公开(公告)号：US20070197045A1

公开(公告)日：2007-08-23

申请号：US11671120

申请日：2007-02-05

Applicant: Michael BACKER ,  Brigitte SCHLOBACH ,  Kerstin KNOTH ,  Barbara SCHUPP-NIEWA ,  Ruben HUHNE ,  Martina FALTER

Inventor： Michael BACKER ,  Brigitte SCHLOBACH ,  Kerstin KNOTH ,  Barbara SCHUPP-NIEWA ,  Ruben HUHNE ,  Martina FALTER

IPC: H01L21/31

CPC classification number: C23C18/1216 ,  C23C18/06 ,  C23C18/1225 ,  C23C18/1241 ,  C23C18/1283 ,  H01L39/2461 ,  Y10S505/741

Abstract: The formation of band-shaped HTSL on a metal substrate is disclosed. The HTSL includes at least one buffer layer comprising zirconates and/or rare-earth oxides. The HTSL layer is formed on the buffer layer. The buffer layer has a texturing that in the case of a RHEED measurement results in discrete reflexes and not only in diffraction rings. In particular, the buffer layer may be textured along its interface with the HTSL layer.

Abstract translation: 公开了在金属基底上形成带状HTSL。 HTSL包括至少一个包含锆酸盐和/或稀土氧化物的缓冲层。 HTSL层形成在缓冲层上。 缓冲层具有纹理，在RHEED测量的情况下，导致离散的反射，并且不仅在衍射环中。 特别地，缓冲层可以沿其与HTSL层的界面纹理化。

公开(公告)号：US09006372B2

公开(公告)日：2015-04-14

申请号：US13698852

申请日：2011-05-16

Applicant: Michael Backer ,  Pierre Chevalier ,  Zhihua Liu ,  Ana Marques ,  Satoshi Onodera ,  Vincent Rerat ,  Motoshi Sasaki

Inventor： Michael Backer ,  Pierre Chevalier ,  Zhihua Liu ,  Ana Marques ,  Satoshi Onodera ,  Vincent Rerat ,  Motoshi Sasaki

IPC: C08G77/26 ,  C08G77/395 ,  C08G77/30 ,  C08G77/388

CPC classification number: C08G77/395 ,  C08G77/26 ,  C08G77/30 ,  C08G77/388

Abstract: Branched silicone (organopolysiloxane) resins and preparation method and use thereof are provided, which contain at least one group selected from phosphonate and phosphinate groups and at least one organic group containing nitrogen. Such silicone resins can be used in thermoplastic, thermosetting or rubber organic polymer compositions to reduce the flammability of the organic polymer compositions.

Abstract translation: 提供了分支硅氧烷（有机聚硅氧烷）树脂及其制备方法和用途，其含有至少一种选自膦酸酯和次膦酸酯基团和至少一种含氮的有机基团。 这种有机硅树脂可用于热塑性，热固性或橡胶有机聚合物组合物中以降低有机聚合物组合物的可燃性。

公开(公告)号：US08476375B2

公开(公告)日：2013-07-02

申请号：US13001677

申请日：2009-07-02

Applicant: Michael Backer ,  Valerie Smits ,  Damien Deheunynck

Inventor： Michael Backer ,  Valerie Smits ,  Damien Deheunynck

IPC: C08F230/08 ,  C08F4/34 ,  C08J3/28 ,  C08J9/04 ,  C08L51/06

CPC classification number: C08F255/02 ,  C08F255/00 ,  C08L51/06 ,  C08L2666/04 ,  C08L2666/02

Abstract: The invention relates to a process for grafting hydrolysable silane groups to a polyolefin, comprising reacting the polyolefin with an unsaturated silane, containing an olefinic —C═C— bond or acetylenic —C≡C— bond and having at least one hydrolysable group bonded to Si, or a hydrolysate thereof, in the presence of means capable of generating free radical sites in the polymer. The silane contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C═C— or acetylenic —C≡C— unsaturation of the silane. The unsaturated silane may also contains electron-withdrawing moiety with respect to the olefinic —C═C— or acetylenic —C≡C— bond. The invention permits to provide a silane-modified polyolefin having a high grafting efficiency while limiting/preventing polymer degradation by chain scission. The silane-modified polyolefin can be further reacted with a polar surface, a filler or a polar polymer or reacted on itself to crosslink the polyolefin and obtain enhanced physical properties of the composites made thereof.

Abstract translation: 本发明涉及将可水解硅烷基接枝到聚烯烃上的方法，包括使聚烯烃与不饱和硅烷反应，所述不饱和硅烷含有烯烃-C = C-键或炔属-C = C-键并且具有至少一个可水解基团键合到 Si或其水解产物，在能够在聚合物中产生自由基位点的手段存在下进行。 所述硅烷含有芳环或其它烯属双键或炔属不饱和键，所述芳环或所述其它烯属双键或炔属不饱和键与所述硅烷的烯烃-C = C-或炔属-C = C-不饱和键结合。 相对于烯烃-C = C-或炔属-C = C-键，不饱和硅烷还可含有吸电子部分。 本发明允许提供具有高接枝效率的硅烷改性聚烯烃，同时通过链断裂限制/防止聚合物降解。 硅烷改性的聚烯烃可以进一步与极性表面，填料或极性聚合物反应，或者自身反应以使聚烯烃交联并获得由其制成的复合材料的增强的物理性能。

