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    PROCESS FOR DERIVATIZING CARBON NANOTUBES WITH DIAZONIUM SPECIES AND COMPOSITIONS THEREOF
    11.
    发明申请
    PROCESS FOR DERIVATIZING CARBON NANOTUBES WITH DIAZONIUM SPECIES AND COMPOSITIONS THEREOF 有权
    用二氧化碳衍生碳纳米管的方法及其组合物

    公开(公告)号：US20090301896A1

    公开(公告)日：2009-12-10

    申请号：US11840433

    申请日：2007-08-17

    申请人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    发明人： James M. Tour ,  Jeffrey L. Bahr ,  Jiping Yang

    IPC分类号： C25B3/00 ,  B82B3/00

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/36 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2002/84 ,  C01P2002/88 ,  C01P2004/04 ,  C01P2004/13 ,  C07C245/20 ,  C07C321/26 ,  C07C321/28 ,  C08K9/04 ,  C09C1/48 ,  C09C1/56 ,  C09C1/565 ,  H01G11/36 ,  Y02E60/13 ,  Y10S977/788 ,  Y10S977/847 ,  Y10T428/13 ,  Y10T428/30

    摘要： Methods for the chemical modification of carbon nanotubes involve the derivatization of multi- and single-wall carbon nanotubes, including small diameter (ca. 0.7 nm) single-wall carbon nanotubes, with diazonium species. The method allows the chemical attachment of a variety of organic compounds to the side and ends of carbon nanotubes. These chemically modified nanotubes have applications in polymer composite materials, molecular electronic applications, and sensor devices. The methods of derivatization include electrochemical induced reactions, thermally induced reactions, and photochemically induced reactions. Moreover, when modified with suitable chemical groups, the derivatized nanotubes are chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as, mechanical strength or electrical conductivity) to the properties of the composite material as a whole. Furthermore, when modified with suitable chemical groups, the groups can be polymerized to form a polymer that includes carbon nanotubes.

    摘要翻译： 用于碳纳米管的化学修饰的方法涉及包括小直径（约0.7nm）单壁碳纳米管与重氮物质的多壁和单壁碳纳米管的衍生化。 该方法允许将各种有机化合物化学连接到碳纳米管的侧面和末端。 这些化学改性的纳米管可用于聚合物复合材料，分子电子应用和传感器装置。 衍生化的方法包括电化学诱导反应，热诱导反应和光化学诱导反应。 此外，当用合适的化学基团改性时，衍生的纳米管与聚合物基质化学相容，允许将纳米管的性质（例如机械强度或电导率）转移到复合材料的整体性能上。 此外，当用合适的化学基团改性时，基团可以聚合形成包括碳纳米管的聚合物。

    Selected acid generating agents and their use in processes for imaging radiation-sensitive elements
    13.
    发明申请
    Selected acid generating agents and their use in processes for imaging radiation-sensitive elements 失效
    选择的酸产生剂及其在辐射敏感元件成像过程中的应用

    公开(公告)号：US20030219673A1

    公开(公告)日：2003-11-27

    申请号：US10155696

    申请日：2002-05-24

    发明人： Ting Tao ,  Jianbing Huang

    IPC分类号： G03F007/016

    CPC分类号： B41C1/1008 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41C2210/266 ,  C07C245/20 ,  C07C305/06 ,  G03F7/0045 ,  G03F7/038

    摘要： An acid generating agent useful for imaging photosensitive elements selected from compounds of formulae (I), (II) and (III). 1 wherein R1 is selected from the group consisting of an unsubstituted and substituted hydrocarbon or aryl group; wherein X is selected from the group consisting of oxygen, sulfur and selenium; wherein Y is selected from the group consisting of sulfur, selenium and tellurium; wherein Ar1 is selected from the group consisting of an unsubstituted and substituted aryl group; wherein R2, R3 and R4 are individually selected from the group consisting of an unsubstituted and substituted hydrocarbon or aryl group or any two of them are bonded together to form a ring structure; and wherein R5 and R6 are individually selected from the group of an unsubstituted and substituted hydrocarbon or aryl group, or are bonded to each other to form a ring structure.

