Process for producing lower olefins from methanol or dimethylether
    13.
    发明申请
    Process for producing lower olefins from methanol or dimethylether 有权
    从甲醇或二甲醚生产低级烯烃的方法

    公开(公告)号:US20070038011A1

    公开(公告)日:2007-02-15

    申请号:US11503913

    申请日:2006-08-15

    IPC分类号: C07C4/02

    摘要: The present invention provides a process for producing lower olefins from methanol or dimethyl ether. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including high operation temperature, low yield and selectivity of lower olefins as the target products, and poor stability and short regeneration period of catalyst. The present process, which is carried out under the conditions of catalytic cracking methanol and dimethyl ether and the presence of diluting gas, and adopts as a feedstock methanol, dimethyl ether or their mixture, comprises the steps of: a) letting the feedstock firstly enter a first reaction zone to contact with a first crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a first reaction effluent containing lower olefins; b) letting the first reaction effluent enter in turn at least one second reaction zone to contact with a second crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a second reaction effluent containing lower olefins; and c) separating lower olefins from the second reaction effluent; wherein the weight ratio of the diluting gas to the feedstock is 0.01-6:1, while controlling the reaction conditions.

    摘要翻译: 本发明提供了由甲醇或二甲醚生产低级烯烃的方法。 本发明主要解决的技术问题是克服现有技术中存在的缺点,包括作为目标产物的低级烯烃的高操作温度,低产率和选择性,以及催化剂的稳定性和较短的再生期。 本工艺在甲醇和二甲醚催化裂解条件下进行,稀释气体的存在,采用甲醇,二甲醚或其混合物为原料,包括以下步骤:a)使原料首先进入 与第一结晶硅铝酸盐催化剂接触的第一反应区,其具有至少10的SiO 2 / Al 2 O 3 N 3摩尔比,至少为10,至 从而产生含有低级烯烃的第一反应流出物; b)使第一反应流出物依次进入至少一个第二反应区以与具有SiO 2 / Al 2 O 3的第二结晶硅铝酸盐催化剂接触 摩尔比为至少10,从而产生含有低级烯烃的第二反应流出物; 和c)从第二反应流出物分离低级烯烃; 其中稀释气体与原料的重量比为0.01-6:1,同时控制反应条件。