摘要:
Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.
摘要:
Improved nanolithography components, systems, and methods are described herein. The systems and methods generally employ a resistively heated atomic force microscope tip to thermally induce a chemical change in a surface. In addition, certain polymeric compositions are also disclosed.
摘要:
Continuous, conducting metal patterns can be formed from metal nanoparticle containing films by exposure to radiation (FIG. 1). The metal patterns can be one, two, or three dimensional and have high resolution resulting in feature sizes in the order of micron down to nanometers. Compositions containing the nanoparticles coated with a ligand and further including a dye, a metal salt, and either a matrix or an optional sacrificial donor are also disclosed.
摘要:
Polydioxaborine compositions are prepared by intermixing a polydioxaborine and a non-linear optical chromophore. Preferred polydioxaborine compositions are photorefractive and/or photoconductive composites.
摘要:
Disclosed are fused ring bridge, ring-locked dyes that form thermally stable photorefractive compositions. The fused ring bridge structures are &pgr;-conjugated bonds in benzene-, naphthalene- or anthracene-derived fused ring systems that connect donor and acceptor groups. The donor and acceptor groups contribute to a high molecular dipole moment and linear polarizability anisotropy. The polarization characteristics of the dye molecules are stabilized since the bonds in the fused ring bridge are not susceptible to rotation, reducing the opportunity for photoisomerization. The dyes are compatible with polymeric compositions, including thermoplastics. The dyes are electrically neutral but have charge transport, electronic and orientational properties such that upon illumination of a composition containing the dye, the dye facilitates refractive index modulation and a photorefractive effect that can be utilized advantageously in numerous applications such as in optical quality devices and biological imaging.
摘要:
Naphthalene diimide (NDI) compounds can be functionalized with tin reagent to provide a useful, versatile synthetic tool. One embodiment provides, for example, a composition comprising at least one NDI compound comprising at least one stannyl substituent bonded to the naphthalene moiety of the NDI compound. Applications include organic electronic devices including OLED, OPV, OFET, and sensing devices.
摘要:
Continuous, conducting metal patterns can be formed from metal nanoparticle containing films by exposure to radiation (FIG. 1). The metal patterns can be one, two, or three dimensional and have high resolution resulting in feature sizes in the order of micron down to nanometers Compositions containing the nanoparticles coated with a ligand and further including a dye, a metal salt, and either a matrix or an optional sacrificial donor are also disclosed.
摘要:
The present invention comprises an optical data storage system utilizing a host material and molecules that exhibit non-linear absorption dissolved therein. The non-linear absorbing molecules allow for energy in the form of heat to be generated during the optical data storage process. This heat provides for localized alterations to occur in the pre-formatted holographic grating. The non-linear feature of these molecules allow for alterations to occur at specific depths and locations within the storage medium while limiting the secondary effects on other locations within the storage medium. The molecules exhibiting non-linear absorption may be selected from the group of molecules exhibiting two-photon absorption or reverse saturable absorption. The invention also comprises a method for preparing the optical storage medium, an optical data storage device comprising the optical data storage medium and having a format hologram stored within the medium. Additionally, the invention comprises an optical data storage system and method for use thereof wherein the storage system uses the optical data storage medium described above when altering a pre-formatted holographic grating in a localized region by non-linear thermal disruption of the grating. Another embodiment of the present invention comprises an optical data retrieval system embodying the optical data storage device described above and a method for retrieving the format hologram stored on the optical data storage device of the present invention.
摘要:
Compositions for use in non-linear optical devices. The compositions have high first molecular electronic hyperpolarizability (.beta.) and therefore display high second order non-linear optical properties when incorporated into non-linear optical devices. The acceptor and donor groups which are used in the compositions, along with the .pi.(pi)-bridge length is chosen to optimize second-order non-linear optical responses.
摘要:
Compositions for use in non-linear optical devices. The compositions have first molecular electronic hyperpolarizability (.beta.) either positive or negative in sign and therefore display second order non-linear optical properties when incorporated into non-linear optical devices.