公开(公告)号：US20120101319A1

公开(公告)日：2012-04-26

申请号：US13285787

申请日：2011-10-31

Applicant: Virginia M. ROBERTS ,  Michel DAAGE ,  James R. BIELENBERG ,  Paul J. BERLOWITZ ,  Paul D. OLDENBURG ,  David C. LONG ,  Halou OUMAR-MAHAMAT

Inventor： Virginia M. ROBERTS ,  Michel DAAGE ,  James R. BIELENBERG ,  Paul J. BERLOWITZ ,  Paul D. OLDENBURG ,  David C. LONG ,  Halou OUMAR-MAHAMAT

IPC: C07C7/00

CPC classification number: C10G3/50 ,  C10G3/42 ,  C10G3/44 ,  C10G3/45 ,  C10G3/52 ,  C10G3/62 ,  C10G45/08 ,  C10G45/26 ,  C10G45/50 ,  C10G47/06 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/201 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/4081 ,  C10G2300/44 ,  C10G2300/70 ,  C10G2300/805 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P30/20

Abstract: Biomass based feeds are processed under hydrothermal treatment conditions, e.g., to produce a hydrocarbon liquid product and a solids portion. The hydrothermal treatment is performed in the presence of a dissolved catalyst or catalyst precursor. The presence of the dissolved catalyst or catalyst precursor can modify the nature of the hydrocarbon products produced from the hydrothermal treatment.

Abstract translation: 基于生物质的饲料在水热处理条件下进行处理，例如产生烃液体产物和固体部分。 在溶解的催化剂或催化剂前体的存在下进行水热处理。 溶解的催化剂或催化剂前体的存在可以改变由水热处理产生的烃产物的性质。

公开(公告)号：US20120094879A1

公开(公告)日：2012-04-19

申请号：US13285519

申请日：2011-10-31

Applicant: Virginia M. ROBERTS ,  Michel DAAGE ,  Paul D. OLDENBURG ,  James R. BIELENBERG ,  Paul J. BERLOWITZ ,  David C. LONG ,  Halou OUMAR-MAHAMAT

Inventor： Virginia M. ROBERTS ,  Michel DAAGE ,  Paul D. OLDENBURG ,  James R. BIELENBERG ,  Paul J. BERLOWITZ ,  David C. LONG ,  Halou OUMAR-MAHAMAT

IPC: C10M169/04 ,  C07C7/163 ,  C10L1/12 ,  C07C7/00

CPC classification number: C10G3/42 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/301 ,  C10G2300/4018 ,  C10J2300/0916 ,  Y02P20/145 ,  Y02P30/20

Abstract: Biomass based feeds are processed under hydrothermal treatment conditions, e.g., to produce a hydrocarbon liquid product and a solids portion. The hydrothermal treatment can be performed in the presence of heterogeneous catalyst particles that can optionally include a catalyst metal or metal salt. The presence of the heterogeneous catalyst can modify the nature of the hydrocarbon products produced from the hydrothermal treatment.

Abstract translation: 基于生物质的饲料在水热处理条件下进行处理，例如产生烃液体产物和固体部分。 水热处理可以在可任选地包括催化剂金属或金属盐的非均相催化剂颗粒的存在下进行。 非均相催化剂的存在可以改变由水热处理产生的烃产物的性质。

公开(公告)号：US20100187155A1

公开(公告)日：2010-07-29

申请号：US12655128

申请日：2009-12-23

Applicant: Stephen J. McCarthy ,  Gary Paul Schleicher ,  Krista Marie Prentice ,  Michel Daage ,  Christopher Gordon Oliveri ,  Thomas Francis Degnan ,  Jose Guadalupe Santiesteban ,  Ajit Bhaskar Dandekar ,  William Joseph Novak ,  Wenyih F. Lai

Inventor： Stephen J. McCarthy ,  Gary Paul Schleicher ,  Krista Marie Prentice ,  Michel Daage ,  Christopher Gordon Oliveri ,  Thomas Francis Degnan ,  Jose Guadalupe Santiesteban ,  Ajit Bhaskar Dandekar ,  William Joseph Novak ,  Wenyih F. Lai

IPC: C10G65/02

CPC classification number: C10G65/12 ,  C10G45/12 ,  C10G65/043 ,  C10G67/04 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/10

Abstract: An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants. The integrated process includes an initial hydrotreatment, hydrocracking, catalytic dewaxing of the hydrocracking effluent, and an option final hydrotreatment.

