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    Manufacture of butanedicarboxylic acid esters
    22.
    发明授权
    Manufacture of butanedicarboxylic acid esters 失效
    丁二酸酸酯的制备

    公开(公告)号：US4169956A

    公开(公告)日：1979-10-02

    申请号：US940463

    申请日：1978-09-08

    Applicant: Rudolf Kummer ,  Heinz-Walter Schneider ,  Franz-Josef Weiss

    Inventor： Rudolf Kummer ,  Heinz-Walter Schneider ,  Franz-Josef Weiss

    IPC: B01J31/00 ,  C07B61/00 ,  C07C67/38 ,  C07C69/44

    CPC classification number: C07C67/38

    Abstract: A process for the manufacture of butanedicarboxylic acid esters, wherein(a) an aqueous cobalt salt solution is treated with carbon monoxide and hydrogen in the presence of active charcoal,(b) the resulting aqueous solution is extracted with butadiene or with a hydrocarbon mixture containing butadiene,(c) the butadiene, or butadiene/hydrocarbon mixture, containing cobalt carbonyl hydride, cobalt carbonyl and butenyl-cobalt tricarbonyl, is reacted with carbon monoxide and an excess of an alkanol of 1 to 4 carbon atoms in the presence of a tertiary nitrogen base,(d) the tertiary nitrogen bases contained in the resulting reaction mixture are removed from the latter to the extent of leaving from 0.1 to 0.3 mole per mole of pentenoic acid ester, excess hydrocarbons are also removed, the pentenoic acid ester remaining in the reaction mixture is reacted with carbon monoxide and an alkanol of 1 to 4 carbon atoms, and thereafter excess alkanol and free nitrogen base are distilled off and(e) the residual reaction mixture, containing cobalt catalysts, butanedicarboxylic acids and by-products is treated with an oxidizing agent in an aqueous acid medium and the mixture is separated into an organic phase, from which butanedicarboxylic acid esters are isolated by distillation, and an aqueous phase containing cobalt salts, which phase is extracted with a water-immiscible solvent.

    Manufacture of methacrylic acid and butyrolactone
    23.
    发明授权
    Manufacture of methacrylic acid and butyrolactone 失效
    甲基丙烯酸和丁内酯的制造

    公开(公告)号：US3980670A

    公开(公告)日：1976-09-14

    申请号：US552734

    申请日：1975-02-25

    Applicant: Rudolf Kummer ,  Rolf Platz ,  Kurt Schwirten

    Inventor： Rudolf Kummer ,  Rolf Platz ,  Kurt Schwirten

    IPC: C07C69/02 ,  B01J21/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/14 ,  C07C51/377 ,  C07C57/065 ,  C07C67/00 ,  C07D307/33 ,  C07D315/00 ,  C07D307/32

    CPC classification number: C07D315/00 ,  C07C51/14 ,  C07C51/377

    Abstract: Methacrylic acid and butyrolactone are manufactured by hydroformylation of allyl esters of lower carboxylic acids in the presence of rhodium catalysts and inert organic solvents, followed by oxidation of the resulting formyl compounds with molecular oxygen (e.g. with air) in the presence of lower fatty acids, without prior removal of the rhodium catalysts, and elimination of the carboxylic acid from the acyloxybutyric acids formed, at from 150.degree. to 500.degree.C, using catalysts such as aluminum oxide, silicates or active charcoal.

    Abstract translation: 甲基丙烯酸和丁内酯是通过在铑催化剂和惰性有机溶剂的存在下将低级羧酸的烯丙酯加氢甲酰化，然后在低级脂肪酸存在下用分子氧（例如与空气）氧化得到的甲酰基化合物来制备的， 没有事先去除铑催化剂，并且使用催化剂如氧化铝，硅酸盐或活性炭，在150℃至500℃下从形成的酰氧基丁酸中除去羧酸。

    Preparation of amines from olefins over boron beta-zeolites
    24.
    发明授权
    Preparation of amines from olefins over boron beta-zeolites 失效
    通过硼β-沸石从烯烃制备胺

