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    Regulating the growth of plants and controlling weeds with carbonyl-substituted azabicycloalkanes
    21.
    发明授权
    Regulating the growth of plants and controlling weeds with carbonyl-substituted azabicycloalkanes 失效
    调节植物的生长和用羰基取代的氮杂双环烷烃控制杂草

    公开(公告)号：US3941579A

    公开(公告)日：1976-03-02

    申请号：US395885

    申请日：1973-09-10

    申请人： Elmar Sturm ,  Hans Joerg Cellarius ,  Christian Vogel

    发明人： Elmar Sturm ,  Hans Joerg Cellarius ,  Christian Vogel

    IPC分类号： C07D209/08 ,  A01N9/22

    CPC分类号： C07D209/08

    摘要： Substituted azabicycloalkanes of the formula I ##EQU1## wherein R represents an alkyl radical which contains 2 or 3 carbon atoms and is substituted by chlorine or a straight-chain or branched alkenyl radical containing 3 or 4 carbon atoms, R.sub.1 and R.sub.2 represent hydrogen or the one represents methyl and the other represents hydrogen, and n is the number 1 or 2, may be used for influencing the growth of plants, preferably for combating weeds in rice-cultures.

    摘要翻译： 取代的式I（CH 2）n的氮杂双环烷烃ANGLE CH-R2（I）N | CO-SR其中R表示含有2或3个碳原子并被氯或含有直链或支链烯基的烷基取代的烷基 3或4个碳原子，R1和R2代表氢或一个代表甲基，另一个代表氢，n是数字1或2，可用于影响植物的生长，优选用于防治水稻培养物中的杂草。

    5-esters of milbemycins for controlling parasitic pests
    22.
    发明授权
    5-esters of milbemycins for controlling parasitic pests 失效
    用于控制寄生虫害的米尔倍霉素的5-酯

    公开(公告)号：US4778809A

    公开(公告)日：1988-10-18

    申请号：US895979

    申请日：1986-08-13

    申请人： Peter Maienfisch ,  Elmar Sturm

    发明人： Peter Maienfisch ,  Elmar Sturm

    IPC分类号： C07D493/22 ,  A01N43/90 ,  A23K20/195 ,  A61K31/365 ,  A61P33/10 ,  C07H19/01

    CPC分类号： C07H19/01 ,  A01N43/90 ,  A23K20/195

    摘要： The invention relates to ecto- and endoparasitic milbemycins of formula I ##STR1## wherein R is methyl, ethyl, isopropyl or sec-butyl;R.sub.1 is hydrogen, fluorine or C.sub.1 -C.sub.4 alkyl;R.sub.2 is one of the groups ##STR2## in which formulaeis a value from 2 to 6;X is oxygen or sulfur;R.sub.3 is halogen; andR.sub.4 is hydrogen, C.sub.1 -C.sub.12 alkoxy, C.sub.3 -C.sub.7 cycloalkoxy or C.sub.2 -C.sub.6 alkenyloxy; or C.sub.1 -C.sub.18 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkoxy, hydroxy and/or COOG, G being hydrogen, an alkali metal cation or an alkaline earth metal cation; or R.sub.4 is C.sub.3 -C.sub.7 cycloalkyl which is unsubstituted or substituted by halogen and/or C.sub.1 -C.sub.4 alkyl;C.sub.2 -C.sub.18 alkenyl which is unsubstituted or substituted by halogen;C.sub.2 -C.sub.18 alkynyl which is unsubstituted or substituted by halogen;phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl C.sub.1 -C.sub.4 alkoxy, nitro, cyano and/or C.sub.1 -C.sub.4 haloalkyl; or a 5- or 6-membered unsaturated or saturated heterocyclic ring system which contains one to three hetero atoms selected from the series consisting of nitrogen, oxygen and sulfur and which is unsubstituted or substituted by oxo and/or by one to three substituents selected from halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy and/or C.sub.1 -C.sub.4 haloalkyl;to the use thereof in agriculture and to the preparation thereof by esterifying the 5-OH-milbemycins on which they are based.

    摘要翻译： 本发明涉及式I的异位和内寄生米尔倍霉素（I），其中R是甲基，乙基，异丙基或仲丁基; R1是氢，氟或C1-C4烷基; R2是其中公式为2至6的值之一之一; X是氧或硫; R3是卤素; 和R 4是氢，C 1 -C 12烷氧基，C 3 -C 7环烷氧基或C 2 -C 6烯氧基; 或未取代或被卤素取代的C 1 -C 18烷基，C 1 -C 4烷氧基，羟基和/或COOG，G为氢，碱金属阳离子或碱土金属阳离子; 或R 4为未被取代或被卤素和/或C 1 -C 4烷基取代的C 3 -C 7环烷基; 未被取代或被卤素取代的C 2 -C 18烯基; 未被取代或被卤素取代的C 2 -C 18炔基; 未被取代或被卤素取代的苯基，C 1 -C 4烷基C 1 -C 4烷氧基，硝基，氰基和/或C 1 -C 4卤代烷基; 或含有一至三个选自氮，氧和硫的杂原子的5-或6-元不饱和或饱和杂环体系，其未被取代或被氧代和/或被1-3个选自以下的取代基取代： 卤素，C 1 -C 4烷基，C 1 -C 4烷氧基和/或C 1 -C 4卤代烷基; 在农业中的用途以及通过酯化其所基于的5-OH- milbemycins来制备它们。

