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    Fluorinated azolyl ethanol growth regulators and microbicides
    1.
    发明授权
    Fluorinated azolyl ethanol growth regulators and microbicides 失效
    氟化唑类乙醇生长调节剂和杀菌剂

    公开(公告)号：US4610716A

    公开(公告)日：1986-09-09

    申请号：US558140

    申请日：1983-12-05

    申请人： Elmar Sturm ,  Urs Muller ,  Hans Tobler

    发明人： Elmar Sturm ,  Urs Muller ,  Hans Tobler

    IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D303/22 ,  C07D303/34 ,  C07D521/00

    CPC分类号： C07D303/22 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

    摘要： The compounds described are those of the general formula I ##STR1## in which R.sub.1 is an azolyl group; R.sub.2 is C.sub.1 -C.sub.12 -alkyl; R.sub.3 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.4 -alkenyl or C.sub.2 -C.sub.4 -alkinyl, or benzyl which is unsubstituted or substituted by C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkyl, halogen and/or cyano; R.sub.4 is hydrogen, fluorine or C.sub.1 -C.sub.6 -alkyl; R.sub.5 is an unsubstituted or substituted radical chosen from the series comprising phenyl, naphthyl, biphenyl, benzylphenyl and benzyloxyphenyl, the substituents being chosen from the series comprising halogen, cyano, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -haloalkoxy, C.sub.1 -C.sub.3 -haloalkylthio, nitro and/or thiocyano; and X is oxygen or sulfur; including the acid addition salts, quaternary azolium salts and metal complexes.Methods for the preparation of these products are also disclosed, as well as agrochemical compositions containing one of these compounds as the active substance. A method of controlling phytopathogenic microorganisms and/or of regulating plant growth with the aid of these substances is furthermore described.

    摘要翻译： 所述的化合物是通式Ⅰ的化合物（Ⅰ），其中R1是唑基; R2是C1-C12-烷基; R3是氢，C1-C12-烷基，C2-C4-烯基或C2-C4-炔基，或未被取代或被C1-C6-烷基，C1-C6-烷氧基，C1-C6-卤代烷基，卤素和 /或氰基; R4是氢，氟或C1-C6-烷基; R5是选自包括苯基，萘基，联苯基，苄基苯基和苄氧基苯基的系列的未取代或取代的基团，所述取代基选自卤素，氰基，C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基C 1 -C 6 - 卤代烷基 ，C 1 -C 6 - 烷硫基，C 1 -C 6卤代烷氧基，C 1 -C 3卤代烷硫基，硝基和/或氰基氰基; X为氧或硫; 包括酸加成盐，季铵盐和金属络合物。 还公开了制备这些产品的方法，以及含有这些化合物之一作为活性物质的农药组合物。 进一步描述了借助于这些物质控制植物病原微生物和/或调节植物生长的方法。

    Microbicidal dioxolanylalkyltriazole compositions
    2.
    发明授权
    Microbicidal dioxolanylalkyltriazole compositions 失效
    杀微生物二氧戊环烷基三唑组合物

    公开(公告)号：US4402963A

    公开(公告)日：1983-09-06

    申请号：US327880

    申请日：1981-12-07

    申请人： Elmar Sturm

    发明人： Elmar Sturm

    IPC分类号： A01N43/653 ,  C07D317/22 ,  C07D405/06 ,  C07D521/00 ,  A01N43/64 ,  C07D405/14

    CPC分类号： C07D231/12 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08 ,  C07D317/22

    摘要： There are described novel compounds of the formula I defined herein ##STR1## wherein R is a phenyl group which is unsubstituted or mono- to tetra-substituted by C.sub.1 -C.sub.4 -alkyl, halogen, nitro, cyano, trifluoromethyl, phenyl or C.sub.1 -C.sub.3 -alkoxy, or it is 3,4-methylenedioxy-phenyl, including the acid addition salts thereof with organic and inorganic acids as well as metal complexes thereof, all having tolerance to cultivated plants and possessing valuable microbicidal properties. They can be used for combating phytopathogenic microorganisms, particularly phytopathogenic fungi. The compounds of the formula I have for practical purposes a very favorable curative, systemic and preventive action for the protection of cultivated plants, without these being impaired as a result of undesirable side-effects. They can be used in practice on their own or in the form of microbicidal compositions.

