公开(公告)号：US4205115A

公开(公告)日：1980-05-27

申请号：US897963

申请日：1978-04-19

Applicant: Robert M. Piccirilli ,  Wen-Hsuan Chang ,  David T. McKeough ,  Samuel Porter, Jr.

Inventor： Robert M. Piccirilli ,  Wen-Hsuan Chang ,  David T. McKeough ,  Samuel Porter, Jr.

IPC: C08G63/00 ,  C08G18/42 ,  C08G18/46 ,  C08G63/12 ,  C08G63/20 ,  C08G63/685 ,  C09D167/00 ,  C09D167/02 ,  C09D177/00 ,  B32B27/40 ,  B32B27/06 ,  B32B27/36

CPC classification number: C08G63/20 ,  C08G18/4205 ,  C08G18/4219 ,  C08G18/4615 ,  C09D167/00 ,  Y10T428/263 ,  Y10T428/31551 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31942

Abstract: Coating compositions having a high degree of elasticity, as well as toughness, durability and good metallic pigment pattern control are disclosed. This combination of properties makes the coatings particularly desirable for use on elastomeric substrates such as those associated with automobiles. The coating compositions comprise as a resinous component, an ungelled hydroxyl-containing polyester of high weight average molecular weight. The polyesters can be cured with a curative such as an aminoplast to give coatings having outstanding elastomeric properties and good pigment dispersibility, particularly good metallic pigment pattern control, properties not normally associated with polyesters for use in coating applications.

Abstract translation: 公开了具有高弹性以及韧性，耐久性和良好的金属颜料图案控制的涂料组合物。 这种性质的组合使得涂层特别适用于弹性体基底，例如与汽车相关的基底。 涂料组合物包含作为树脂组分的高均匀分子量的未凝胶化含羟基聚酯。 聚酯可以用诸如氨基塑料的固化剂固化，得到具有突出的弹性性质和良好的颜料分散性的涂料，特别是良好的金属颜料图案控制，通常不与用于涂料应用的聚酯缔合的性质。

公开(公告)号：US4174228A

公开(公告)日：1979-11-13

申请号：US891109

申请日：1978-03-28

Applicant: William G. Boberski ,  Wen-Hsuan Chang ,  Jerome A. Seiner

Inventor： William G. Boberski ,  Wen-Hsuan Chang ,  Jerome A. Seiner

IPC: C04B24/42 ,  C04B28/32 ,  C07F7/18 ,  C04B9/02 ,  C04B9/04

CPC classification number: C04B28/32 ,  C04B24/42 ,  C07F7/182

Abstract: Magnesium oxide cementitious compositions are disclosed containing salts of organo-silanols. The silanol salts are water-soluble and are characterized in having attached to the silicon atom at least one group comprising a moiety attached to the silicon atom through a substantially non-hydrolyzable silicon-carbon bond and at least one silanol group which is at least partially neutralized with a base. A magnesia composition containing one or more of these organo-silanol salts has improved casting, molding, or spraying properties, as compared to a magnesia composition lacking the silanol salt.

Abstract translation: 公开了含有有机硅烷醇盐的氧化镁水泥组合物。 硅烷醇盐是水溶性的，其特征在于通过基本上不可水解的硅 - 碳键和至少一部分至少部分硅烷醇基团连接至少一个包含与硅原子连接的部分的基团 用碱中和。 与不含硅烷醇盐的氧化镁组合物相比，含有这些有机硅烷醇盐中的一种或多种的氧化镁组合物具有改进的铸造，模塑或喷涂性能。

公开(公告)号：US4147679A

公开(公告)日：1979-04-03

申请号：US853780

申请日：1977-11-21

Applicant: Roger L. Scriven ,  Wen-Hsuan Chang

Inventor： Roger L. Scriven ,  Wen-Hsuan Chang

IPC: C08G18/08 ,  C08G18/10 ,  C09D175/04 ,  C08L75/12

CPC classification number: C09D175/04 ,  C08G18/0804 ,  C08G18/0833 ,  C08G18/10 ,  Y10T428/31678 ,  Y10T442/2369

Abstract: A water-diluted, ungelled, non-sedimenting polyurethane and a process for preparing such a polyurethane in an aqueous medium is disclosed. High molecular weight thermoplastic products are obtained by chain extending in aqueous medium an NCO polymer having a salt group equivalent weight of 6000 or less and substantially free of reactive hydrogen. The average functionality and equivalent ratio of the polyisocyanate and active hydrogen-containing materials used in making the NCO polymer, as well as the functionality of the chain extender, are carefully controlled so as to get high molecular weight ungelled products. Thermosetting compositions can be made by adding curing agent to the chain extended material. Curing agents can also be incorporated into the polymer molecule either in the making of the partially reacted NCO-containing prepolymer or by further reaction with the partially reacted NCO-containing prepolymer. The water-dispersed polyurethanes of the present invention are excellent film formers, capable of making coatings with a wide spectrum of desirable properties. In addition, they can be added to other water-compatible compositions to improve flexibility, hardness, drying and other coating properties.

