Method of preparing cathode containing Iron disulfide for a lithium cell
    30.
    发明申请
    Method of preparing cathode containing Iron disulfide for a lithium cell 有权
    制备锂电池用二硫化铁的阴极的方法

    公开(公告)号:US20090291366A1

    公开(公告)日:2009-11-26

    申请号:US12154572

    申请日:2008-05-23

    IPC分类号: H01M4/40 H01M4/08

    摘要: A primary cell having an anode comprising lithium or lithium alloy and a cathode comprising iron disulfide (FeS2) or a mixture of iron disulfide (FeS2) and iron sulfide (FeS) and conductive carbon particles. A cathode slurry is prepared comprising the FeS2 or FeS2 plus FeS powder, conductive carbon, binder, and a solvent. The binder is preferably a styrene-ethylene/butylene-styrene (SEBS) block copolymer. There is an advantage discovered in utilizing a hydronaphthalene solvent to form the cathode slurry. The preferred solvent is 1,2,3,4-tetrahydronaphthalene or decahydronaphthalene and mixtures thereof. The slurry mixture is coated onto a conductive substrate and the solvent evaporated leaving a dry cathode coating on the substrate. Higher drying temperature may be used resulting in a dry cathode coating which resists cracking. The anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added.

    摘要翻译: 具有包含锂或锂合金的阳极和包含二硫化铁(FeS 2)或二硫化铁(FeS 2)和硫化铁(FeS)和导电碳颗粒的混合物的阴极的初级电池。 制备包含FeS 2或FeS 2加FeS粉末,导电碳,粘合剂和溶剂的阴极浆料。 粘合剂优选为苯乙烯 - 乙烯/丁烯 - 苯乙烯(SEBS)嵌段共聚物。 在利用氢化萘溶剂形成阴极浆料时发现了一个优点。 优选的溶剂是1,2,3,4-四氢化萘或十氢萘及其混合物。 将浆料混合物涂覆到导电基材上,蒸发溶剂,在基材上留下干燥的阴极涂层。 可以使用更高的干燥温度,导致干燥的阴极涂层,其耐龟裂。 阳极和阴极可以用分离器螺旋卷绕并插入电池壳体中,然后加入电解质。