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    METHODS OF MAKING SILOXY-IMINE FUNCTIONALIZED RUBBERY POLYMERS AND USES THEREOF IN RUBBER COMPOSITIONS FOR TIRES
    12.
    发明申请
    METHODS OF MAKING SILOXY-IMINE FUNCTIONALIZED RUBBERY POLYMERS AND USES THEREOF IN RUBBER COMPOSITIONS FOR TIRES 审中-公开
    制备硅氧烷官能化橡胶聚合物的方法及其在轮胎用橡胶组合物中的应用

    公开(公告)号：US20090203826A1

    公开(公告)日：2009-08-13

    申请号：US12030224

    申请日：2008-02-13

    申请人： Michael Joseph Rachita ,  Kenneth Allen Bates ,  Vanessa Marika Riedlinger ,  Tang Hong Wong

    发明人： Michael Joseph Rachita ,  Kenneth Allen Bates ,  Vanessa Marika Riedlinger ,  Tang Hong Wong

    IPC分类号： C08F36/06 ,  C08K3/00

    CPC分类号： C08C19/44 ,  B60C1/00 ,  B60C1/0016 ,  C08F2/38 ,  C08K3/013 ,  C08L15/00

    摘要： The invention includes a siloxy-imine functionalized rubbery polymer, which exhibits good reinforcing characteristics and filler dispersing effect, a method for making, and a rubber composition including the same. In one embodiment, a process for manufacturing the functionalized rubbery polymer includes polymerizing a conjugated diene monomer using an organolithium compound as an initiator in a hydrocarbon solvent. Next, an active terminal end of the polymer is reacted with a functionalized terminating agent, represented by the general formula: RCH═N(CH2)XSi(OR1)YR23-Y,   Formula (1) wherein R represents a group consisting of an aryl or substituted aryl having 6 to 18 carbon atoms, or a heterocycle or heteroaryl having 3 to 18 carbon atoms; R1 and R2 each independently represents a group having 1 to 18 carbon atoms selected from an alkyl, a cycloalkyl, an allyl, and or aryl; X is an integer from 1 to 20; and Y is an integer from 1 to 3.

    摘要翻译： 本发明包括表现出良好的增强特性和填料分散效果的甲硅烷氧基亚胺官能化橡胶状聚合物，其制备方法，以及含有它们的橡胶组合物。 在一个实施方案中，制备官能化橡胶聚合物的方法包括在烃溶剂中使用有机锂化合物作为引发剂使共轭二烯单体聚合。 接下来，聚合物的活性末端与官能化终止剂反应，由通式表示：<？in-line-formula description =“In-line Formulas”end =“lead”→RCH-N（CH2 ）XSi（OR1）YR23-Y，式（1）<？在线公式描述=“在线式”末端=“尾”→其中R表示由芳基或取代芳基组成的基团， 18个碳原子，或具有3至18个碳原子的杂环或杂芳基; R 1和R 2各自独立地表示选自烷基，环烷基，烯丙基和/或芳基的碳原子数1〜18的基团。 X为1〜20的整数; Y为1〜3的整数。

    FLUID RESISTANT HIGH TEMPERATURE HOSE
    13.
    发明申请
    FLUID RESISTANT HIGH TEMPERATURE HOSE 审中-公开
    耐流体软管

    公开(公告)号：US20120090720A1

    公开(公告)日：2012-04-19

    申请号：US12907250

    申请日：2010-10-19

    申请人： Thomas George Burrowes ,  Kenneth Allen Bates

    发明人： Thomas George Burrowes ,  Kenneth Allen Bates

    IPC分类号： F16L11/02

    CPC分类号： B32B1/08 ,  B32B5/028 ,  B32B5/10 ,  B32B5/26 ,  B32B15/02 ,  B32B25/02 ,  B32B25/10 ,  B32B25/16 ,  B32B27/12 ,  B32B27/20 ,  B32B27/322 ,  B32B2262/08 ,  B32B2264/102 ,  B32B2264/108 ,  B32B2307/536 ,  B32B2307/54 ,  B32B2597/00 ,  C08K3/04 ,  C08K5/02 ,  F16L11/082 ,  F16L11/086 ,  F16L11/088

    摘要： The present invention is based on the unexpected discovery that the fluid resistance of hoses can be greatly enhanced by adding a chlorinated paraffin to a chlorinated polyethylene elastomer or a chlorosulfonated polyethylene elastomer which is used as the tubular inner core layer of the hose. Hoses made using this approach offer the advantage of having improved resistance to modern automotive fluids, including power steering fluid, transmission fluid, and the like, without compromising flexural characteristics or burst strength. Accordingly, the hoses of this invention provide a longer service life and better reliability then hoses made utilizing conventional technology. The present invention more specifically discloses a hose which is comprised of (1) an elastomeric tubular inner core layer defining a lumen, (2) a friction layer, and (3) an elastomeric cover, wherein the elastomeric tubular inner core layer is comprised of (i) a chlorinated elastomer selected from the group consisting of epichlorohydrin, polychloroprene, chlorinated polyethylene and chlorosulfonated polyethylene, (ii) 1 phr to 50 phr of a chlorinated paraffin, and (iii) 30 phr to 120 phr of carbon black. It is typically preferred for the chlorinated elastomer to be chlorinated polyethylene or chlorosulfonated polyethylene.

    摘要翻译： 本发明基于意想不到的发现，通过将氯化石蜡加入氯化聚乙烯弹性体或用作软管的管状内核层的氯磺化聚乙烯弹性体，可以大大提高软管的流体阻力。 使用这种方法制造的软管具有改善对现代汽车流体的抵抗力的优点，包括动力转向流体，传动液体等，而不损害弯曲特性或爆裂强度。 因此，本发明的软管提供了使用常规技术的软管更长的使用寿命和更好的可靠性。 本发明更具体地公开了一种软管，其包括（1）限定内腔的弹性体管状内芯层，（2）摩擦层，和（3）弹性体盖，其中弹性管状内芯层由 （i）选自表氯醇，聚氯丁二烯，氯化聚乙烯和氯磺化聚乙烯的氯化弹性体，（ii）1phr至50phr的氯化石蜡，和（iii）30phr至120phr的炭黑。 氯化弹性体通常优选为氯化聚乙烯或氯磺化聚乙烯。