摘要:
A photorefractive compositions of the present invention includes a copolymer component that provides both photoconductive (charge transport) ability and non-linear optical ability, and optionally sensitizer and plasticizer components. Both of the photoconductive and non-linear optical components are incorporated into the chemical structure of the copolymer itself, typically as side groups. Furthermore, the composition includes a copolymer component that provides photoconductive (charge transport) ability, non-linear optical ability, and plasticizer ability, optionally, sensitizer and plasticizer components.
摘要:
Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.
摘要:
Naphthalene diimide (NDI) compounds can be functionalized with tin reagent to provide a useful, versatile synthetic tool. One embodiment provides, for example, a composition comprising at least one NDI compound comprising at least one stannyl substituent bonded to the naphthalene moiety of the NDI compound. Applications include organic electronic devices including OLED, OPV, OFET, and sensing devices.
摘要:
The inventions describe disclosed and described herein relate to polymerizable ambipolar monomers, useful for making polymer or copolymer host materials for guest phosphorescent metal complexes, which together can form emission layers of organic light emitting diodes (OLEDs). Methods of making the ambipolar monomers are also described. Formula (I) wherein at least one of the R1, R2 and R3 groups is an optionally substituted carbazole group.
摘要:
The present invention describes compounds with iridium complexes and poly(norbornene)s made therefrom. Methods of making the compounds and the poly(norbornene)s are also described. Further disclosed herein are light-emitting diodes employing such poly(norbornene)s which are covalently attached to a hole transport material.
摘要:
Continuous, conducting metal patterns can be formed from metal nanoparticle containing films by exposure to radiation (FIG. 1). The metal patterns can be one, two, or three dimensional and have high resolution resulting in feature sizes in the order of micron down to nanometers Compositions containing the nanoparticles coated with a ligand and further including a dye, a metal salt, and either a matrix or an optional sacrificial donor are also disclosed.
摘要:
A device and method for producing a third harmonic signal from an optical pulse of wavelength k. In the device and method, an optical pulse at a wavelength k is incident on a material including at least one molecule having a formula D—U—A, where D is an electron donor group, A is an electron acceptor group, and Π is a conjugated structure having it bonds that connect D to A. The molecule exhibits a strong absorption band centered at a wavelengthko and a weakly absorbing region centered at a wavelength k, which is less than Xo. A wavelength k/2 has a value of about Xo, and a wavelength k/3 has a value of about X1. A third harmonic signal at k/3 is generated. From a measured third harmonic signal as a function of a time delay for separate optical pulses entering the material, at least one of a pulse width and a pulse shape of the optical pulse can be extracted. From a spectrally resolved third harmonic signal, a phase of the optical pulse can be extracted.
摘要:
Novel polydioxaborines are prepared by polymerizing novel monomers that contain a dioxaborine group. Polydioxaborines are readily soluble, excellent film formers, and have semiconducting properties useful in various applications.
摘要:
A photorefractive composition comprising a polymer prepared by living radical polymerization, wherein: the living radical polymerization is carried out using a monomer, a polymerization initiator, transition metal catalyst and a ligand capable of reversibly forming a complex with the transition metal catalyst, and the polymer comprises at least one of a repeat unit including a moiety having charge transport ability and a repeat unit including a moiety having non-linear-optical ability.
摘要:
Compositions for use in non-linear optical devices. The compositions have high first molecular electronic hyperpolarizability (.beta.) and therefore display high second order non-linear optical properties when incorporated into non-linear optical devices. The acceptor and donor groups which are used in the compositions, along with the .pi.(pi)-bridge length is chosen to optimize second-order non-linear optical responses.