Abstract translation: 公开了一种水稀释，未凝胶化，非沉降聚氨酯和在水性介质中制备这种聚氨酯的方法。 通过在水性介质中延伸具有当量为6000以下的盐基团且基本上不含反应性氢的NCO聚合物获得高分子量热塑性产物。 用于制备NCO聚合物的多异氰酸酯和含活性氢的材料的平均官能度和当量比以及扩链剂的官能度被小心地控制，以便获得高分子量的未凝胶产物。 热固性组合物可以通过向扩链材料中加入固化剂来制备。 在制备部分反应的含NCO的预聚物中或通过与部分反应的含NCO的预聚物进一步反应，固化剂也可以掺入聚合物分子中。 本发明的水分散性聚氨酯是优异的成膜剂，能够制备具有广泛期望性能的涂层。 此外，它们可以加入到其他与水相容的组合物中以改善柔韧性，硬度，干燥和其它涂料性能。

公开(公告)号：US4105025A

公开(公告)日：1978-08-08

申请号：US741295

申请日：1976-11-12

Applicant: Yen Wang ,  Wen-Hsuan Chang

Inventor： Yen Wang ,  Wen-Hsuan Chang

IPC: A61F13/04 ,  A61L15/12

CPC classification number: A61F13/04 ,  A61L15/12 ,  Y10T428/31551 ,  Y10T428/31591

Abstract: A supportive wrapping for a surgical support or orthopedic cast is produced by providing a bandage material which is impregnated or coated with a molten polyurethane polymer that is crystallizable in a predetermined, delayed time period at room temperatures or at temperatures tolerable to human skin and permitting the polyurethane polymer to crystallize on the bandage material to form a strong, supportive, self adhered wrapping while standing at or cooling to room temperature.

Abstract translation: 通过提供一种绷带材料来生产用于外科支架或矫形外科植入物的支撑性包裹物，所述绷带材料被浸渍或涂覆有熔融聚氨酯聚合物，所述熔融聚氨酯聚合物可在室温下或在对人体皮肤耐受的温度下在预定的延迟时间段内结晶，并允许 聚氨酯聚合物在绷带材料上结晶以在静置或冷却至室温时形成强的，支撑的，自粘的包裹物。

公开(公告)号：US3953391A

公开(公告)日：1976-04-27

申请号：US233319

申请日：1972-03-09

Applicant: Rostyslaw Dowbenko ,  Wen-Hsuan Chang

Inventor： Rostyslaw Dowbenko ,  Wen-Hsuan Chang

IPC: C09D5/44 ,  C08L33/14

CPC classification number: C09D5/4411

Abstract: It has been found that aqueous coating compositions comprising acid-solubilized, imine-modified, carboxylic acid group-containing acrylic resins can be electrodeposited. These compositions deposit on the cathode to provide coatings having excellent properties.

公开(公告)号：US5413867A

公开(公告)日：1995-05-09

申请号：US251150

申请日：1994-05-31

Applicant: Wen-Hsuan Chang ,  John F. Grunewalder ,  Mark A. Harley ,  Edward E. McEntire

Inventor： Wen-Hsuan Chang ,  John F. Grunewalder ,  Mark A. Harley ,  Edward E. McEntire

IPC: B27K3/34 ,  B27K5/00 ,  C07F7/18 ,  B32B9/04

CPC classification number: C07F7/1836 ,  B05D7/08 ,  Y10T428/31663

Abstract: A stable aqueous dispersion having a particle size in the range of about 10 to 200 nanometers containing specific silanes carrying at least one hydrophobic moiety and at least one water-solubilizing moiety is used in a process for treating a cellulosic substrate resulting in a treated product. The aqueous dispersions used in treating the cellulosic substrate are stable for at least 20 days without externally added surfactant.

