公开(公告)号：US08932979B2

公开(公告)日：2015-01-13

申请号：US12191949

申请日：2008-08-14

申请人： Marek Matusz ,  Michael Alan Richard ,  Martin Lysle Hess

发明人： Marek Matusz ,  Michael Alan Richard ,  Martin Lysle Hess

IPC分类号： B01J27/25 ,  B01J23/00 ,  B01J23/02 ,  B01J23/06 ,  A01N37/20 ,  A01N37/34 ,  A01N37/40 ,  A01N47/46 ,  A01N47/48 ,  B01J21/04 ,  B01J23/68 ,  C07C233/76 ,  C07C235/46 ,  C07C255/57 ,  C07C331/12 ,  C07C331/20 ,  C07D301/10 ,  B01J35/10

CPC分类号： A01N37/20 ,  A01N37/34 ,  A01N37/40 ,  A01N47/46 ,  A01N47/48 ,  B01J21/04 ,  B01J23/688 ,  B01J35/1009 ,  C07C233/76 ,  C07C235/46 ,  C07C255/57 ,  C07C331/12 ,  C07C331/20 ,  C07D301/10 ,  Y02P20/142 ,  Y02P20/52

摘要： A catalyst composition comprising a support having a surface area of at least 500 m2/kg, and deposited on the support: silver metal, a metal or component comprising rhenium, tungsten, molybdenum or a nitrate- or nitrite-forming compound, and a Group IA metal or component comprising a Group IA metal having an atomic number of at least 37, and in addition potassium, wherein the value of the expression (QK/R)+QHIA is in the range of from 1.5 to 30 mmole/kg, wherein QHIA and QK represent the quantities in mmole/kg of the Group IA metal having an atomic number of at least 37 and potassium, respectively, present in the catalyst composition, the ratio of QHIA to QK is at least 1:1, the value of QK is at least 0.01 mmole/kg, and R is a dimensionless number in the range of from 1.5 to 5, the units mmole/kg being relative to the weight of the catalyst composition.

摘要翻译： 一种催化剂组合物，其包含表面积至少为500m 2 / kg的载体，并沉积在载体上：银金属，包含铼，钨，钼或硝酸盐或亚硝酸盐形成化合物的金属或组分，以及组 IA金属或包含原子序数至少为37的IA族金属的组分，以及另外的钾，其中表达式（QK / R）+ QHIA的值在1.5至30mmole / kg的范围内，其中 QHIA和QK分别表示存在于催化剂组合物中的原子序数至少为37的IA族金属的摩尔数/ kg，QHIA与QK的比例至少为1:1， QK至少为0.01毫摩尔/ kg，R为1.5至5的无量纲数，单位mmole / kg相对于催化剂组合物的重量。

公开(公告)号：US08603937B2

公开(公告)日：2013-12-10

申请号：US13470867

申请日：2012-05-14

申请人： Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

发明人： Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

IPC分类号： B01J23/00

CPC分类号： B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/50 ,  B01J23/688 ,  B01J27/138 ,  B01J35/002 ,  C07C29/106 ,  C07D301/10 ,  Y02P20/142 ,  C07C31/20

摘要： A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.

公开(公告)号：US08569527B2

公开(公告)日：2013-10-29

申请号：US12865010

申请日：2008-05-15

申请人： Marek Matusz

发明人： Marek Matusz

IPC分类号： C07D301/10 ,  C07D301/03 ,  C07C69/96 ,  C07C215/00 ,  C07C31/18 ,  C07C27/10

CPC分类号： B01J8/067 ,  B01D53/0423 ,  B01D2253/112 ,  B01D2257/308 ,  B01J8/0476 ,  B01J20/0233 ,  B01J20/04 ,  B01J20/041 ,  B01J20/08 ,  B01J20/28057 ,  B01J20/3021 ,  B01J20/3078 ,  B01J20/3092 ,  B01J20/3204 ,  B01J20/3236 ,  B01J21/04 ,  B01J23/66 ,  B01J23/685 ,  B01J23/686 ,  B01J23/687 ,  B01J23/688 ,  B01J2208/00221 ,  B01J2208/0023 ,  B01J2208/00982 ,  B01J2208/025

摘要： The present invention provides a reactor system comprising: —one or more purification zones comprising an absorbent which comprises silver, an alkali or alkaline earth metal, and a support material having a surface area of more than 20 m2/g, and —a reaction zone comprising a catalyst, which reaction zone is positioned downstream from the one or more purification zones; an absorbent; a process for reacting a feed comprising one or more feed components; and a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.

