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公开(公告)号:US20130066009A1
公开(公告)日:2013-03-14
申请号:US13698852
申请日:2011-05-16
申请人: Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
发明人: Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
IPC分类号: C08G77/18 , C08K3/36 , C08L83/08 , C08G77/395 , C08L69/00
CPC分类号: C08G77/395 , C08G77/26 , C08G77/30 , C08G77/388
摘要: Branched silicone (organopolysiloxane) resins and preparation method and use thereof are provided, which contain at least one group selected from phosphonate and phosphinate groups and at least one organic group containing nitrogen. Such silicone resins can be used in thermoplastic, thermosetting or rubber organic polymer compositions to reduce the flammability of the organic polymer compositions.
摘要翻译: 提供了分支硅氧烷(有机聚硅氧烷)树脂及其制备方法和用途,其含有至少一种选自膦酸酯和次膦酸酯基团和至少一种含氮的有机基团。 这种有机硅树脂可用于热塑性,热固性或橡胶有机聚合物组合物中以降低有机聚合物组合物的可燃性。
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公开(公告)号:US09006372B2
公开(公告)日:2015-04-14
申请号:US13698852
申请日:2011-05-16
申请人: Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
发明人: Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
IPC分类号: C08G77/26 , C08G77/395 , C08G77/30 , C08G77/388
CPC分类号: C08G77/395 , C08G77/26 , C08G77/30 , C08G77/388
摘要: Branched silicone (organopolysiloxane) resins and preparation method and use thereof are provided, which contain at least one group selected from phosphonate and phosphinate groups and at least one organic group containing nitrogen. Such silicone resins can be used in thermoplastic, thermosetting or rubber organic polymer compositions to reduce the flammability of the organic polymer compositions.
摘要翻译: 提供了分支硅氧烷(有机聚硅氧烷)树脂及其制备方法和用途,其含有至少一种选自膦酸酯和次膦酸酯基团和至少一种含氮的有机基团。 这种有机硅树脂可用于热塑性,热固性或橡胶有机聚合物组合物中以降低有机聚合物组合物的可燃性。
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公开(公告)号:US20130065993A1
公开(公告)日:2013-03-14
申请号:US13698828
申请日:2011-05-16
申请人: Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
发明人: Michael Backer , Pierre Chevalier , Zhihua Liu , Ana Marques , Satoshi Onodera , Vincent Rerat , Motoshi Sasaki
IPC分类号: C08K5/544 , C08K3/36 , C08L69/00 , C08L83/08 , C08K5/5419
摘要: The invention provides a process for improving the fire resistance of a thermoplastic or thermoset organic polymer composition, characterised in that an alkoxysilane containing at least one organic nitrogen-containing group and an alkoxysilane or silicone resin containing at least one group selected from phosphonate and phosphinate groups are added to a thermoplastic or thermosetting organic polymer composition and heated in the presence of moisture to cause hydrolysis and siloxane condensation of the alkoxysilane or alkoxysilanes. The alkoxysilanes, or alkoxysilane(s) and silicone resin, of the invention are particularly effective in increasing the fire resistance of polycarbonates and blends of polycarbonate with other resins such as polycarbonate/ABS blends.