    摘要翻译： 描述了本文定义的式I的新化合物其中R是未被取代的或被C 1 -C 4 - 烷基，卤素，硝基，氰基，三氟甲基，苯基或 或者它是3,4-亚甲二氧基 - 苯基，包括其与有机和无机酸及其金属络合物的酸加成盐，它们都具有对栽培植物的耐受性并且具有有价值的杀微生物性质。 它们可用于对抗植物病原微生物，特别是植物病原真菌。 式I化合物对于实际目的而言是用于保护栽培植物的非常有利的治疗，系统和预防作用，而不会由于不期望的副作用而受损。 它们可以在实践中自己使用或以杀微生物剂的形式使用。

    Cyclobutanedicarboxylic acid imides, and compositions for their use as phytopathogenic fungicides
    3.
    发明授权
    Cyclobutanedicarboxylic acid imides, and compositions for their use as phytopathogenic fungicides 失效
    环丁烷二羧酸酰亚胺及其用作植物病原性杀真菌剂的组合物

    公开(公告)号：US4361576A

    公开(公告)日：1982-11-30

    申请号：US201950

    申请日：1980-10-29

    申请人： Niklaus Buhler ,  Marcus Baumann ,  Daniel Bellus ,  Elmar Sturm

    发明人： Niklaus Buhler ,  Marcus Baumann ,  Daniel Bellus ,  Elmar Sturm

    IPC分类号： A01N37/32 ,  C07C51/353 ,  C07D209/52 ,  C07D209/02

    CPC分类号： C07D209/52 ,  A01N37/32 ,  C07C51/353

    摘要： Cyclobutanecarboxylic acid imides of the formula I ##STR1## wherein one of R.sub.1 and R.sub.6 is hydrogen, methyl or ethyl, and the other is methyl or ethyl, R.sub.2 and R.sub.3 independently of one another are each hydrogen, fluorine or methyl, or R.sub.2 is acetoxy or chlorine while R.sub.3 is hydrogen, and wherein R.sub.4 is hydrogen, methyl or chlorine, and R.sub.5 is hydrogen or methyl, whereby R.sub.3 and R.sub.4 together can also form an additional bond in the four-membered ring, are suitable for combating various fungi and have a particularly excellent action against Botrytis. They can be produced in an especially advantageous manner by photochemical [2+2] cycloaddition of alkenes or alkines with for example appropriately substituted maleic acid-(3,5-dichlorophenyl)-imides.

    摘要翻译： 式I（I）的环丁烷羧酸酰亚胺其中R 1和R 6中的一个为氢，甲基或乙基，另一个为甲基或乙基，R 2和R 3彼此独立地为氢，氟或甲基，或 R2是乙酰氧基或氯，而R3是氢，R4是氢，甲基或氯，R5是氢或甲基，其中R3和R4一起也可以在四元环中形成另外的键，适于对抗各种 真菌，对Botrytis有特别出色的作用。 它们可以通过烯烃或烯烃与例如适当取代的马来酸 - （3,5-二氯苯基） - 酰亚胺的光化学[2 + 2]环加成以特别有利的方式制备。

    Use of 1,2-dimethyl-3-fluoro-, 1-methyl-3,3-difluoro-, and 1,2-dimethyl-3,3-difluoro-cyclobutane-1,2-dicarbonic acid 3,5-dichlorophenyl imides as plant fungicides
    4.
    发明授权
    Use of 1,2-dimethyl-3-fluoro-, 1-methyl-3,3-difluoro-, and 1,2-dimethyl-3,3-difluoro-cyclobutane-1,2-dicarbonic acid 3,5-dichlorophenyl imides as plant fungicides 失效
    使用1,2-二甲基-3-氟-1-甲基-3,3-二氟 - 和1,2-二甲基-3,3-二氟 - 环丁烷-1,2-二羧酸3,5-二氯苯基 作为植物杀真菌剂