    5-azolylacetoxymilbemycins as ecto- and endoparasites
    23.
    发明授权
    5-azolylacetoxymilbemycins as ecto- and endoparasites 失效
    5-azolylaceoxymilbemycins as ecto-和endoparasites

    公开(公告)号：US4696922A

    公开(公告)日：1987-09-29

    申请号：US799373

    申请日：1985-11-18

    申请人： Elmar Sturm ,  Peter Maienfisch

    发明人： Elmar Sturm ,  Peter Maienfisch

    IPC分类号： A01N43/90 ,  A61K31/365 ,  A61P33/10 ,  C07D493/22 ,  C07H19/01 ,  C07D249/08

    CPC分类号： C07H19/01

    摘要： The present invention relates to milbemycin derivatives of the formula I ##STR1## wherein X is hydrogen or .beta.-halogen, R is methyl, ethyl, isopropyl or sec-butyl and Az is a 5 membered heterocyclic aromatic ring which contains 2-4 nitrogen atoms and is attached in the 1-position and which is unsubstituted or substituted by one or two C.sub.1 -C.sub.6 alkyl groups. These compounds, and the acid addition salts and metal complexes thereof, are effective pesticides for controlling endo-and ectoparasites, especially for controlling neamatodes which are parasites of animals. The may be obtained by appropriate esterification in 5-position of milbemycin derivatives. The selective .beta.-halogenation of 14,15-epoxymilbemycin derivatives can be effected via the intermediate .DELTA..sup.13,14 -15-hydroxymilbemycins with appropriate halogenating agents.

    摘要翻译： 本发明涉及式I（I）的密尔伯霉素衍生物，其中X是氢或β-卤素，R是甲基，乙基，异丙基或仲丁基，而Az是含有2- 4个氮原子并且连接在1-位且未被取代或被一个或两个C 1 -C 6烷基取代。 这些化合物及其酸加成盐和金属络合物是用于控制内寄生虫和外寄生虫的有效农药，特别是用于控制作为动物寄生虫的寄生虫。 可以通过在密尔伯霉素衍生物的5-位合适的酯化获得。 14,15-环氧米尔伯霉素衍生物的选择性β-卤代化可以通过中间体DELTA 13,14-15-羟吗啉霉素与适当的卤化剂进行。

    Quinolonecarboxylic acid derivatives as bactericides
    26.
    发明授权
    Quinolonecarboxylic acid derivatives as bactericides 失效
    喹诺酮羧酸衍生物作为杀菌剂

    公开(公告)号：US4264604A

    公开(公告)日：1981-04-28

    申请号：US918999

    申请日：1978-06-26

    申请人： Elmar Sturm

    发明人： Elmar Sturm

    IPC分类号： A01N43/42 ,  A01P1/00 ,  C07D215/56

    CPC分类号： C07D215/56 ,  A01N43/42

    摘要： Phytobactericidal compositions which contain, as active ingredient, a compound of the formula I, or one of the salts thereof, ##STR1## wherein X represents hydrogen, fluorine or chlorine, and R represents a lower alkyl group, are suitable for combating Erwinia spp., particularly E. amylovora (fireblight on fruit trees) and E. carotovora (soft rot on potatoes and vegetables).

    摘要翻译： 含有式I化合物或其盐之一的作为活性成分的植物杀菌组合物，其中X代表氢，氟或氯，R代表低级烷基适用于 防治欧文氏菌属，尤其是果树上的火龙果和胡萝卜腐质霉（土豆和蔬菜上的软腐烂）。

    Substituted 2-azabicycloalkanes as selective herbicides
    28.
    发明授权
    Substituted 2-azabicycloalkanes as selective herbicides 失效
    取代的2-氮杂双环烷烃作为选择性除草剂

    公开(公告)号：US4002461A

    公开(公告)日：1977-01-11

    申请号：US630057

    申请日：1975-11-07

    申请人： Elmar Sturm ,  Christian Vogel

    发明人： Elmar Sturm ,  Christian Vogel

    IPC分类号： C07D209/08 ,  C07D215/08 ,  A01N9/22

    CPC分类号： C07D209/08 ,  C07D215/08

    摘要： Compounds of the Formula I ##STR1## wherein R represents alkyl having from 1 to 4 carbon atoms and one of the symbols R.sub.1 and R.sub.2 is methyl and the other is hydrogen possess favorable herbicidal properties for practical purposes when used in crops for controlling their infestation by undesired plant growth.

    摘要翻译： 式Ⅰ的化合物其中R代表具有1-4个碳原子的烷基和一个符号R1和R2的烷基是甲基，另一个是氢，当用于控制它们的侵染作物时，在实际应用中具有有利的除草性质 由不期望的植物生长。