Abstract translation: 在用于处理产生处理过的产品的纤维素底物的方法中，使用具有约10-200纳米范围内的粒度在内的稳定的含水分散体，其含有至少一个疏水部分和至少一个水溶性部分的特定硅烷。 用于处理纤维素底物的水性分散体在不含外部添加的表面活性剂的情况下是稳定的至少20天。

公开(公告)号：US5162420A

公开(公告)日：1992-11-10

申请号：US707250

申请日：1991-05-22

Applicant: Wen-Hsuan Chang ,  Edward E. McEntire ,  Marvin L. Kaufman

Inventor： Wen-Hsuan Chang ,  Edward E. McEntire ,  Marvin L. Kaufman

IPC: C08F230/08 ,  C09D143/04

CPC classification number: C09D143/04 ,  C08F230/08

Abstract: Disclosed is an aqueous composition containing a vinyl-type polymer product having hydrolyzable silyl groups which aqueous composition is stable at relatively high solids for such a composition and yet cures at relatively low temperatures upon the evaporation of water. More particularly, disclosed is a stable, aqueous, colloidal silica-free, dispersion or solution containing a solution-polymerized vinyl-type polymer having acid functionality sufficient to provide an acid value of from 5 to 160 and having a hydroxyl value of less than or equal to 10 and sufficient hydrolyzable silyl groups to provide a Si content in the range of from 0.40 to 6.0 percent by weight based on the total weight of the vinyl-type polymer. The vinyl-type polymer is characterized in that a composition consisting of at least 25 percent by weight of the polymer in water remains stable in a closed container for at least 24 hours at a temperature of 48.9 degrees Celsius.Also disclosed is a stable, aqueous, colloidal silica-free, coating composition having a total organic resin solids content of greater than or equal to 25 percent by weight, at least 50 percent by weight of the total organic resin solids content consisting of the aforesaid solution-polymerized vinyl-type polymer.

Abstract translation: 公开了一种水性组合物，其含有具有可水解甲硅烷基的乙烯基型聚合物产物，该水性组合物对于这种组合物在相对高的固含量下是稳定的，并且在水蒸发时在相对低的温度下固化。 更具体地，公开了一种稳定的含水胶态二氧化硅的分散体或溶液，其含有溶液聚合的乙烯基型聚合物，该聚合物的酸官能度足以提供5至160的酸值，并且其羟基值小于或等于 等于10和足够的可水解甲硅烷基，以提供基于乙烯基类聚合物总重量的0.40至6.0重量％的Si含量。 乙烯基型聚合物的特征在于由水中至少25重量％的聚合物组成的组合物在密封容器中在48.9摄氏度的温度下保持稳定至少24小时。 还公开了一种稳定的水性无胶体二氧化硅涂料组合物，其总有机树脂固体含量大于或等于25重量％，至少占总有机树脂固体含量的50重量％，由上述 溶液聚合的乙烯基型聚合物。

公开(公告)号：US4732929A

公开(公告)日：1988-03-22

申请号：US19917

申请日：1987-02-27

Applicant: Wen-Hsuan Chang ,  David T. McKeough ,  John R. Peffer

Inventor： Wen-Hsuan Chang ,  David T. McKeough ,  John R. Peffer

IPC: C08G18/46 ,  C08G18/50 ,  C08G18/64 ,  C09D183/14 ,  C09D201/10 ,  C08G77/04 ,  C08L83/00

CPC classification number: C09D183/14 ,  C08G18/4692 ,  C08G18/5096 ,  C08G18/6469 ,  C09D201/10

Abstract: Disclosed are essentially zinc-free, organic coating compositions based on silicon-containing polyols comprising reaction products of hydrophobic polyols, organosilicon-containing materials, and higher monohydric alcohols, R-OH. The organosilicon-containing material comprises an organosilicon-containing substance free of certain functional groups attached directly to carbon and essentially free of alkali metal ions. The organosilicon-containing substance has atoms bonded directly to Si all of which are selected from O, N, and/or Cl. The organosilicon-containing substance also has moieties directly bonded to Si which are displaceable by reaction with water and/or alcohol. The reaction product is not capable of being gelled when subjected to a specific gel test, has a content of hydroxyl groups from the hydrophobic polyol ranging from 0.4 to 10 milliequivalents per gram of reaction product, has a content of groups, --OR, from the higher monofunctional alcohol ranging from 0.1 to 7 milliequivalents per gram of reaction product, and a content of the moieties directly bonded to Si which are displaceable of less than 1 milliequivalent per gram of reaction product.The organic coating composition also contains a curing agent for for the silicon-containing polyol selected from the group consisting of an aminoplast, a phenoplast, an isocyanate, a blocked isocyanate, a semi-blocked isocyanate, a lower-alkoxy-containing silane, and a hydrolyzed lower- alkoxy-containing silane.The coating composition is essentially free of elemental zinc and cures to an essentially organic coating.