    公开(公告)号：US4349564A

    公开(公告)日：1982-09-14

    申请号：US141746

    申请日：1980-04-18

    申请人： Niklaus Buhler ,  Marcus Baumann ,  Daniel Bellus ,  Elmar Sturm

    发明人： Niklaus Buhler ,  Marcus Baumann ,  Daniel Bellus ,  Elmar Sturm

    IPC分类号： A01N37/32 ,  C07C51/353 ,  C07D209/52 ,  A01N43/38

    CPC分类号： C07D209/52 ,  A01N37/32 ,  C07C51/353

    摘要： Cyclobutanecarboxylic acid imides of the formula I ##STR1## wherein one of R.sub.1 and R.sub.6 is hydrogen, methyl or ethyl, and the other is methyl or ethyl, R.sub.2 and R.sub.3 independently of one another are each hydrogen, fluorine or methyl, or R.sub.2 is acetoxy or chlorine while R.sub.3 is hydrogen, and wherein R.sub.4 is hydrogen, methyl or chlorine, and R.sub.5 is hydrogen or methyl, whereby R.sub.3 and R.sub.4 together can also form an additional bond in the four-membered ring, are suitable for combating various fungi and have a particularly excellent action against Botrytis. They can be produced in an especially advantageous manner by photochemical [2+2] cycloaddition of alkenes or alkynes with for example appropriately substituted maleic acid-(3,5-dichlorophenyl)imides.

    摘要翻译： 式I（I）的环丁烷羧酸酰亚胺其中R 1和R 6中的一个为氢，甲基或乙基，另一个为甲基或乙基，R 2和R 3彼此独立地为氢，氟或甲基，或 R2是乙酰氧基或氯，而R3是氢，R4是氢，甲基或氯，R5是氢或甲基，其中R3和R4一起也可以在四元环中形成另外的键，适于对抗各种 真菌，对Botrytis有特别出色的作用。 它们可以通过烯烃或炔烃与例如适当取代的马来酸 - （3,5-二氯苯基）酰亚胺的光化学[2 + 2]环加成以特别有利的方式制备。

    Amidino-phosphoric acid thiol esters for combating pests
    6.
    发明授权
    Amidino-phosphoric acid thiol esters for combating pests 失效
    用于防治害虫的脒基磷酸硫醇酯

    公开(公告)号：US4203978A

    公开(公告)日：1980-05-20

    申请号：US919335

    申请日：1978-06-26

    申请人： Elmar Sturm

    发明人： Elmar Sturm

    IPC分类号： A01N57/28 ,  C07F9/24 ,  A01N9/36

    CPC分类号： A01N57/28 ,  C07F9/2458

    摘要： Amidino-phosphoric acid thiol esters hereinafter defined in formula I are useful as active ingredients in pesticidal compositions containing them. They are useful for combating insects, Acarina, ectoparasites and particularly nematodes.

    摘要翻译： 下文定义的式I中的脒基磷酸硫醇酯可用作含有它们的杀虫组合物中的活性成分。 它们可用于防治昆虫，蜱螨属，外寄生虫，特别是线虫。

    Octahydroindole phosphorylacylamines
    9.
    发明授权
    Octahydroindole phosphorylacylamines 失效
    八氢吲哚磷酰胺

    公开(公告)号：US3969367A

    公开(公告)日：1976-07-13

    申请号：US545465

    申请日：1975-01-30

    申请人： Elmar Sturm ,  Hans Jorg Cellarius, deceased

    发明人： Elmar Sturm ,  Hans Jorg Cellarius, deceased

    IPC分类号： A01N57/16 ,  C07D209/08 ,  C07F9/59 ,  C07F9/60 ,  C07D209/12

    CPC分类号： A01N57/16 ,  C07D209/08 ,  C07F9/591 ,  C07F9/60

    摘要： Phosphorylthio-acetyl derivatives of decahydroquinolines, octahydroindoles and octahydropyrindines are effective plant regulating agents (growth regulators and selective herbicides) and fungicides.The new phosphorylacylamines correspond to the formula I ##SPC1##wherein R.sub.1 and R.sub.2 each independently represents hydrogen or methyl, R.sub.3 represents alkyl or haloalkyl, R.sub.4 represents alkyl, alkoxy, haloalkoxy, alkylthio or an amino radical, X represents oxygen or sulphur, and one of the two indices m and n represents 1 and the other represents 0 or 1.

    摘要翻译： 十氢喹啉，八氢吲哚和八氢吡啶的磷酰硫基 - 乙酰基衍生物是有效的植物调节剂（生长调节剂和选择性除草剂）和杀真菌剂。