PHASE BOUNDARY PROCESSES FOR PREPARING POLYCARBONATES
    22.
    发明申请
    PHASE BOUNDARY PROCESSES FOR PREPARING POLYCARBONATES 有权
    制备聚碳酸酯的相边界工艺

    公开(公告)号:US20090275709A1

    公开(公告)日:2009-11-05

    申请号:US12398243

    申请日:2009-03-05

    IPC分类号: C08F2/04

    CPC分类号: C08G64/24

    摘要: Continuous processes for preparing polycarbonates having a weight average molecular weight MW, of 15,000 to 200,000 g/mol, the processes comprising reacting a dihydroxydiarylalkane and phosgene in the presence of a catalyst in a phase boundary process comprising: continuously dispersing in a disperser an organic phase comprising at least a portion of the phosgene and a solvent suitable for the polycarbonate and an aqueous phase comprising the dihydroxydiarylalkane, water and an alkali solution present in an amount of 1.5 to 2.5 moles per mole of the dihydroxydiarylalkane, to form a mixture; reacting the mixture in a first reactor with a residence time of less than 0.5 seconds; further reacting the mixture in a second reactor with addition of further alkali solution and, optionally, a chain terminator; and effecting further condensation in a third reactor with addition of further alkali solution and, optionally, a chain terminator, in the presence of the catalyst.

    摘要翻译: 用于制备重均分子量MW为15,000至200,000g / mol的聚碳酸酯的连续方法,包括在相界过程中在催化剂存在下使二羟基二芳基烷烃和光气反应的方法包括:在分散器中连续分散有机相 包含至少一部分光气和适用于聚碳酸酯的溶剂和包含二羟基二芳基烷烃的水相,每摩尔二羟基二芳基烷烃存在的量为1.5至2.5摩尔的水和碱溶液形成混合物; 使混合物在第一反应器中反应,停留时间小于0.5秒; 在第二反应器中进一步使混合物反应,再加入另外的碱溶液和任选的链终止剂; 并在催化剂存在下,在第三反应器中进一步加入另外的碱溶液和任选的链终止剂。

    Production and use of polycarbonates with special purified, oligomeric epoxy resins
    24.
    发明申请
    Production and use of polycarbonates with special purified, oligomeric epoxy resins 审中-公开
    生产和使用聚碳酸酯与特殊纯化的低聚环氧树脂

    公开(公告)号:US20070088107A1

    公开(公告)日:2007-04-19

    申请号:US11545394

    申请日:2006-10-10

    IPC分类号: C08K5/15

    摘要: A thermoplastic composition having improved rheological and optical properties containing aromatic polycarbonate and an oligomeric epoxy resin is disclosed. The epoxy resin that conforms to formula (I) wherein R1, R2 mutually independently denote H, C1-C12 alkyl, cyclic C5-C12 alkyl, phenyl or benzyl groups and n is an integer of 0 to 20, contains no more than 0.1% water. A process for purifying the epoxy is also disclosed

    摘要翻译: 公开了一种具有改进的流变学和光学性质的含芳族聚碳酸酯和低聚环氧树脂的热塑性组合物。 符合式(I)的环氧树脂,其中R 1,R 2,2彼此独立地表示H,C 1 -C 12 烷基,环C 5 -C 12烷基,苯基或苄基,n是0至20的整数,含有不超过0.1%的水。 还公开了一种净化环氧树脂的方法

    Polycarbonates with good wettability
    25.
    发明申请
    Polycarbonates with good wettability 有权
    具有良好润湿性的聚碳酸酯

    公开(公告)号:US20060135735A1

    公开(公告)日:2006-06-22

    申请号:US11312020

    申请日:2005-12-20

    IPC分类号: C08G64/00

    摘要: A polycarbonate resin that after alkaline hydrolysis with sodium hydroxide contain an amount of 0.01 to 150 ppm of carbamate compounds according to formula (1) wherein R1 and R2 independently of one another denote hydrogen or C1-C12-alkyl, or together denote C4-C12-alkylidene, and R3 and R4 independently of one another denote hydrogen, C1-C12-alkyl or phenyl, or together with the carbon atom to which they are bonded form cyclohexyl or trimethylcyclohexyl, said amount measured after alkaline hydrolysis with sodium hydroxide by high pressure liquid chromatography.

    摘要翻译: 用氢氧化钠碱性水解后的聚碳酸酯树脂含有0.01〜150ppm的式(1)的氨基甲酸酯化合物,其中R 1和R 2独立地为1 另一个表示氢或C 1 -C 12 - 烷基,或一起表示C 4 -C 12 - 亚烷基 ,R 3和R 4彼此独立地表示氢,C 1 -C 12 - 烷基或 苯基或与它们键合的碳原子一起形成环己基或三甲基环己基,所述量通过高压液相色谱用氢氧化钠碱化后测量。

    Compositions containing polycarbonate
    29.
    发明授权
    Compositions containing polycarbonate 有权
    含有聚碳酸酯的组合物

    公开(公告)号:US06713181B2

    公开(公告)日:2004-03-30

    申请号:US10356948

    申请日:2003-02-03

    IPC分类号: B32B2736

    摘要: A thermoplastic molding composition is disclosed. The composition that contains a polymer selected from the group consisting of a polycarbonate, a transparent polycarbonate-polyester-blend, a copolyestercarbonate and a transparent polyester and a compound of formula (I) and one or more compounds of formula (II) wherein a is 1 to 17, b is 0 to 16, c is 6 to 14, d is 3 to 7, e is 6 to 14, f is 3 to 7, g is 5 to 40 and a+b is 9 to 25 and n is 1 to 10, was found to be especially suitable for co-extrusion applications.

    摘要翻译: 公开了一种热塑性模塑组合物。 含有选自聚碳酸酯,透明聚碳酸酯 - 聚酯共混物,共聚酯碳酸酯和透明聚酯以及式(I)化合物和一种或多种式(II)化合物的聚合物的组合物,其中a为 1〜17,b为0〜16,c为6〜14,d为3〜7,e为6〜14,f为3〜7,g为5〜40,a + b为9〜25,n为 被发现特别适用于共挤出应用。