    摘要翻译： 用于成像从式（I），（II）和（III）的化合物中选择的感光元件的酸产生剂。 其中R 1选自未取代和取代的烃或芳基; 其中X选自氧，硫和硒; 其中Y选自硫，硒和碲; 其中Ar 1选自未取代和取代的芳基; 其中R 2，R 3和R 4分别选自未取代的和取代的烃基或芳基，或者它们中的任意两个键合在一起形成环结构; 并且其中R 5和R 6分别选自未取代和取代的烃基或芳基，或者彼此键合形成环结构。

    Novel 4-dedimethylaminotetracycline derivatives
    14.
    发明申请
    Novel 4-dedimethylaminotetracycline derivatives 失效

    公开(公告)号：US20030195174A1

    公开(公告)日：2003-10-16

    申请号：US10274841

    申请日：2002-10-18

    发明人： Robert A. Ashley ,  Joseph J. Hlavka

    IPC分类号： A61K031/65 ,  C07C237/26

    CPC分类号： C07C235/82 ,  C07C237/26 ,  C07C245/20 ,  C07C247/18 ,  C07C329/20 ,  C07C2603/46 ,  C07D295/13

    摘要： The present invention provides new chemically modified 4-dedimethylaminotetracycline compounds that can be substituted with aryl, alkenyl, or alkynyl groups. The 7, 8, and/or 9 positions and methods for preparing such compounds. Other tetracycline compounds include the 4-dedimethylaminotetracycline derivatives with an oxime group, NH-Alkyl, or NnullNH-Alkyl group substituted at the C4 position as well as C2 Mannich derivatives. The present invention also provides a method of treating a mammal suffering from conditions or diseases by administering to the mammal an effective amount of the new chemically modified tetracycline compounds.

    Diazonium ion assay reagents and methods for their use
    15.
    发明授权
    Diazonium ion assay reagents and methods for their use 失效
    重氮离子测定试剂及其使用方法

    公开(公告)号：US5935861A

    公开(公告)日：1999-08-10

    申请号：US975796

    申请日：1997-11-21

    申请人： Matthew F. Gnezda ,  Tracey E. Gordon ,  Jennifer S. Bournique ,  Sharanpal K. Walker

    发明人： Matthew F. Gnezda ,  Tracey E. Gordon ,  Jennifer S. Bournique ,  Sharanpal K. Walker

    IPC分类号： C07C245/20 ,  G01N21/77 ,  G01N33/72 ,  G01N33/00

    CPC分类号： C07C245/20 ,  G01N33/72 ,  Y10T436/10 ,  Y10T436/103332 ,  Y10T436/146666

    摘要： Diazonium ions which are useful as reagents for the assay of bilirubin content in a sample, such as a body fluid sample, are provided. In one preferred embodiment, 2-methyl-3-nitroaniline diazonium ion is provided, having the structure: ##STR1## Also provided are reagent compositions including the diazonium ions. The reagent compositions may be in liquid or solid form, and further may include other components, such as buffers, carriers, and solubilizers. Salts including the diazonium ion and a counteranion also are provided. Also provided are methods of using the diazonium ions in assays to detect or quantitate bilirubin present in a sample such as a body fluid sample. Using the assays, the amount of direct, indirect, and total bilirubin in a sample may be accurately and reproducibly detected, and optionally correlated with the presence or absence of any of a variety of diseases or disorders of organs such as the liver, gall bladder or intestines. Using the assays, a wide range of different body fluid samples, such as urine, plasma or serum samples may be tested, and the interference in the assay from other components of the sample may be minimized.

    摘要翻译： 提供了可用作样品中诸如体液样品中胆红素含量测定试剂的重氮离子。 在一个优选的实施方案中，提供2-甲基-3-硝基苯胺重氮离子，其具有以下结构：还提供了包含重氮离子的试剂组合物。 试剂组合物可以是液体或固体形式，并且还可以包括其它组分，例如缓冲液，载体和增溶剂。 还提供了包括重氮离子和抗衡阴离子的盐。 还提供了在测定中使用重氮离子来检测或定量存在于样品例如体液样品中的胆红素的方法。 使用测定法，样品中直接，间接和总胆红素的量可以被准确和可重复地检测，并且可选地与各种各样的器官疾病或病症的存在或不存在相关，例如肝脏，胆囊 或肠。 使用测定法，可以测试各种不同的体液样品，例如尿液，血浆或血清样品，并且可以将来自样品的其它组分的测定中的干扰降到最小。

    Process for diazotizing aromatic amines
    18.
    发明授权
    Process for diazotizing aromatic amines 失效
    去氧化芳香胺的方法

    公开(公告)号：US3888841A

    公开(公告)日：1975-06-10

    申请号：US27025672

    申请日：1972-07-10

    申请人： HOECHST AG

    发明人： SPIETSCHKA ERNST ,  LANDLER JOSEF

    IPC分类号： C07C20060101 ,  C07D235/26 ,  C07C113/04

    CPC分类号： C07C245/20

    摘要： A process for diazotizing amines in organic solvents is shown. A solution or suspension of a diazotizable amine compound such as p-toluidine or 2-naphthylamine in an excess of a heterocyclic base which may be for example pyridine, quinoline, picoline, lutidine or mixtures thereof and which is inert toward the action of compounds capable of splitting off nitrosyl groups, is diazotized by contacting it with a compound capable of splitting off nitrosyl groups such as nitrosylsulfuric acid or nitrosyl chloride.