiation by the reaction mixture is carried out to determine the concentration of nitro and nitroso compounds in the reaction mixture.
摘要翻译: 本发明涉及通过在催化剂存在下氢化硝基芳族化合物来制备芳族胺的方法,其中在反应器中形成包含胺并在其中分离催化剂的流体反应混合物。 催化剂分离后,进行反应混合物对UV / VIS辐射吸收的测定,以确定反应混合物中硝基和亚硝基化合物的浓度。
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