摘要:
The present invention relates to polycarbonate, polyester carbonate and polyester having end groups derived from alkylsiloxane-substituted phenols, as well as to the use of phenolic compounds having alkylsiloxane substituents as chain terminators in the preparation of polycarbonate, polyester carbonate and polyester, as well as to mouldings and extrudates produced from these polymers, to processes for the preparation of the polymers, and to novel phenolic compounds of formula (2).
摘要:
Continuous processes for preparing polycarbonates having a weight average molecular weight MW, of 15,000 to 200,000 g/mol, the processes comprising reacting a dihydroxydiarylalkane and phosgene in the presence of a catalyst in a phase boundary process comprising: continuously dispersing in a disperser an organic phase comprising at least a portion of the phosgene and a solvent suitable for the polycarbonate and an aqueous phase comprising the dihydroxydiarylalkane, water and an alkali solution present in an amount of 1.5 to 2.5 moles per mole of the dihydroxydiarylalkane, to form a mixture; reacting the mixture in a first reactor with a residence time of less than 0.5 seconds; further reacting the mixture in a second reactor with addition of further alkali solution and, optionally, a chain terminator; and effecting further condensation in a third reactor with addition of further alkali solution and, optionally, a chain terminator, in the presence of the catalyst.
摘要:
A process for treating the working surfaces of equipment used in the production and processing of polycarbonate is disclosed. The thermal treatment in an oxidative atmosphere results in resin and molded articles having improved optical quality.
摘要:
A thermoplastic composition having improved rheological and optical properties containing aromatic polycarbonate and an oligomeric epoxy resin is disclosed. The epoxy resin that conforms to formula (I) wherein R1, R2 mutually independently denote H, C1-C12 alkyl, cyclic C5-C12 alkyl, phenyl or benzyl groups and n is an integer of 0 to 20, contains no more than 0.1% water. A process for purifying the epoxy is also disclosed
摘要:
A polycarbonate resin that after alkaline hydrolysis with sodium hydroxide contain an amount of 0.01 to 150 ppm of carbamate compounds according to formula (1) wherein R1 and R2 independently of one another denote hydrogen or C1-C12-alkyl, or together denote C4-C12-alkylidene, and R3 and R4 independently of one another denote hydrogen, C1-C12-alkyl or phenyl, or together with the carbon atom to which they are bonded form cyclohexyl or trimethylcyclohexyl, said amount measured after alkaline hydrolysis with sodium hydroxide by high pressure liquid chromatography.
摘要:
Optical fibers suitable for transmission of optical signals and comprising a core that contains polycarbonate are disclosed. The polycarbonate is characterized in its low content of insoluble particles.
摘要:
The invention relates to new, monomeric, perfluoroalkyl-substituted metal complexes, processes for their production, and their use in diagnosis and therapy.The compounds according to the invention are suitable especially as in vivo contrast media in nuclear spin tomography (MRT). They can preferably be used as blood-pool agents and as lymphographic agents.
摘要:
The use of zwitterionic compounds as mold release agents in thermoplastics is disclosed. Molding compositions having good release properties, preferably compositions containing polycarbonate resins are thus disclosed.
摘要:
A thermoplastic molding composition is disclosed. The composition that contains a polymer selected from the group consisting of a polycarbonate, a transparent polycarbonate-polyester-blend, a copolyestercarbonate and a transparent polyester and a compound of formula (I) and one or more compounds of formula (II) wherein a is 1 to 17, b is 0 to 16, c is 6 to 14, d is 3 to 7, e is 6 to 14, f is 3 to 7, g is 5 to 40 and a+b is 9 to 25 and n is 1 to 10, was found to be especially suitable for co-extrusion applications.
摘要:
The invention relates to a device for magnetic separation of pharmaceutical preparations, their starting or intermediate products that contain a separation space, in which a magnetic gradient field prevails and which has an inlet and an outlet, whereby the device is embodied in the form of an attachment filter for injection instruments or infusion instruments.