摘要:
A thermostable polymer electrolyte gel containing an acrylonitrile polymer, an electrolyte and a solvent, the acrylonitrile polymer having an acrylonitrile content of from 89 wt % to 98 wt % and meeting the following relationship:1,040,000-(A.times.10,000).ltoreq.B.ltoreq.1,490,000-(A.times.10,000)where A is the acrylonitrile content in wt % and B is the weight average molecular weight of the acrylonitrile polymer, the polymer electrolyte gel having an ion conductivity of 10.sup.-3 S/cm or higher at 20.degree. C., exhibiting the "retention of shape" in a thermostability test, and containing the acrylonitrile polymer in a proportion of from 3 wt % to 9 wt %. The thermostable polymer electrolyte gel can be produced by dissolving an acrylonitrile polymer and an electrolyte in a solvent to prepare a solution of the polymer, and cooling the polymer solution to a temperature of 0.degree. C. or lower.
摘要:
A new non-aqueous electrolyte system for use in batteries, capacitors and electrochromic displays, and consisting essentially of an alkali or ammonium salt, a solvent mixture, and optionally a polymer is disclosed. The new system is characterized in that the solvent mixture comprises a mixture of ethylene carbonate (EC) and -valerolactone (-VL), optionally containing one or more additional solvents selected from other organic carbonates, other lactones, esters and glymes, said system optionally being confined a separator. The electrolyte system can be applied in a broad voltage range, has a conductivity higher than 10.sup.-3 S/cm at room temperature, and shows a high stability against reduction. The improved stability towards reduction is mirrored in a cycling efficiency which is superior to the cycling efficiency of known non-aqueous electrolyte systems.
摘要:
A composite electrolyte comprises (a) surface modified fumed silica filler, wherein the surface modified fumed silica comprises polymerizable groups on the surface thereof, the polymerizable groups being bonded to each other such that the surface modified fumed silica filler is crosslinked in a three-dimensional structure; (b) a dissociable lithium salt; and (c) a bulk medium which contains the surface modified fumed silica filler and the dissociable lithium salt. An electrochemical cell comprises an anode, a cathode, and a composite electrolyte dispersed between the anode and cathode.
摘要:
An electric battery, for example, a zinc-bromine battery for an automobile, is protected against leakage of electrolyte, in particular against bromine liberated during a crash. For this purpose, the reservoirs provided for the electrolyte are filled with a sponge-like material that stores the electrolyte. Alternatively, or in addition, the reservoirs are surrounded by a protective sheathing made of a material that binds the escaping electrolyte, in particular through chemical reaction.
摘要:
An electrolyte system (40) for use in connection with an electrochemical cell (10). The cell (10) includes a positive electrode (20) and a negative electrode (30) with the electrolyte system (40) disposed therebetween. The electrolyte system is a polymer gel electrolyte system including a liquid electrolyte species which may be either aqueous or non-aqueous and a polymer gel electrolyte support structure. The polymer gel electrolyte support structure includes at least an non woven first polymer and a second polymer which is adapted to absorb the electrolyte active species. The first polymer is a fibrous polymer to reduce swelling of the gel electrolyte in the presence of the electrolyte active species, and further to enhance mechanical integrity of the support structure.
摘要:
An electrolyte system (40) for use in connection with an electrochemical cell (10). The cell (10) includes a positive (20) and a negative (30) electrode, and an electrolyte system (40) disposed therebetween. The electrolyte system includes a polymer matrix fabricated of a polyacrylic acid or polyacrylic acid derivative polymeric material. The polymer material is adapted to engage in electroactive species. Examples of electroactive species may be either an acid or a base electrolyte, such as KOH or H.sub.2 SO.sub.4.
摘要翻译:一种用于与电化学电池(10)结合使用的电解质系统(40)。 电池(10)包括正极(20)和负极(30),以及设置在其间的电解液系统(40)。 电解质系统包括由聚丙烯酸或聚丙烯酸衍生物聚合物材料制成的聚合物基体。 聚合物材料适于与电活性物质接合。 电活性物质的实例可以是酸或碱性电解质,例如KOH或H 2 SO 4。
摘要:
A solid electrolyte for use in a reference electrochemical half cell, the electrolyte comprising an insulative binder forming a matrix, a particulate salt dispersed within the binder and immobilized by the binder, and a hydrophilic polymer network disposed within the binder in an amount sufficient to effect ion diffusion within the electrolyte.
摘要:
Disclosed are immobilized electrolyte membranes having a high electric conductivity and a high mechanical strength, where an ionic conductor such as a polymer electrolyte or an ion-exchange resin is immobilized in pores of a porous solid polymer membrane, particularly of polyolefin having a weight average molecular weight of not less than 5.times.10.sup.5, the porous solid polymer membrane having a thickness of 0.1 .mu.m to 50 .mu.m, a porosity of 40% to 90%, a tensile strength of not less than 200 kg/cm.sup.2, and an average permeable pore diameter of 0.001 .mu.m to 0.1 .mu.m.
摘要:
This invention is directed to compositions having viscosity aging and/or gas-release properties comprising 4 to 20 weight parts of an alkaline material, particularly an aqueous solution of sodium hydroxide or potassium hydroxide, and 0.05 to 5 weight parts of a suspending copolymer of a major proportion of an acrylic acid and a minor proportion of a comonomer, particularly selected from acrylamide, N-lauryl methacrylamide, lauryl acrylate, 2-ethylhexyl methacrylate, lauryl methacrylate, and stearyl methacrylate. Such compositions can also include 40 to 80 weight parts of an electrochemically active metal, particularly zinc, suspended in the alkaline material by means of said copolymer whereby said composition functions as a component part of an electrochemical cell containing a cathode, an anode, and an electrolyte wherein said metal serves as the anode and said alkaline material serves as the electrolyte.