摘要翻译: 本发明提供一种改善热塑性或热固性有机聚合物组合物的耐火性的方法,其特征在于含有至少一种含有机氮基团的烷氧基硅烷和含有至少一种选自膦酸酯和次膦酸基团的烷氧基硅烷或硅氧烷树脂 加入到热塑性或热固性有机聚合物组合物中并在水分存在下加热以引起烷氧基硅烷或烷氧基硅烷的水解和硅氧烷缩合。 本发明的烷氧基硅烷或烷氧基硅烷和有机硅树脂在增加聚碳酸酯和聚碳酸酯与其它树脂如聚碳酸酯/ ABS共混物的共混物的耐火性方面特别有效。
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公开(公告)号:US09175177B2
公开(公告)日:2015-11-03
申请号:US12523914
申请日:2008-01-18
申请人: Masaru Nagato , Masahiko Maeda , Tetsuya Masutani , Satoshi Onodera , Eiji Kitaura , Motoshi Sasaki , Peter Cheshire Hupfield
发明人: Masaru Nagato , Masahiko Maeda , Tetsuya Masutani , Satoshi Onodera , Eiji Kitaura , Motoshi Sasaki , Peter Cheshire Hupfield
CPC分类号: C09D7/1233 , C08G77/24 , C08K5/5406 , C08L61/20 , C08L83/02 , C09D7/63 , C09D167/00 , C08L83/00 , C08L2666/02
摘要: There is provided a polyester coating composition having excellent action of preventing deposition of outdoor stain and stain caused by rainfall, being capable of extending a period of time (pot life) from the mixing to the coating, and comprising (A) a polyester resin, (B) one or more of fluorine-containing organosilicon compounds having a fluorine content of 5 to 30% by mass, (C) one or more of aliphatic hydrocarbon compounds having hydroxyl group and 1 to 10 carbon atoms, in which a part of hydrogen atoms bonded to carbon atom may be substituted by fluorine atoms and/or one or more of alkoxy compounds having 2 to 10 carbon atoms, in which a part of hydrogen atoms bonded to carbon atom may be substituted by fluorine atoms, and (D) an organic solvent.
摘要翻译: 提供一种具有防止室外污渍沉积和由降雨引起的污渍的能够延长从混合到涂层的时间(适用期)的聚酯涂料组合物,并且包含(A)聚酯树脂, (B)一种或多种氟含量为5〜30质量%的含氟有机硅化合物,(C)一种或多种具有羟基和1至10个碳原子的脂族烃化合物,其中一部分氢 与碳原子键合的原子可以被氟原子和/或一个或多个具有2-10个碳原子的烷氧基化合物取代,其中一部分与碳原子键合的氢原子可以被氟原子取代,和(D) 有机溶剂。
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公开(公告)号:US20110124800A1
公开(公告)日:2011-05-26
申请号:US12993575
申请日:2009-06-03
申请人: Satoshi Onodera , Toru Masatomi , Motoshi Sasaki
发明人: Satoshi Onodera , Toru Masatomi , Motoshi Sasaki
IPC分类号: C09D133/08
CPC分类号: C09D143/04
摘要: To provide a coating agent composition that cures to form a transparent film that exhibits a high water repellency, a high durability, and an excellent adhesiveness to substrate. A coating agent composition that characteristically comprises (A) an acrylic copolymer obtained by the radical copolymerization of (A1) 1 mole silane compound represented by the general formula: CH2═C(R1)—COO-Q-SiR2n(OR3)3-n, (A2) 3.70 to 6.20 moles of at least one compound that contains a vinyl polymerizable unsaturated bond, and (A3) 1.05 to 1.80 moles of a siloxysilane compound represented by general formula (2): CH2═C(R1)—COO-Q-Si(OSiR43)3 at an molar ratio (A1)/{(A1)+(A2)+(A3)}=0.11 to 0.17; and (B) a condensation reaction catalyst.
摘要翻译: 提供固化形成透明膜的涂布剂组合物,其具有高斥水性,高耐久性和对基材的优异粘附性。 一种涂料组合物,其特征在于包含(A)通过(A1)由通式:CH2 = C(R1)-COO-Q-SiR2n(OR3)3-n表示的1摩尔硅烷化合物的自由基共聚获得的丙烯酸共聚物 ,(A2)3.70〜6.20摩尔含有乙烯基聚合性不饱和键的至少一种化合物,(A3)1.05〜1.80摩尔由通式(2)表示的硅氧烷硅烷化合物:CH 2 = C(R 1)-COO- 摩尔比(A1)/ {(A1)+(A2)+(A3)}的Q-Si(OSiR43)3 = 0.11〜0.17; 和(B)缩合反应催化剂。
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公开(公告)号:US09273224B2
公开(公告)日:2016-03-01
申请号:US12993575
申请日:2009-06-03
申请人: Satoshi Onodera , Toru Masatomi , Motoshi Sasaki
发明人: Satoshi Onodera , Toru Masatomi , Motoshi Sasaki
IPC分类号: C09D143/04
CPC分类号: C09D143/04
摘要: To provide a coating agent composition that cures to form a transparent film that exhibits a high water repellency, a high durability, and an excellent adhesiveness to substrate. A coating agent composition that characteristically comprises (A) an acrylic copolymer obtained by the radical copolymerization of (A1) 1 mole silane compound represented by the general formula: CH2═C(R1)—COO-Q-SiR2n(OR3)3-n, (A2) 3.70 to 6.20 moles of at least one compound that contains a vinyl polymerizable unsaturated bond, and (A3) 1.05 to 1.80 moles of a siloxysilane compound represented by general formula (2): CH2═C(R1)—COO-Q-Si(OSiR43)3 at an molar ratio (A1)/{(A1)+(A2)+(A3)}=0.11 to 0.17; and (B) a condensation reaction catalyst.
