公开(公告)号：US4122125A

公开(公告)日：1978-10-24

申请号：US739766

申请日：1976-11-08

Applicant: Timothy P. Murtha ,  William A. Jones ,  Ernest A. Zuech ,  Marvin M. Johnson

Inventor： Timothy P. Murtha ,  William A. Jones ,  Ernest A. Zuech ,  Marvin M. Johnson

IPC: B01J29/14 ,  C07C2/74 ,  C07C15/00

CPC classification number: B01J29/14 ,  C07C2/74 ,  C07C2529/14

Abstract: An aromatic hydrocarbon is contacted under hydroalkylation conditions and in the presence of hydrogen with a catalyst comprising at least one ruthenium compound and at least one nickel compound supported on a calcined, acidic, rare earth-treated crystalline zeolite.

Abstract translation: 芳烃在加氢烷基化条件下和氢存在下与包含至少一种钌化合物的催化剂和至少一种负载在煅烧，酸性，稀土处理的结晶沸石上的镍化合物接触。

公开(公告)号：US4010217A

公开(公告)日：1977-03-01

申请号：US548582

申请日：1975-02-10

Applicant: Ernest A. Zuech

Inventor： Ernest A. Zuech

IPC: B01J31/14 ,  B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07C6/04 ,  C07C6/06 ,  C07C3/62

CPC classification number: B01J31/143 ,  B01J31/16 ,  B01J31/181 ,  B01J31/2234 ,  B01J31/2295 ,  B01J31/2404 ,  C07C6/04 ,  C07C6/06 ,  B01J2531/64 ,  B01J2531/66

Abstract: A process for the conversion of olefinic hydrocarbons according to the olefin reaction (e.g., the olefin disproportionation reaction) by contacting the olefinic hydrocarbon with a catalyst comprising a coordination compound of molybdenum or tungsten complexed with NO, together with an organoaluminum adjuvant.

Abstract translation: 通过使烯烃与包含与NO络合的钼或钨的配位化合物的催化剂与有机铝佐剂接触，根据烯烃反应（例如烯烃歧化反应）转化烯烃的方法。

公开(公告)号：US3670043A

公开(公告)日：1972-06-13

申请号：US3670043D

申请日：1970-03-23

Applicant: DONALD H KUBICEK ,  ERNEST A ZUECH ,  PHILLIPS PETROLEUM CO

Inventor： KUBICEK DONALD H ,  ZUECH ERNEST A

IPC: B01J31/14 ,  B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J31/26 ,  C07C6/04 ,  C07C6/06 ,  C07C3/62

CPC classification number: C07C6/06 ,  B01J31/143 ,  B01J31/181 ,  B01J31/1875 ,  B01J31/1895 ,  B01J31/2234 ,  B01J31/2295 ,  B01J31/24 ,  B01J2231/543 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C07C6/04

Abstract: Olefins are converted into other olefins having different numbers of carbon atoms by contact with a homogenous catalyst active for disproportionating an olefin into other olefins of both higher and lower carbon atoms comprising a coordination complex of zirconium, titanium or hafnium together with an aluminum-containing catalytic adjuvant.

Abstract translation: 通过与烯烃反应的均相催化剂接触，将烯烃转化为具有不同数目碳原子的其它烯烃，所述催化剂用于将烯烃歧化成包含锆，钛或铪的配位络合物与含铝催化剂的高碳原子和低碳原子的其它烯烃 佐剂。

公开(公告)号：US4386229A

公开(公告)日：1983-05-31

申请号：US307452

申请日：1981-10-01

Applicant: Louis F. Heckelsberg ,  William T. Nelson ,  Sidney Schiff ,  Ernest A. Zuech

Inventor： Louis F. Heckelsberg ,  William T. Nelson ,  Sidney Schiff ,  Ernest A. Zuech

IPC: B01J27/12 ,  C07C2/20 ,  C07C6/04 ,  C07C9/22 ,  C07C11/02 ,  C07C1/16

CPC classification number: C07C9/22 ,  B01J27/12 ,  C07C11/02 ,  C07C2/20 ,  C07C6/04 ,  C07C2523/36 ,  C07C2527/08 ,  C07C2531/02

Abstract: Internal olefins such as those obtained from a disproportionation of 1-olefins like 1-decene are dimerized over a promoted boron trifluoride catalyst to yield oils useful as lubricant basestock.

公开(公告)号：US4357257A

公开(公告)日：1982-11-02

申请号：US894069

申请日：1978-04-06

Applicant: Yulin Wu ,  Ernest A. Zuech

Inventor： Yulin Wu ,  Ernest A. Zuech

IPC: B01F3/12 ,  B01J13/00

CPC classification number: B01J13/0026 ,  B01F3/1214

Abstract: A low viscosity slurry is prepared by first making a powder such that the shape of the particles of the powder is granular and then mixing the powder and a suitable dispersant.