公开(公告)号：US20130065992A1

公开(公告)日：2013-03-14

申请号：US13698806

申请日：2011-05-16

Applicant: Michael Backer ,  Pierre Chevalier ,  Ana Marques

Inventor： Michael Backer ,  Pierre Chevalier ,  Ana Marques

IPC: C08K5/357 ,  C08L69/00 ,  C08K3/36

CPC classification number: C08L83/04 ,  C08G77/26 ,  C08K5/5442 ,  C08K9/08 ,  C08L69/00 ,  C08L83/08 ,  C08L83/00

Abstract: The invention provides a process for improving the fire resistance of a thermoplastic, thermoset or rubber organic polymer composition, characterised in that an alkoxysilane is added to a thermoplastic, thermosetting and rubber organic polymer composition and is heated to cause hydrolysis and condensation of the alkoxysilane. For example the alkoxysilane is a Benzoxazine triethoxysilane.

Abstract translation: 本发明提供一种改善热塑性，热固性或橡胶有机聚合物组合物的耐火性的方法，其特征在于将烷氧基硅烷加入到热塑性，热固性和橡胶状有机聚合物组合物中，并加热以使烷氧基硅烷水解和缩合。 例如，烷氧基硅烷是苯并恶嗪三乙氧基硅烷。

公开(公告)号：US08314164B2

公开(公告)日：2012-11-20

申请号：US12745213

申请日：2008-11-28

Applicant: Valerie Smits ,  Michael Backer ,  Sebastien Grofils ,  Thierry Materne ,  Laurence Stelandre ,  Randall Schmidt ,  Steven Swier ,  Thomas Chaussee

Inventor： Valerie Smits ,  Michael Backer ,  Sebastien Grofils ,  Thierry Materne ,  Laurence Stelandre ,  Randall Schmidt ,  Steven Swier ,  Thomas Chaussee

IPC: C08L1/02 ,  C08K3/34

CPC classification number: B60C1/00 ,  C08K3/36 ,  C08K5/5419 ,  C08K5/5425 ,  C08K5/548 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L83/04 ,  C08L2666/02 ,  C08L83/00

Abstract: The present invention relates to a curable rubber composition comprising an organic elastomer, a filler and at least one curing agent for the elastomer. Such curable rubber compositions are widely used in the production of cured rubber articles, such as tires, belts and hoses. The composition contains a branched silicone resin having Si-bonded hydroxyl groups or azo groups. This may lead to a reduction in the mixing energy required for processing, particularly in the energy required in the first (non-productive) mixing phase to give good dispersion of the filler in the organic elastomer. Use of the branched silicone resin can also accelerate cure (vulcanization), thus reducing the required cure time or reducing the amount of cure accelerator required.

Abstract translation: 本发明涉及包含有机弹性体，填料和至少一种用于弹性体的固化剂的可固化橡胶组合物。 这种可固化橡胶组合物广泛用于生产固化橡胶制品，如轮胎，皮带和软管。 该组合物含有具有Si键合的羟基或偶氮基团的支链硅树脂。 这可能导致加工所需的混合能量的降低，特别是在第一（非生产性）混合阶段所需的能量中，以使填料在有机弹性体中得到良好的分散。 使用支化硅树脂也可以加速固化（硫化），从而减少所需的固化时间或减少所需的固化促进剂的量。

公开(公告)号：US20120283346A1

公开(公告)日：2012-11-08

申请号：US13520859

申请日：2010-12-22

Applicant: Michael Backer ,  Francois De Buyl ,  Damien Deheunynck ,  Jean De La Croix Habimana ,  Vincent Rerat ,  Valerie Smits

Inventor： Michael Backer ,  Francois De Buyl ,  Damien Deheunynck ,  Jean De La Croix Habimana ,  Vincent Rerat ,  Valerie Smits

IPC: C08L23/36 ,  C08L23/26 ,  C08J9/00

CPC classification number: C08F255/02 ,  C08F212/14 ,  C08F230/08 ,  C08F236/14

Abstract: The invention provides a process for grafting silane or silicone functionality onto a polyolefin, comprising reacting the polyolefin with an unsaturated monomer (A) containing an olefinic —C═C— bond or acetylenic —C≡C— bond and a reactive functional group X in the presence of means capable of generating free radical sites in the polyolefin and with an organosilicon compound (B) having a functional group Y which is reactive with the functional group X of the unsaturated monomer (A), characterized in that the unsaturated monomer (A) contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C═C— or acetylenic —C≡C— unsaturation of the unsaturated monomer (A).

Abstract translation: 本发明提供将硅烷或硅氧烷官能度接枝到聚烯烃上的方法，包括使聚烯烃与含有烯烃-C≡C-键或炔属-C≡C-键和反应性官能团X的不饱和单体（A）反应 存在能够在聚烯烃中产生自由基位点的装置和具有与不饱和单体（A）的官能团X反应的官能团Y的有机硅化合物（B）的存在，其特征在于不饱和单体（A ）含有芳环或另外的烯属双键或炔属不饱和键，芳环或其它烯属双键或炔属不饱和键与不饱和单体的烯属-C≡C-或炔属-C≡C-不饱和键相结合（ 一个）。