摘要翻译: 提供固化形成透明膜的涂布剂组合物,其具有高斥水性,高耐久性和对基材的优异粘附性。 一种涂料组合物,其特征在于包含(A)通过(A1)由通式:CH2 = C(R1)-COO-Q-SiR2n(OR3)3-n表示的1摩尔硅烷化合物的自由基共聚获得的丙烯酸共聚物 ,(A2)3.70〜6.20摩尔含有乙烯基聚合性不饱和键的至少一种化合物,(A3)1.05〜1.80摩尔由通式(2)表示的硅氧烷硅烷化合物:CH 2 = C(R 1)-COO- 摩尔比(A1)/ {(A1)+(A2)+(A3)}的Q-Si(OSiR43)3 = 0.11〜0.17; 和(B)缩合反应催化剂。
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公开(公告)号:US20100168304A1
公开(公告)日:2010-07-01
申请号:US12523914
申请日:2008-01-18
申请人: Masaru Nagato , Masahiko Maeda , Tetsuya Masutani , Satoshi Onodera , Eiji Kitaura , Motoshi Sasaki , Peter Cheshire Hupfield
发明人: Masaru Nagato , Masahiko Maeda , Tetsuya Masutani , Satoshi Onodera , Eiji Kitaura , Motoshi Sasaki , Peter Cheshire Hupfield
IPC分类号: C08K5/5415
CPC分类号: C09D7/1233 , C08G77/24 , C08K5/5406 , C08L61/20 , C08L83/02 , C09D7/63 , C09D167/00 , C08L83/00 , C08L2666/02
摘要: There is provided a polyester coating composition having excellent action of preventing deposition of outdoor stain and stain caused by rainfall, being capable of extending a period of time (pot life) from the mixing to the coating, and comprising (A) a polyester resin, (B) one or more of fluorine-containing organosilicon compounds having a fluorine content of 5 to 30% by mass, (C) one or more of aliphatic hydrocarbon compounds having hydroxyl group and 1 to 10 carbon atoms, in which a part of hydrogen atoms bonded to carbon atom may be substituted by fluorine atoms and/or one or more of alkoxy compounds having 2 to 10 carbon atoms, in which a part of hydrogen atoms bonded to carbon atom may be substituted by fluorine atoms, and (D) an organic solvent.
摘要翻译: 提供一种具有防止室外污渍沉积和由降雨引起的污渍的能够延长从混合到涂层的时间(适用期)的聚酯涂料组合物,并且包含(A)聚酯树脂, (B)一种或多种氟含量为5〜30质量%的含氟有机硅化合物,(C)一种或多种具有羟基和1至10个碳原子的脂族烃化合物,其中一部分氢 与碳原子键合的原子可以被氟原子和/或一个或多个具有2-10个碳原子的烷氧基化合物取代,其中一部分与碳原子键合的氢原子可以被氟原子取代,和(D) 有机溶剂。
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8.
公开(公告)号:US5486564A
公开(公告)日:1996-01-23
申请号:US387697
申请日:1995-02-13
摘要: Disclosed is a highly reproducible method for the molecular weight fractionation of polyhydrogen silsesquioxane that gives a very storage-stable polyhydrogen silsesquioxane having a freely selectable molecular weight. The method involves dissolving polyhydrogen silsesquioxane in active-hydrogen-free nonpolar solvent; adding an active-hydrogen-free polar solvent to the resulting solution in order to precipitate polyhydrogen silsesquioxane; and collecting the desired molecular weight fraction of polyhydrogen silsesquioxane.
