Increasing the octane of olefinic gasolines using disproportionation alkylation and reforming steps
    11.
    发明授权
    Increasing the octane of olefinic gasolines using disproportionation alkylation and reforming steps 失效
    使用分解烷烃和改性步骤增加烯烃汽油的十一烷基

    公开(公告)号:US3763032A

    公开(公告)日:1973-10-02

    申请号:US3763032D

    申请日:1971-12-10

    Inventor: BANKS R

    CPC classification number: C10G59/06

    Abstract: A process for converting an olefinic gasoline to a higher octane value gasoline comprises the steps of subjecting the feed gasoline, or a fraction thereof, to olefin disproportionation in the presence of added ethylene to convert some of the heavier olefins to lighter olefins, disproportionating propylene produced by the first step to ethylene and butenes, alkylating the butenes with isobutane, catalytically reforming a C5+ fraction from the first step, and recombining the alkylate and reformate with unconverted gasoline fractions to form the higher octane gasoline.

    Process for improving the production of benzene and toluene

    公开(公告)号:US11453829B2

    公开(公告)日:2022-09-27

    申请号:US16767939

    申请日:2018-11-16

    Abstract: The invention relates to a process for the production of C6-C7 aromatic compounds from a hydrocarbon feedstock of naphtha type comprising a step of fractionating (2) the feedstock in order to obtain an upper stream and a lower stream, a step of catalytic reforming of the upper stream (6) and of the lower stream (9), a step of recombining (15) the reformate effluents obtained, a step of recontacting (16) and a step of stabilizing (19) the stabilized reformate effluents and a step of separating (22) the raffinate in order to recover C6 and C7 hydrocarbon compounds.

    Optimized reactor configuration for optimal performance of the aromax catalyst for aromatics synthesis

    公开(公告)号:US11149211B2

    公开(公告)日:2021-10-19

    申请号:US16860638

    申请日:2020-04-28

    Abstract: A naphtha reforming reactor system comprising a first reactor comprising a first inlet and a first outlet, wherein the first reactor is configured to operate as an adiabatic reactor, and wherein the first reactor comprises a first naphtha reforming catalyst; and a second reactor comprising a second inlet and a second outlet, wherein the second inlet is in fluid communication with the first outlet of the first reactor, wherein the second reactor is configured to operate as an isothermal reactor, and wherein the second reactor comprises a plurality of tubes disposed within a reactor furnace, a heat source configured to heat the interior of the reactor furnace; and a second naphtha reforming catalyst disposed within the plurality of tubes, wherein the first naphtha reforming catalyst and the second naphtha reforming catalyst are the same or different.

    Apparatus and method for investigating naphtha reforming processes

    公开(公告)号:US10774275B2

    公开(公告)日:2020-09-15

    申请号:US15541403

    申请日:2015-12-22

    Abstract: An apparatus and a method are used for investigating the naphtha reforming process in catalyst test devices with reactors arranged in parallel. The apparatus has a plurality of reactors arranged in parallel with reaction chambers (R1, R2, . . . ), a product fluid supply, a process control, and at least one analysis unit. Each individual reactor has an outlet line for the product fluid stream, wherein the analysis unit is operatively connected to each outlet line for the product fluid stream and the apparatus is functionally connected to the control of the apparatus. In carrying out the method, naphtha-containing reactant fluid streams are brought into contact with catalysts in the individual reactors and the product fluid streams are subsequently supplied to the online analysis unit from the respective outlet lines of the individual reactors and analyzed. Using the evaluation of the online analytical characterization data, the process parameters of the respective reactor unit are adapted. The process steps of analytical characterization, evaluation, and adaptation of process parameters are repeated for the duration of the investigation.

    Aromatic production apparatus
    17.
    发明授权
    Aromatic production apparatus 失效
    芳香生产设备

    公开(公告)号:US07727490B2

    公开(公告)日:2010-06-01

    申请号:US11840461

    申请日:2007-08-17

    Applicant: Lubo Zhou

    Inventor: Lubo Zhou

    CPC classification number: B01D3/143 B01J2219/00006

    Abstract: One exemplary embodiment can include an aromatic production apparatus. The aromatic production apparatus can include a first fractionation zone, a second fractionation zone, and a third fractionation zone. Generally, the first fractionation zone can provide a stream rich in an aromatic C8− and a stream rich in an aromatic C9, the second fractionation zone can separate at least one of benzene and optionally toluene from a transalkylation zone effluent and provide a feed to the first fractionation zone, and the third fractionation zone can receive the stream rich in the aromatic C8− from the first fractionation zone. An effluent from the third fractionation zone can be directly comprised in a para-xylene-separation zone feed to a para-xylene-separation zone.

