摘要:
The adherence of an individual fibre embedded in a polymer matrix is determined by a drawing experiment in which the fibre is drawn out of the polymer matrix and simultaneously the pertaining force-distance diagram is registered. To this end a test sample consisting of the polymer matrix with the individual fibre embedded therein is manufactured by melting down a quantity of polymer present in granular or powder form on an object holder, the individual fibre is dipped into the molten polymer mass and the polymer mass is subsequently cooled down below the melting point. Subsequently the object holder with the test sample adhering thereto is brought into a force-distance measuring device, and the free end of the fibre is fixed to a chucking device moveable in the direction of the fibre. In the drawing experiment, the drawing force acting on the fibre is converted into corresponding electrical signals by the force transducer, and evaluated, and simultaneously the distance covered by the chucking device is converted into corresponding electrical signals by the distance transducer, and evaluated.
摘要:
Paraffin-containing monomer-free aqueous emulsions of a mixture comprising two unsaturated polyesters, of which one contains .alpha.,.gamma.-unsaturated ether groups, but no co-condensed residues of higher polyalkylene glycols, while the other contains co-condensed residues of higher polyalkylene glycols and monofunctional alcohols and/or carboxylic acids, but no .alpha.,.gamma.-unsaturated ether groups, are eminently suitable for the production of extremely thin-layer coatings without levelling faults.
摘要:
Air-drying unsaturated coating compositions are obtained by reacting at least 60% of the epoxide groups of a polyepoxid with more than one epoxid group per molecule(a) with 0.01 to 0.5 NH-equivalents, based on one epoxide group of ammonia, an aliphatic or cycloaliphatic primary or secondary amine and subsequently(b) with 0.99 to 0.5 carboxyl equivalents, based on one epoxide group of acrylic or methacrylic acid.The reaction products may be mixed with solvents and/or copolymerizable monomers and are preferably hardened in the presence of known photoinitiators with the aid of energy radiation.Their particular advantages are their stability in the dark and that they also harden very quickly in the presence of atmospheric oxygen.Preferred substrates are paper and cardboards.
摘要:
Process for the preparation of octa-2,7-dienyl-1-amine by telomerization of butadiene with ammonia in a two-phase system in the presence of hydrophilic palladium complexes, characterized in that octa-2,7-dienyl-1-amine and octa-1,7-dienyl-3-amine are isolated separately from one another from the reaction mixture present after telomerization, and the octa-1,7-dienyl-3-amine isolated in this way is subjected to an isomerization reaction to form octa-2,7-dienyl-1-amine, and also novel triphenylphosphine mono- and dimethoxytri(sodium sulphonates) and the use of triphenylphosphine trimethoxytri(sodium sulphonates), triphenylphosphine trimethyltri(sodium sulphonates) and triphenylphosphine trifluorodi- and tri(sodium sulphonates) as ligands for the preparation of palladium complexes.
摘要:
In a process for the telomerization of dienes with nucleophiles in a liquid two-phase system, use is made as catalysts of complexes comprising a transition metal as central atom and at least one tris-(hydroxyalkyl)-phosphine or -phosphine oxide as ligand. The use as catalysts of compounds comprising a transition metal as central atom and at least one tris-(hydroxy-C.sub.2 -C.sub.5 -alkyl)-phosphine or -phosphine oxide as ligand, new compounds of this type and aqueous solutions of such compounds are likewise described.
摘要:
The combination comprising iminodisuccinates of the formula ##STR1## in which the substituents have the meaning given in the description and polymers containing recurring succinic acid units improve the properties of detergents or cleaners.
摘要:
In a process for the telomerization of dienes with nucleophiles in a liquid two-phase system, use is made as catalysts of complexes comprising a transition metal as central atom and at least one tris-(hydroxyalkyl)-phosphine or -phosphine oxide as ligand. The use as catalysts of compounds comprising a transition metal as central atom and at least one tris-(hydroxy-C.sub.2 -C.sub.5 -alkyl)-phosphine or -phosphine oxide as ligand, new compounds of this type and aqueous solutions of such compounds are likewise described.
摘要:
The preparation of dimethyl carbonate by reaction of methanol, carbon monoxide and oxygen in the presence of Cu compounds is carried out in distillation units and the water of reaction is removed at least partially from the stripping region or the bottom phase.
摘要:
Organic compounds are selectively oxidized by means of a particularly advantageous process, using elemental oxygen and a catalyst containing palladium and copper and carrying out the process in the presence of carbon monoxide.