Abstract translation: 通过首先制备粉末使得粉末颗粒的形状为粒状，然后将粉末和合适的分散剂混合来制备低粘度浆料。

公开(公告)号：US4268699A

公开(公告)日：1981-05-19

申请号：US101378

申请日：1979-12-07

Applicant: Timothy P. Murtha ,  Ernest A. Zuech

Inventor： Timothy P. Murtha ,  Ernest A. Zuech

IPC: B01J29/068 ,  C07C2/74 ,  C07C5/03 ,  C07C5/10

CPC classification number: B01J29/068 ,  C07C2/74 ,  C07C2529/072

Abstract: Hydroalkylation of aromatic hydrocarbons using an acidic crystalline zeolite type support having ruthenium and nickel thereon, the nickel having been placed thereon responsive to correlation of hydroalkylation selectivity and the amount of alkali metal or alkaline earth metal ion removed from the support during cation exchange when preparing a catalyst. In one embodiment benzene is converted to cyclohexylbenzene.

Abstract translation: 使用其上具有钌和镍的酸性结晶沸石型载体，其上放置有镍的方法，其中的镍已经被放置在其上，其响应于加氢烷基选择性与在阳离子交换期间从载体上除去的碱金属或碱土金属离子的量的相关性， 催化剂。 在一个实施方案中，将苯转化为环己基苯。

公开(公告)号：US4246177A

公开(公告)日：1981-01-20

申请号：US50854

申请日：1979-06-21

Applicant: Yulin Wu ,  Ernest A. Zuech

Inventor： Yulin Wu ,  Ernest A. Zuech

IPC: C07D309/18

CPC classification number: C07D309/18

Abstract: Dihydropyrans, such as 3,4-dihydro-4-methyl-2[H]-pyran, are prepared from unsaturated alcohols, such as 3-methyl-3-buten-1-ol, by reaction with carbon monoxide and hydrogen employing a Group VIII or VIB catalyst.

Abstract translation: 二氢吡喃如3,4-二氢-4-甲基-2 [H] - 吡喃由不饱和醇如3-甲基-3-丁烯-1-醇通过与一氧化碳和氢气反应制备，采用 VIII族或VIB族催化剂。

公开(公告)号：US4178269A

公开(公告)日：1979-12-11

申请号：US866135

申请日：1977-12-30

Applicant: Timothy P. Murtha ,  Ernest A. Zuech

Inventor： Timothy P. Murtha ,  Ernest A. Zuech

IPC: B01J29/12 ,  B01J29/14 ,  C07C2/74 ,  B01J27/06 ,  B01J29/06

CPC classification number: B01J29/14 ,  B01J29/12 ,  C07C2/74 ,  C07C2529/14

Abstract: An aromatic hydrocarbon is contacted under hydroalkylation conditions and in the presence of hydrogen with a composition comprising at least one platinum compound supported on a calcined, acidic, nickel and rare earth-treated crystalline zeolite which additionally has a halide content sufficient to promote the selectivity of the composition to produce a desired cycloalkyl aromatic hydrocarbon.

Abstract translation: 在加氢烷基化条件下和在氢的存在下使芳族烃与包含至少一种负载在煅烧，酸性，镍和稀土处理的结晶沸石上的铂化合物的组合物接触，所述组合物还具有足以促进 所述组合物产生所需的环烷基芳族烃。

公开(公告)号：US4177165A

公开(公告)日：1979-12-04

申请号：US865158

申请日：1977-12-28

Applicant: Timothy P. Murtha ,  Ernest A. Zuech

Inventor： Timothy P. Murtha ,  Ernest A. Zuech

IPC: B01J29/12 ,  B01J29/14 ,  C07C2/74 ,  B01J29/06

CPC classification number: B01J29/14 ,  B01J29/12 ,  C07C2/74 ,  C07C2529/14 ,  Y02P20/588

Abstract: An aromatic hydrocarbon is contacted under hydroalkylation conditions and in the presence of hydrogen with a composition comprising at least one rhodium or palladium compound or mixture thereof supported on a calcined, acidic, nickel and rare earth-treated crystalline zeolite.

Abstract translation: 芳烃在加氢烷基化条件下和氢的存在下与包含至少一种负载在煅烧，酸性，镍和稀土处理的结晶沸石上的铑或钯化合物或其混合物组成。

公开(公告)号：US4171245A

公开(公告)日：1979-10-16

申请号：US802228

申请日：1977-06-01

Applicant: Timothy P. Murtha ,  Ernest A. Zuech

Inventor： Timothy P. Murtha ,  Ernest A. Zuech

IPC: B01D3/40 ,  C07C37/80 ,  C07C45/83

CPC classification number: C07C37/80 ,  B01D3/40 ,  C07C45/83

Abstract: Acid catalyzed cleavage products of hydrocarbyl aromatic hydroperoxides are subjected to extractive distillation employing a hydrocarbon solvent. In a specific embodiment a mixture containing cyclohexylbenzene, phenol and cyclohexanone obtained from the acid catalyzed cleavage of cyclohexylbenzene hydroperoxide is subjected to extractive distillation employing hexadecane.

Abstract translation: 使用烃溶剂对烃基芳族氢过氧化物的酸催化裂解产物进行萃取蒸馏。 在一个具体的实施方案中，将由环己基苯氢过氧化物的酸催化裂解获得的环己基苯，苯酚和环己酮的混合物用十六烷进行萃取蒸馏。