Abstract translation: 提供了一种在酸性条件下从原料生产石脑油燃料，柴油和/或润滑油基础油的综合方法。 在更高硫和/或氮条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。 可以将酸性进料输送到催化脱蜡步骤，而不会分离硫和氮污染物，或者可以使用高压分离来部分地消除污染物。 整合过程包括初步的加氢处理，加氢裂化，加氢裂化流出物的催化脱蜡以及最终的加氢处理。

公开(公告)号：US20090005627A1

公开(公告)日：2009-01-01

申请号：US12157971

申请日：2008-06-13

Applicant: Darden Sinclair ,  Michel Daage ,  Charles J. Mart ,  Louis Burns ,  Timothy L. Hilbert

Inventor： Darden Sinclair ,  Michel Daage ,  Charles J. Mart ,  Louis Burns ,  Timothy L. Hilbert

IPC: C07C7/148

CPC classification number: C10G65/043 ,  B01J21/063 ,  B01J23/44 ,  B01J29/0325 ,  B01J29/043 ,  B01J29/7461 ,  B01J35/0026 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/62 ,  C10G65/08 ,  C10G73/02 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/4018 ,  C10G2400/10

Abstract: Integrated hydroprocessing methods using high activity, low density catalysts are provided. The high activity catalysts allow for blocked operation when processing lube range feedstocks of widely varying characteristics, such as wax content, without having to substantially change the configuration or operating conditions of the process train. Instead, the different feedstocks can be accommodated by varying the reaction temperature in the process train.

Abstract translation: 提供了使用高活性，低密度催化剂的综合加氢处理方法。 当处理广泛变化的特性（例如蜡含量）的润滑剂范围原料时，高活性催化剂允许堵塞操作，而不必基本上改变工艺列车的构造或操作条件。 相反，可以通过改变过程列中的反应温度来适应不同的原料。

公开(公告)号：US06753354B2

公开(公告)日：2004-06-22

申请号：US10059916

申请日：2002-01-29

Applicant: Russell John Koveal ,  Michel Daage ,  Eric Baochun Shen

Inventor： Russell John Koveal ,  Michel Daage ,  Eric Baochun Shen

IPC: C07C2700

CPC classification number: C10G2/332 ,  B01J21/063 ,  B01J23/40 ,  B01J23/70 ,  B01J23/94 ,  B01J23/96 ,  B01J38/10 ,  B01J38/12 ,  B01J38/62 ,  B01J38/66 ,  B01J38/70 ,  C10G2/333

Abstract: There is provided a process for hydrocarbon synthesis wherein a supported metal catalyst for hydrogenating carbon monoxide to form a mixture of hydrocarbons is regenerated by decreasing its hydrocarbon content, impregnating under a non-oxidative atmosphere with a solution of at least one member selected from the group consisting of ammonium salts, alkyl ammonium salts and weak organic acids, optionally including ammonia, oxidizing with a gaseous oxidant in the presence of the impregnating solution, activating the catalyst by reduction with hydrogen at elevated temperatures and reusing the catalyst. The treatment may be carried out in a single reactor, or by carrying out up to all steps after catalyst has been withdrawn therefrom and returned to at least one reactor. Up to all steps subsequent to decreasing the hydrocarbon content may be effected in a subsequent reactor, or in specialized apparatus.