    公开(公告)号：US6143934A

    公开(公告)日：2000-11-07

    申请号：US341

    申请日：1998-01-20

    Applicant: Uwe Dingerdissen ,  Rudolf Kummer ,  Peter Stops ,  Ulrich Muller ,  Jurgen Herrmann ,  Karsten Eller

    Inventor： Uwe Dingerdissen ,  Rudolf Kummer ,  Peter Stops ,  Ulrich Muller ,  Jurgen Herrmann ,  Karsten Eller

    IPC: B01J29/86 ,  C07B61/00 ,  C07C209/60 ,  C07C211/07 ,  C07C211/35 ,  C07C209/00

    CPC classification number: C07C209/60

    Abstract: In a process for preparing amines of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 are hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl,R.sup.1 and R.sup.2 are together a saturated or unsaturated, divalent C.sub.3 -C.sub.9 -alkylene chain andR.sup.3 and R.sup.5 are each C.sub.21 -C.sub.200 -alkyl, C.sub.21 -C.sub.200 -alkenyl or together are a divalent C.sub.2 -C.sub.12 -alkylene chain,by reacting olefins of the general formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are as defined above, with ammonia or primary or secondary amines of the general formula III ##STR3## where R.sup.1 and R.sup.2 are as defined above, at from 200 to 350.degree. C. and pressures of from 100 to 300 bar in the presence of a zeolitic catalyst, the zeolitic catalyst used is a boron BETA-zeolite.

    Abstract translation: PCT No.PCT / EP96 / 03634 371日期1998年1月20日 102（e）1998年1月20日PCT PCT 1996年8月19日PCT公布。 出版物WO97 / 07088 日期：1997年2月27日在制备通式I的胺的方法中，其中R 1，R 2，R 3，R 4，R 5，R 6为氢，C 1 -C 20 - 烷基，C 2 -C 20 - 烯基，C 2 -C 20炔基，C 3 C 20 - 环烷基，C 4 -C 20 - 烷基环烷基，C 4 -C 20 - 环烷基烷基，芳基，C 7 -C 20 - 烷基芳基或C 7 -C 20 - 芳烷基，R 1和R 2一起是饱和或不饱和的二价C 3 -C 9 - 亚烷基链和R 3 和R 5各自为C 21 -C 20 - 烷基，C 21 -C 2-链烯基或一起为二价C 2 -C 12 - 亚烷基链，其中R 3，R 4，R 5和R 6如上定义的通式II的烯烃与氨 或通式III的伯胺或仲胺，其中R 1和R 2如上定义，在沸石催化剂存在下，在200-350℃和100-300巴的压力下，所用的沸石催化剂是硼 BETA-沸石。

    Preparation of amines from olefins over mesoporous oxides having a high surface area
    25.
    发明授权
    Preparation of amines from olefins over mesoporous oxides having a high surface area 失效
    从具有高表面积的介孔氧化物上由烯烃制备胺

    公开(公告)号：US5780680A

    公开(公告)日：1998-07-14

    申请号：US839800

    申请日：1997-04-18

    Applicant: Karsten Eller ,  Rudolf Kummer ,  Ulrich Muller

    Inventor： Karsten Eller ,  Rudolf Kummer ,  Ulrich Muller

    IPC: B01J21/12 ,  B01J23/10 ,  C07B61/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/03 ,  C07C211/16 ,  C07C211/21 ,  C07C211/25 ,  C07C211/26 ,  C07C211/34 ,  C07C211/45 ,  C07C211/54 ,  C07C211/57

    CPC classification number: C07C209/60

    Abstract: In a process for preparing amines of the formula I ##STR1## where R.sup.1,R.sup.2,R.sup.3,R.sup.4,R.sup.5,R.sup.6 are hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkyl-cycloalkyl, C.sub.4 -C.sub.20 -cycloalkyl-alkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl, R.sup.1 and R.sup.2 together form a saturated or unsaturated, divalent C.sub.3 -C.sub.9 -alkylene chain and R.sup.3 and R.sup.5 are C.sub.21 -C.sub.200 -alkyl, C.sub.21 -C.sub.200 -alkenyl or together form a divalent C.sub.2 -C.sub.12 -alkylene chain, by reating olefins of the formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are as defined above, with ammonia or primary or secondary amines of the formula III ##STR3## where R.sup.1 and R.sup.2 are as defined above, at from 200.degree. to 350.degree. C. and a pressure of from 100 to 300 bar in the presence of a heterogeneous catalyst, the heterogeneous catalysts being mesoporous oxides having a high surface area.