摘要翻译: 公开了一种高度可重复的聚氢倍半硅氧烷分子量分级方法,其提供了具有可自由选择的分子量的非常储存稳定的聚氢倍半硅氧烷。 该方法包括将聚氢倍半硅氧烷溶解在无活性氢的非极性溶剂中; 向所得溶液中加入无活性氢的极性溶剂,以沉淀聚氢倍半硅氧烷; 并收集所需的聚氢倍半硅氧烷的分子量分数。
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公开(公告)号:US20070167559A1
公开(公告)日:2007-07-19
申请号:US10562656
申请日:2004-06-25
申请人: Toru Masatomi , Motoshi Sasaki , Hideki Kobayashi
发明人: Toru Masatomi , Motoshi Sasaki , Hideki Kobayashi
IPC分类号: C08L33/00
CPC分类号: C09D143/04
摘要: A coating agent composition of the present invention consists of: (A) an acrylic-type copolymer that has a weight-average molecular weight within the range of 3,000 to 100,000 and contains in its side molecular chains hydrolysable silyl groups of the following formula: —COO-Q-SiR2n(OR3)3-n and organosiloxysilyl groups of the following formula: —COO-Q-Si(OSiR43)3; and (B) a condensation-reaction accelerating catalyst. Prior to curing, the composition demonstrates excellent storage stability and coating properties, while after curing the composition produces a coating film of high hardness that has excellent water-repellent properties and durability.
摘要翻译: 本发明的涂料组合物由以下组成:(A)重均分子量在3,000〜100,000的丙烯酸类共聚物,并且在其分子链中含有下式的可水解甲硅烷基: 下式的有机甲硅烷氧基:下式的有机硅氧基甲硅烷基:(C 1 -C 4) -COO-Q-Si(OSiR 4)3 sub> 3; 和(B)缩合反应促进催化剂。 在固化之前,组合物表现出优异的储存稳定性和涂布性能,而在固化后,组合物产生具有优异的防水性能和耐久性的高硬度的涂膜。
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公开(公告)号:US20060281889A1
公开(公告)日:2006-12-14
申请号:US10478158
申请日:2002-05-27
申请人: Hideki Kobayashi , Motoshi Sasaki
发明人: Hideki Kobayashi , Motoshi Sasaki
CPC分类号: C08L83/14 , C08G77/18 , C08G77/50 , C08L83/04 , C09D183/04 , C09D183/14
摘要: A silicone composition for a water-repellent coating comprising (A) a polydimethylsiloxane expressed by the general formula: (RO)3Si-Q-{(CH3)2SiO}n—(CH3)2Si-Q-Si(OR)3, where R is a C1 to C10 monovalent hydrocarbon group, Q is an oxygen atom or a C2 to C10 alkylene group, and n is an integer from 10 to 1000; (B) an alkoxysilane partial hydrolysate/condensate, where the alkoxysilane is described by general formula: R1xSi(OR2)4-x, where R1 is a C1 to C6 monovalent hydrocarbon group, R2 is a C1 to C6 alkyl group, and x is an integer from 0 to 3; (C) an organotitanium-based catalyst; (D) an aliphatic hydrocarbon solvent or ester-based solvent; and (E) an alcohol-based solvent.
摘要翻译: 用于防水涂料的硅氧烷组合物,其包含(A)由以下通式表示的聚二甲基硅氧烷:<?in-line-formula description =“In-Line Formulas”end =“lead”?>(RO)3 Si-Q - {(CH 3 3)2 SiO} - (CH 3 3) 2-Si-Q-Si(OR)3 <3,<?in-line-formula description =“In-line Formulas”end =“tail”?>其中R是 C 1至C 10的一价烃基,Q为氧原子或C 2至C 10亚烷基, 亚烷基,n为10〜1000的整数, (B)烷氧基硅烷部分水解产物/缩合物,其中烷氧基硅烷由下列通式描述:R 1 Si(OR 2)是C 6〜C 6的烷基,x是0〜3的整数; (C)有机钛基催化剂; (D)脂族烃溶剂或酯类溶剂; 和(E)醇类溶剂。
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