Abstract translation: 提供了一种用于烃合成的方法，其中用于氢化一氧化碳以形成烃混合物的负载型金属催化剂通过降低其烃含量而再生，在非氧化性气氛下用选自组中的至少一种的溶液浸渍 由铵盐，烷基铵盐和弱有机酸，任选地包括氨，在浸渍溶液存在下用气态氧化剂氧化，通过在高温下用氢还原并重新使用催化剂来活化催化剂。 处理可以在单个反应器中进行，或者通过在催化剂从其中排出之后进行到所有步骤，并且返回至少一个反应器。 直到降低碳氢化合物含量后的所有步骤可以在随后的反应器中或在专门的装置中进行。

公开(公告)号：US06221240B1

公开(公告)日：2001-04-24

申请号：US09326827

申请日：1999-06-07

Applicant: Darryl P. Klein ,  Michele S. Touvelle ,  Edward S. Ellis ,  Carl W. Hudson ,  Sylvain Hantzer ,  Jingguang Chen ,  David E. W. Vaughan ,  Michel Daage ,  James J. Schorfheide ,  William C. Baird, Jr. ,  Gary B. McVicker

Inventor： Darryl P. Klein ,  Michele S. Touvelle ,  Edward S. Ellis ,  Carl W. Hudson ,  Sylvain Hantzer ,  Jingguang Chen ,  David E. W. Vaughan ,  Michel Daage ,  James J. Schorfheide ,  William C. Baird, Jr. ,  Gary B. McVicker

IPC: C10G4500

CPC classification number: C10G25/003 ,  C10G45/10

Abstract: A process for the hydrodesulfurization (HDS) of multiple condensed ring heterocyclic organosulfur compounds present in petroleum and petrochemical streams and the saturation of aromatics over noble metal-containing catalysts under relatively mild conditions. The noble metal is selected from Pt, Pd, Ir, Rh and polymetallics thereof. The catalyst system also contains a hydrogen sulfide sorbent material.

Abstract translation: 存在于石油和石油化学物流中的多种稠环杂环有机硫化合物的加氢脱硫（HDS）和在相对温和的条件下含贵金属的催化剂的芳族化合物的饱和过程。 贵金属选自Pt，Pd，Ir，Rh及其多金属。 催化剂体系还含有硫化氢吸附剂材料。

公开(公告)号：US6103106A

公开(公告)日：2000-08-15

申请号：US326843

申请日：1999-06-07

Applicant: Gary B. McVicker ,  James J. Schorfheide ,  William C. Baird Jr. ,  Michele S. Touvelle ,  Michel Daage ,  Darryl P. Klein ,  Edward S. Ellis ,  David E.W. Vaughan ,  Jingguang Chen ,  Sylvain S. Hantzer

Inventor： Gary B. McVicker ,  James J. Schorfheide ,  William C. Baird Jr. ,  Michele S. Touvelle ,  Michel Daage ,  Darryl P. Klein ,  Edward S. Ellis ,  David E.W. Vaughan ,  Jingguang Chen ,  Sylvain S. Hantzer

IPC: C10G45/10 ,  C10G65/04 ,  C10G65/08 ,  C10G67/06 ,  C10G45/00

CPC classification number: C10G67/06 ,  C10G45/10 ,  C10G65/04 ,  C10G65/043 ,  C10G65/08

Abstract: A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds and the ring opening of ring compounds present in petroleum and petrochemical streams. The process is conducted in the presence of hydrogen, one or more noble metal catalysts, and a hydrogen sulfide sorbent material.

Abstract translation: 多重稠环杂环有机硫化合物的加氢脱硫（HDS）和存在于石油和石油化工流中的环化合物的开环方法。 该方法在氢气，一种或多种贵金属催化剂和硫化氢吸附剂材料的存在下进行。

公开(公告)号：US09487714B2

公开(公告)日：2016-11-08

申请号：US14011061

申请日：2013-08-27

Applicant: William J. Novak ,  Robert Allen Bradway ,  Stuart S. Shih ,  Timothy Lee Hilbert ,  Michel Daage

Inventor： William J. Novak ,  Robert Allen Bradway ,  Stuart S. Shih ,  Timothy Lee Hilbert ,  Michel Daage

IPC: C10G47/18 ,  C10G49/04 ,  C10G65/10 ,  C10G65/12

CPC classification number: C10G65/10 ,  C10G47/18 ,  C10G49/04 ,  C10G65/12 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/307 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/10

Abstract: This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.