    Abstract translation: 在制备式I的胺的方法中，其中R 1，R 2，R 3，R 4，R 5，R 6为氢，C 1 -C 20 - 烷基，C 2 -C 20 - 烯基，C 2 -C 20 - 炔基，C 3 -C 20 - 环烷基，C 4 -C 20 - 烷基 - 环烷基，C 4 -C 20 - 环烷基 - 烷基，芳基，C 7 -C 20 - 烷基芳基或C 7 -C 20 - 芳烷基，R 1和R 2一起形成饱和或不饱和的二价C 3 -C 9 - 亚烷基链和R 3和R 5是C 21 -C 200-烷基，C 21 -C 2-链烯基或一起形成二价C 2 -C 12亚烷基链，通过反应式II的烯烃（II），其中R3，R4，R5和 R6如上定义，与式III的氨或伯或仲胺（III）其中R 1和R 2如上定义，在200-350℃和100-300巴的压力下 在非均相催化剂的存在下，非均相催化剂是具有高表面积的介孔氧化物。

    Obtaining C.sub.1 -C.sub.4 -alkyl pentenoates by distillation
    29.
    发明授权
    Obtaining C.sub.1 -C.sub.4 -alkyl pentenoates by distillation 失效
    通过蒸馏获得戊烯酸C1-C4烷基酯

    公开(公告)号：US4586987A

    公开(公告)日：1986-05-06

    申请号：US721810

    申请日：1985-04-10

    Applicant: Heinz-Walter Schneider ,  Rudolf Kummer ,  Otto Leman ,  Paul Panitz

    Inventor： Heinz-Walter Schneider ,  Rudolf Kummer ,  Otto Leman ,  Paul Panitz

    IPC: B01J31/00 ,  B01J31/20 ,  C07B61/00 ,  C07C67/38 ,  C07C69/533 ,  B01D3/34 ,  C07C67/54

    CPC classification number: C07C67/54

    Abstract: C.sub.1 -C.sub.4 -alkyl pentenoates are obtained from reaction mixtures which contain this and which are obtained by reacting butadiene, or a butadiene-containing hydrocarbon mixture, with carbon monoxide and a C.sub.1 -C.sub.4 -alkanol, in the presence of a cobalt carbonyl catalyst and a tertiary nitrogen base at elevated temperatures and under superatmospheric pressure by a process in which(a) the liquid reaction mixture freed from excess carbon monoxide is treated with hydrogen at elevated temperatures and under from 5 to 80 bar,(b) hydrocarbons are distilled off from the resulting liquid reaction mixture,(c) the C.sub.1 -C.sub.4 -alkyl pentenoate, the alkanol and the nitrogen base are then distilled off under reduced pressure, and(d) the C.sub.1 -C.sub.4 -alkyl pentenoate is obtained by fractional distillation from the distillate containing this compound, the alkanol and the tertiary nitrogen base.

    Abstract translation: 由含有这一点的反应混合物获得戊烯酸C 1 -C 4烷基酯，其通过使丁二烯或含丁二烯的烃混合物与一氧化碳和C 1 -C 4烷醇在羰基钴催化剂存在下反应获得， 在高温和超大气压下，通过一种方法，（a）在高温和5至80巴下用氢处理脱除过量一氧化碳的液体反应混合物，（b）将烃蒸馏掉， 从所得液体反应混合物中，（c）戊烯酸C 1 -C 4烷基酯，然后在减压下蒸馏除去链烷醇和氮碱，并且（d）戊烯酸C1-C4烷基酯是通过从 含有该化合物的馏出物，链烷醇和叔氮碱。

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