摘要翻译： 本发明提供了一种反应器系统，其包含： - 一个或多个净化区，包括含有银，碱金属或碱土金属的吸收剂和表面积大于20m 2 / g的载体材料，以及 - 反应区 包括催化剂，该反应区位于该一个或多个净化区的下游; 吸收剂; 使包含一种或多种进料组分的进料反应的方法; 和1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺的制备方法。

公开(公告)号：US20120213679A1

公开(公告)日：2012-08-23

申请号：US13462490

申请日：2012-05-02

申请人： Wayne Errol EVANS ,  Marek MATUSZ ,  Eugene Marie Godfried Andre VAN KRUCHTEN ,  Martin Lysle HESS

发明人： Wayne Errol EVANS ,  Marek MATUSZ ,  Eugene Marie Godfried Andre VAN KRUCHTEN ,  Martin Lysle HESS

IPC分类号： B01J19/00

CPC分类号： C07C29/12 ,  B01D53/02 ,  B01D53/70 ,  B01D2253/112 ,  B01D2255/104 ,  B01D2257/2068 ,  C07C29/106 ,  Y02P20/154 ,  Y02P20/52 ,  C07C31/202

摘要： The invention provides a reaction system for the production of an alkylene carbonate and/or an alkylene glycol comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an iodide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of iodide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and/or an alkylene glycol.

摘要翻译： 本发明提供了一种用于生产碳酸亚烷基酯和/或亚烷基二醇的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含碘化物羧化催化剂的羧化区; 以及一个或多个纯化区，其含有能够减少包含循环气体的进料中的含碘化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和/或亚烷基二醇的方法。

公开(公告)号：US07932407B2

公开(公告)日：2011-04-26

申请号：US10816080

申请日：2004-04-01

申请人： Marek Matusz ,  Ruth Mary Kowaleski

发明人： Marek Matusz ,  Ruth Mary Kowaleski

IPC分类号： C07D301/10 ,  C07D301/03

CPC分类号： C07C29/106 ,  B01J21/04 ,  B01J23/66 ,  B01J23/687 ,  B01J23/688 ,  B01J35/1009 ,  B01J37/0203 ,  C07D301/10 ,  Y02P20/52 ,  C07C31/202

摘要： A process for the epoxidation of an olefin, which process comprises reacting a feed comprising an olefin, oxygen and an organic halide, in the presence of a catalyst comprising silver and rhenium deposited on a carrier, wherein the catalyst comprises rhenium in a quantity of at most 1.5 mmole/kg, relative to the weight of the catalyst, and at most 0.0015 mmole/m2, relative to the surface area of the carrier, and in which process the reaction temperature is increased to at least partly reduce the effect of loss of activity of the catalyst while the organic halide is present in a relative quantity Q which is maintained constant as defined herein.

摘要翻译： 一种烯烃环氧化方法，该方法包括在包含沉积在载体上的银和铼的催化剂存在下使包含烯烃，氧和有机卤化物的进料反应，其中催化剂包含一定量的铼 相对于催化剂的重量，最多为1.5mmol / kg，相对于载体的表面积为至多0.0015mmole / m 2，并且在该过程中，反应温度升高至少部分降低损失的影响 有机卤化物存在的相对量Q保持恒定的催化剂的活性，如本文所定义的。

公开(公告)号：US07704908B2

公开(公告)日：2010-04-27

申请号：US11613862

申请日：2006-12-20

申请人： Marek Matusz ,  Richard Anthony Fragnito

发明人： Marek Matusz ,  Richard Anthony Fragnito

IPC分类号： B01J38/48

CPC分类号： C07D301/08 ,  C07D301/10 ,  C07D301/22 ,  C07D301/36

摘要： A method for reusing rhenium from a donor spent epoxidation catalyst, the method comprising: providing a donor comprising spent epoxidation catalyst comprising rhenium, the donor having a cumulative alkylene oxide production of 0.16 kT/m3 of the spent epoxidation catalyst or more; contacting the donor with an aqueous liquid to produce rhenium-depleted donor and aqueous extract comprising extracted rhenium; separating the aqueous extract and the rhenium-depleted donor; and, using the extracted rhenium as a source of rhenium in a subsequent process.

摘要翻译： 一种用于从施主耗尽的环氧化催化剂重新使用铼的方法，所述方法包括：提供包含铼的废环氧化催化剂的供体，所述供体具有0.16kT / m 3的废环氧化催化剂或更多的累积环氧烷产生量; 使供体与含水液体接触以产生铼耗尽的供体和包含萃取的铼的含水萃取物; 分离水提取物和铼耗尽的供体; 并且在随后的方法中使用提取的铼作为铼源。

公开(公告)号：US07560411B2

公开(公告)日：2009-07-14

申请号：US11215267

申请日：2005-08-30

申请人： Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

发明人： Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

IPC分类号： B01J23/68

CPC分类号： C07C29/106 ,  B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/24 ,  B01J23/50 ,  B01J23/688 ,  B01J23/755 ,  B01J27/138 ,  B01J35/1042 ,  B01J37/26 ,  C07D301/10 ,  Y02P20/142 ,  C07C31/20

摘要： A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.