公开(公告)号：US09458367B2

公开(公告)日：2016-10-04

申请号：US13793298

申请日：2013-03-11

Applicant: Michael Siskin ,  Robert Basil Fedich ,  Michel Daage

Inventor： Michael Siskin ,  Robert Basil Fedich ,  Michel Daage

IPC: C09K3/00 ,  B01D53/14

CPC classification number: C09K3/00 ,  B01D53/1468 ,  B01D53/1493 ,  B01D2252/103 ,  B01D2252/2023 ,  B01D2252/2025 ,  B01D2252/204 ,  B01D2252/504 ,  B01D2252/60 ,  Y10T137/0391

Abstract: A liquid aminoether acid gas absorbent which is subject to freezing in a cold climatic zone though which the aminoether is to be shipped is rendered freeze-resistant by mixing the aminoether with water prior to transport through the cold climatic zone; the aminoether/water mixture typically contains 10 to 40 weight percent water, based on the weight of the aminoether. The aminoether/water mixture can also be stored in the cold climatic zone without being externally maintained at a temperature above the inherent freezing point of the aminoether.

Abstract translation: 在运输氨基醚的寒冷气候区域内要冷冻的液体氨基醚酸吸收剂在通过冷气候区域运输之前通过混合氨基醚与水而变成抗冻性; 基于氨基醚的重量，氨基醚/水混合物通常含有10至40重量％的水。 氨基醚/水混合物也可以储存在寒冷气候区，而不会外部保持在高于氨基醚固有凝固点的温度。

公开(公告)号：US09221725B2

公开(公告)日：2015-12-29

申请号：US13917743

申请日：2013-06-14

Applicant: Virginia M. Roberts ,  Michel Daage ,  Paul D. Oldenburg ,  Suzzy C. Ho ,  Kun Wang ,  Bradley R. Fingland

Inventor： Virginia M. Roberts ,  Michel Daage ,  Paul D. Oldenburg ,  Suzzy C. Ho ,  Kun Wang ,  Bradley R. Fingland

IPC: C07C1/00 ,  C07C1/207 ,  C10G29/22 ,  C10G3/00 ,  C11C3/00 ,  B01J21/12 ,  B01J23/02 ,  B01J23/10

CPC classification number: C07C1/2076 ,  B01J21/12 ,  B01J23/02 ,  B01J23/10 ,  C10G3/44 ,  C10G3/50 ,  C10G29/22 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/10 ,  C11C3/00 ,  Y02E50/13 ,  Y02P30/20

Abstract: Methods are provided for processing glycerides to form lubricant boiling range molecules in a single reactor and/or a single reaction zone. The glycerides are exposed to catalysts that are stable under the conditions present in the reaction zones during conversion of glycerides to fatty ketones via a coupling reaction in the presence of a first catalyst, and the subsequent deoxygenation and isomerization of the ketones in the presence of a second dewaxing catalyst. The glyceride-containing feedstock can further include free fatty acids or fatty acid derivatives that can also be used for formation of ketones and subsequent deoxygenation and isomerization. In some configuration, the processing can occur in a single reaction zone containing mixed beds of the first and second catalyst. Such configurations can be used to control the ratio of diesel boiling range molecules versus lubricant boiling range molecules generated by the methods.

Abstract translation: 提供了用于处理甘油酯以在单个反应器和/或单个反应区中形成润滑剂沸程分子的方法。 将甘油酯暴露于在第一催化剂存在下通过偶联反应将甘油酯转化成脂肪酮的反应区中存在的条件下稳定的催化剂，以及随后在存在下的酮的脱氧和异构化 第二脱蜡催化剂。 含甘油酯的原料还可以包括游离脂肪酸或脂肪酸衍生物，其还可用于形成酮和随后的脱氧和异构化。 在一些配置中，处理可以发生在包含第一和第二催化剂的混合床的单个反应区中。 这种配置可用于控制柴油沸程分子与通过该方法产生的润滑剂沸程分子的比例。