Abstract translation: 本发明公开了基于含硅多元醇的无锌有机涂料组合物，其包含疏水多元醇，含有机硅材料和较高级一元醇R-OH的反应产物。 含有机硅的材料包含不含直接连接到碳上并且基本上不含碱金属离子的某些官能团的含有机硅物质。 含有机硅的物质具有直接与Si键合的原子，所有这些原子均选自O，N和/或Cl。 含有机硅的物质还具有直接键合到Si的部分，其可通过与水和/或醇反应而置换。 当进行特定的凝胶试验时，反应产物不能凝胶化，每克反应产物的疏水性多元醇的羟基含量为0.4-10毫克当量，其含量为-OR， 每克反应产物为0.1至7毫当量的高级单官能醇，以及直接键合至Si的部分的​​含量，其每克反应产物可置换少于1毫当量。 有机涂料组合物还含有用于含硅多元醇的固化剂，其选自氨基塑料，酚醛树脂，异氰酸酯，封端异氰酸酯，半封端异氰酸酯，含低级烷氧基的硅烷和 水解的含低级烷氧基的硅烷。 涂料组合物基本上不含元素锌并固化成基本上有机涂层。

公开(公告)号：US4613451A

公开(公告)日：1986-09-23

申请号：US462590

申请日：1983-01-31

Applicant: Wen-Hsuan Chang ,  David T. McKeough

Inventor： Wen-Hsuan Chang ,  David T. McKeough

IPC: C08K5/053 ,  C09D4/00 ,  C09K3/00

CPC classification number: C08K5/053 ,  C09D4/00

Abstract: Disclosed is a liquid composition comprising a mixture of (A) a hydrophobic polyol, and (B) an organosilicon-containing material. The organosilicon-containing material is substantially free of unhydrolyzed aminoalkylsilane and comprises an organosilicon-containing substance free of functional groups attached to carbon and essentially free of alkali metal ions. The organosilicon-containing substance has atoms bonded directly to silicon all of which are selected from O, N, and/or Cl. The silicon-containing substance additionally has moieties directly bonded to Si which are displaceable by reaction with water and/or alcohol. At least a part of the silicon-containing substance is hydrolyzed to a compound or a mixture of compounds which contains a residual amount of the moieties directly bonded to Si which are displaceable by reaction with water and/or alcohol.After components (A) and (B) are mixed, the composition is a homogeneous liquid which is capable of self-curing to a continuous film by reaction, with moisture and/or the hydrophobic polyol, of the residual moieties bonded directly to silicon which are displaceable by reaction with water and/or alcohol.

Abstract translation: 公开了包含（A）疏水多元醇和（B）含有机硅材料的混合物的液体组合物。 含有机硅的材料基本上不含未水解的氨基烷基硅烷，并且包含不含有连接到碳上并基本上不含碱金属离子的官能团的含有机硅的物质。 含有机硅的物质具有直接与硅键合的原子，所有这些原子都选自O，N和/或Cl。 含硅物质另外具有直接键合到Si的部分，其可以通过与水和/或醇反应而置换。 将至少一部分含硅物质水解成化合物或化合物的混合物，其中残留量的直接与Si键合的部分可通过与水和/或醇反应而置换。 在组分（A）和（B）混合后，组合物是均匀的液体，其能够通过与水分和/或疏水性多元醇反应直接结合到硅上的残余部分与硅连接而自固化， 可通过与水和/或醇的反应而置换。

公开(公告)号：US4528344A

公开(公告)日：1985-07-09

申请号：US612507

申请日：1984-05-21

Applicant: Wen-Hsuan Chang

Inventor： Wen-Hsuan Chang

IPC: C08G12/42 ,  C09D161/32 ,  C08L61/28

CPC classification number: C08G12/42 ,  C09D161/32

Abstract: Disclosed herein is an ungelled, crosslinkable, hydroxyl-group containing resin having a molecular weight of less than 4500. The ungelled, hydroxyl-group containing resin is a reaction product of components comprising (A) a nonaromatic polyol having a molecular weight of less than 230, and (B) an aminoplast.Also disclosed is a curable composition containing such hydroxyl-group containing resin.

Abstract translation: 本文公开了一种分子量小于4500的未凝胶化，可交联的含羟基的树脂。未凝胶化的含羟基树脂是包含（A）分子量小于等于或小于10的非芳族多元醇的组分的反应产物 230，（B）氨基塑料。 还公开了含有这种含羟基的树脂的可固化组合物。