    Abstract translation: 一个示例性实施方案可以包括芳族生产装置。 芳香族生产装置可以包括第一分馏区,第二分馏区和第三分馏区。 通常,第一分馏区可以提供富含芳族C 8 - 和富含芳族C 9的物流的物流,第二分馏区可以从烷基转移区流出物中分离出苯和任选的甲苯中的至少一种,并且向 第一分馏区,第三分馏区可以从第一分馏区接收富含芳族C8-的物流。 来自第三分馏区的流出物可以直接包含在对二甲苯分离区进料到对二甲苯分离区中。

    Split-feed two-stage parallel aromatization for maximum para-xylene yield
    18.
    发明授权
    Split-feed two-stage parallel aromatization for maximum para-xylene yield 失效
    分离进料两阶段平行芳构化,以获得最大的对二甲苯产率

    公开(公告)号:US6051128A

    公开(公告)日:2000-04-18

    申请号:US470845

    申请日:1995-06-06

    CPC classification number: C10G59/06

    Abstract: A full boiling hydrocarbon feed is reformed to enhance para-xylene and benzene yields. First, the hydrocarbon feed is separated into a C.sub.5- cut, a C.sub.6 -C.sub.7 cut, and a C.sub.8+ cut. The C.sub.6 -C.sub.7 cut has less than 5 lv. % of C.sub.8+ hydrocarbon, and the C.sub.8+ cut has less than 10 lv. % of C.sub.7- hydrocarbon. The C.sub.6 -C.sub.7 cut is subjected to catalytic aromatization at elevated temperatures in a first reformer in the presence of hydrogen and using a non-acidic catalyst comprising at least one Group VIII metal and a non-acidic zeolite support to produce a first reformate stream; and the C.sub.8+ cut is subjected to catalytic aromatization at elevated temperatures in a second reformer in the presence of hydrogen and using an acidic catalyst comprising at least one Group VIII metal and a metallic oxide support to produce a second reformate stream. Less than 20 wt. % of the total amount of C.sub.8 aromatics produced in the first and second reformer is ethylbenzene, and more than 20 wt. % of the total amount of xylenes produced in the first and second reformer are para-xylenes.

    Abstract translation: 改变全沸腾烃进料以提高对二甲苯和苯产率。 首先,将烃进料分离成C5切割,C6-C7切割和C8 +切割。 C6-C7切割小于5 lv。 %的C8 +烃,而C8 +馏分的含量小于10 lv。 %的碳氢化合物。 C 6 -C 7馏分在高温存在下在第一重整器中在升高的温度下进行催化芳构化,并使用包含至少一种Ⅷ族金属和非酸性沸石载体的非酸性催化剂以产生第一重整产物流; 并且在氢的存在下,使用包含至少一种第Ⅷ族金属和金属氧化物载体的酸性催化剂,在高温下在C8的第二重整器中使C8 +馏分进行催化芳构化以产生第二重整产物流。 少于20wt 在第一和第二重整器中产生的C8芳族化合物的总量的%为乙苯,并且大于20wt。 在第一和第二重整器中产生的二甲苯的总量的百分比是对二甲苯。

    Selective upgrading of naphtha
    19.
    发明授权
    Selective upgrading of naphtha 失效
    石脑油选择性升级

    公开(公告)号:US5401388A

    公开(公告)日:1995-03-28

    申请号:US117466

    申请日:1993-09-07

    CPC classification number: C10G59/06

    Abstract: A process combination is disclosed to selectively upgrade naphtha to obtain gasoline which is in accordance with current standards for reformulated fuels. A naphtha feedstock is fractionated to selectively direct light naphtha to isomerization or blending, a head-cut fraction to reforming, and a heavy potion to selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy potion of the synthesis naphtha is processed by reforming. Light naphtha may be isomerized, with or without recycle of low-octane components of the product. A gasoline component is blended from light, synthesis, and reformate products from the process combination.

    Abstract translation: 公开了一种方法组合以选择性地升级石脑油以获得符合目前重新配制的燃料标准的汽油。 将石脑油原料分馏以选择性地将轻石脑油引导至异构化或共混,将头馏分转化为重馏分,并将重质部分引入选择性异链烷烃合成以产生轻质和重质合成石脑油和异丁烷。 通过重整处理合成石脑油的重药剂。 轻石脑油可以异构化,有或没有产物的低辛烷值组分的再循环。 来自工艺组合的轻质,合成和重整产物的汽油组分混合。

Patent Agency Ranking