摘要翻译： 提供了一种制备载体的方法，该方法包括在载体制备的任何阶段在载体中引入强度增强添加剂。 还提供了其中结合有强度增强添加剂的所得载体和包含载体的催化剂。 还提供了使用该催化剂对烯烃进行环氧化的方法。 还提供了使用如此制备的用于制备1,2-二醇，1,2-二醇醚或链烷醇胺的烯烃氧化物的方法。

公开(公告)号：US10532989B2

公开(公告)日：2020-01-14

申请号：US12116905

申请日：2008-05-07

申请人： Marek Matusz

发明人： Marek Matusz

IPC分类号： C07D301/10 ,  C07C213/04 ,  B01J23/68 ,  B01J27/188 ,  C07C68/04 ,  B01J23/00 ,  C07C29/10 ,  B01J27/055

摘要： A catalyst for the epoxidation of an olefin comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the quantity of the rhenium promoter deposited on the carrier is greater than 1 mmole/kg, relative to the weight of the catalyst;the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; andthe total quantity of the first co-promoter and the second co-promoter deposited on the carrier is at most 3.8 mmole/kg, relative to the weight of the catalyst;a process for preparing the catalyst; a process for preparing an olefin oxide by reacting a feed comprising an olefin and oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.

公开(公告)号：US09527787B2

公开(公告)日：2016-12-27

申请号：US13462490

申请日：2012-05-02

申请人： Wayne Errol Evans ,  Marek Matusz ,  Eugene Marie Godfried Andre Van Kruchten ,  Martin Lysle Hess

发明人： Wayne Errol Evans ,  Marek Matusz ,  Eugene Marie Godfried Andre Van Kruchten ,  Martin Lysle Hess

IPC分类号： B01J19/00 ,  C07C29/12 ,  B01D53/02 ,  B01D53/70 ,  C07C29/10

CPC分类号： C07C29/12 ,  B01D53/02 ,  B01D53/70 ,  B01D2253/112 ,  B01D2255/104 ,  B01D2257/2068 ,  C07C29/106 ,  Y02P20/154 ,  Y02P20/52 ,  C07C31/202

摘要： The invention provides a reaction system for the production of an alkylene carbonate and/or an alkylene glycol comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an iodide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of iodide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and/or an alkylene glycol.

摘要翻译： 本发明提供了一种用于生产碳酸亚烷基酯和/或亚烷基二醇的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含碘化物羧化催化剂的羧化区; 以及一个或多个纯化区，其含有能够减少包含循环气体的进料中的含碘化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和/或亚烷基二醇的方法。

公开(公告)号：US08937031B2

公开(公告)日：2015-01-20

申请号：US13581641

申请日：2011-02-24

申请人： John Robert Lockemeyer ,  Marek Matusz ,  Randall Clayton Yeates

发明人： John Robert Lockemeyer ,  Marek Matusz ,  Randall Clayton Yeates

IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J25/00 ,  B01J29/00 ,  B01J31/00 ,  B01J27/047 ,  C07C213/04 ,  B01J27/051 ,  B01J27/188 ,  B01J27/19 ,  B01J35/10 ,  B01J37/02 ,  C07D301/10

CPC分类号： B01J27/051 ,  B01J27/047 ,  B01J27/188 ,  B01J27/19 ,  B01J35/108 ,  B01J35/1095 ,  B01J37/0201 ,  C07C213/04 ,  C07D301/10 ,  Y02P20/142 ,  C07C215/08

摘要： A catalyst for the epoxidation of an olefin comprising a carrier and, deposited thereon, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the quantity of the rhenium promoter deposited on the carrier is greater than 1 mmole/kg, relative to the weight of the catalyst; the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; the total quantity of the first co-promoter and the second co-promoter deposited on the carrier is at most 5.0 mmole/kg, relative to the weight of the catalyst; and wherein the carrier has a monomodal, bimodal or multimodal pore size distribution, a pore diameter of 0.01-200 μm, a specific surface area of 0.03-10 m2/g, a pore volume of 0.2-0.7 cm3/g, wherein the median pore diameter is 0.1-100 μm, and a water absorption of 10-80%.

摘要翻译： 一种用于环氧化包含载体并在其上沉积有银，铼助催化剂，第一共助催化剂和第二共助催化剂的烯烃的催化剂; 其中沉积在载体上的铼助催化剂的量相对于催化剂的重量大于1mmol / kg; 第一共助催化剂选自硫，磷，硼及其混合物; 第二共助催化剂选自钨，钼，铬及其混合物; 沉积在载体上的第一助催化剂和第二助催化剂的总量相对于催化剂的重量为至多5.0mmol / kg; 并且其中所述载体具有单峰，双峰或多峰孔径分布，孔径为0.01-200μm，比表面积为0.03-10m 2 / g，孔体积为0.2-0.7cm 3 / g，其中中值 孔径为0.1〜100μm，吸水率为10-80％。