摘要:
The problem to be solved by the present invention is to provide a method for continuously and effectively producing an aliphatic polyester having an increased molecular weight which prevents evaporation of diisocyanate at the step of mixing the diisocyanate with the aliphatic polyester prepolymer in a molten state at a temperature not lower than the melting point of the prepolymer and enables uniform mixing of the diisocyanate with the aliphatic polyester prepolymer. In order to solve this problem, the present invention provides a method for producing an aliphatic polyester having an increased molecular weight comprising the steps of: (i) quantitatively injecting a diisocyanate into an aliphatic polyester prepolymer which has a number average molecular weight of 5000 or higher and has terminal hydroxyl groups and in which at least one acid component is a succinic acid compound, in a molten state at a temperature not lower than the melting point thereof, wherein the amount of diisocyanate is equivalent to between one tenth and two times the amount of the hydroxyl groups in the aliphatic polyester prepolymer, (ii) quantitatively and continuously mixing the diisocyanate-containing aliphatic polyester prepolymer obtained at step (i) by a static mixer, discharging same from the static mixer, and then supplying same to a coupling reaction tank, and (iii) reacting the aliphatic polyester prepolymer with the diisocyanate in the coupling reaction tank.
摘要:
A fuel cell system is provided with a plurality of cell units, a feeding channel, a bypass channel and a control unit. The cell units generate power by feeding hydrogen-containing gas an oxygen-containing gas separated from each other and then having them flow and join with each other. The feeding channel has an ejector arranged therein for refluxing exhausted hydrogen-containing gas exhausted from the cell units back to the cell units. The bypass channel has the hydrogen-containing gas flowing to the cell units bypass the ejector. The control unit includes a gas feeding pressure varying section that is programmed to make the hydrogen-containing gas flow in the bypass channel, and, at the same time, vary the pressure of the hydrogen-containing gas flowing in the feeding channel upon determining a flow rate of the hydrogen-containing gas flowing in the feeding channel is over a prescribed level.
摘要:
A method of toughening thermoplastic polyurethane (TPU). The TPU is dipped into a urethane solution having a penetrating agent, then heated and dried for a period sufficient to toughen the surface. Also, articles such as golf balls having a toughened thermoplastic polyurethane surface. The toughened thermoplastic polyurethane surface is more scuff-resistant and has a greater strain-rate shear resistance than the TPU.
摘要:
Generally disclosed is a golf ball having a core and a cover layer. The cover layer includes areas that are hard corresponding to the dimples, and areas that are soft corresponding to the land between the dimples. The cover layer may be selectively treated, such as by heating, to achieve a difference in hardness using a single cover layer material. Alternatively, the cover layer may be selectively coated with a coating material having a different hardness. As a result of the arrangement of the hard dimples and the soft land, the golf ball achieves reduced spin, and greater distances, when struck with a larger force (such as during a dive) while also achieving increased spin, and better control, when struck with a smaller force (such as during a chip).
摘要:
A rebound resilient golf ball having an core layer or layers with one or more cores, a scuff resistant cover of thermoplastic polyurethane surrounding the core layer or layers, and optionally a mantle layer positioned between the cover and the core layer or layers. The cover is made from a dendritic thermoplastic polyurethane that includes an isocyanate monomer and a hyper branched polyol, optional additional polyols, and one or more chain extenders. An optional mantle layer may also be made of thermoplastic polyurethane, particularly a dendritic thermoplastic polyurethane.
摘要:
A four piece golf ball includes several relationships among the values of the densities of its layers. Namely, the sum of the density of the inner core and the outer core is at least 2 g/cm3, the sum of the density of the inner cover layer and the outer cover layer is at least 2.2 g/cm3, and the difference between these two sums is at least 0.1 g/cm3. The inner core is made of a highly neutralized acid polymer, the outer core is made of a polybutadiene rubber, and the inner and outer cover layers are made of a non-ionomeric thermoplastic material, such as thermoplastic polyurethane. The layers may have certain relationships among their hardness values. Finally, the golf ball exhibits certain physical properties, such as a certain moment of inertia.
摘要翻译:四层高尔夫球包括其层的密度值之间的几个关系。 即,内芯和外芯的密度的总和为至少2g / cm 3,内覆盖层和外覆盖层的密度之和为2.2g / cm 3以上, 这两个总和至少为0.1g / cm 3。 内芯由高度中和的酸性聚合物制成,外芯由聚丁二烯橡胶制成,内外层由非离聚物热塑性材料如热塑性聚氨酯制成。 这些层可能在它们的硬度值之间具有某些关系。 最后,高尔夫球表现出一定的物理特性,如一定的惯性力矩。
摘要:
A rebound resilient golf ball having one or more core layers, a cover surrounding the core layer or layers, and optionally a mantle layer positioned between the cover and the core layer or layers. At least one of the layers of the golf ball includes a material whose resilience increases as the hardness of the material increases.
摘要:
A multi-piece solid golf ball comprises a core having a 5 structure consisting of at least two layers and a cover on the core consisting of outer and inner cover layers. The outer cover layer has a Shore D hardness of 40-60 degrees. The inner cover layer has a Shore D hardness of up to 53 degrees and lower than that of the outer cover layer. The ball's carry is comparable to conventional solid golf balls and spin receptivity is approximate to wound golf balls while the ball is durable and offers pleasant feel.
摘要:
In a multi-piece solid golf ball comprising a solid core, a mantle and a cover, the solid core is made of a rubber composition that includes a base rubber containing a polybutadiene synthesized using a rare-earth catalyst, a small amount of organic peroxide, an unsaturated carboxylic acid and/or a metal salt thereof, an organic sulfur compound and an inorganic filler. The mantle is made of a thermoplastic resin composition. The cover is made primarily of a thermoplastic polyurethane material. This construction provides the golf ball with a combination of outstanding flight performance and soft feel with cover's scuff resistance and coating's abrasion resistance, that is unprecedented.
摘要:
A multi-piece golf ball includes a core 30–40 mm in diameter, an intermediate layer including an outermost layer 0.5–2.0 mm thick, and a cover 0.5–2.0 mm thick. The core is a rubber composition mainly containing polybutadiene. The outermost layer is a resin material containing an ionomer resin in an amount of 30% by weight or more. The cover material is obtained by dispersedly blending a silicone powder in a main resin containing an ionomer resin in an amount of 50% by weight or more. The hardness of the outermost layer is harder than the hardness of the core's a center portion. The hardness of the cover is harder than the hardness of the outermost layer. A difference in hardness between the cover and the center portion of the core satisfies a relation of 10≦(Durometer D hardness of cover−Durometer D hardness of center portion of core≦40.