摘要:
The non-aqueous electrolyte secondary battery 10 provided by the present invention comprises a positive electrode 30, a negative electrode 50 and a non-aqueous electrolyte. The negative electrode 50 includes a negative electrode current collector 52 and a negative electrode active material layer 54 formed on the current collector 52, the negative electrode active material layer 54 containing a negative electrode active material 55 capable of storing and releasing charge carriers and having shape anisotropy so that the charge carriers are stored and released along a predefined direction. The negative electrode active material layer 54 includes, at a bottom thereof contacting the current collector 52, a minute conductive material 57 with granular shape and/or minute conductive material 57 with fibrous shape having an average particle diameter that is smaller than that of the negative electrode active material 55, and includes, at the bottom thereof; a part of the negative electrode active material 55. At least 50% by number of the total amount of the negative electrode active material 55 is oriented so that the direction of storage and release of the charge carriers is at an angle of 45° or more and 90° or less relative to the surface of the current collector 52.
摘要:
The present invention provides a non-aqueous electrode secondary battery supplied with a non-aqueous electrolyte comprising an overcharge additive. The positive electrode material layer constituting the positive electrode in the non-aqueous electrolyte secondary battery is characterized by having a differential pore volume peak A as well as a peak B located on the smaller pore diameter side than the peak A in a pore diameter range of 0.05 μm to 2 μm in a pore size distribution curve measured by a mercury porosimeter, wherein the pore size distribution curve has a minimum C corresponding to a minimum differential pore volume between the peak A and the peak B, such that a ratio (XC/XL) of the minimum C's differential pore volume XC to a differential pore volume XL, which is the larger between the peak A's differential pore volume XA and the peak B's differential pore volume XB is 0.6 or larger.
摘要:
A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a porous insulating layer, and nonaqueous electrolyte. The porous insulating layer is interposed between the positive electrode and the negative electrode. The nonaqueous electrolyte is contained at least in the porous insulating layer. The mixture layer of the positive electrode and the porous insulating layer each include a structure retainer.
摘要:
A battery control system includes a lithium ion secondary battery and a control device and further includes a voltage storage unit, a resistance storage unit, a current storage unit, a difference obtaining unit for obtaining a difference resistance ΔR(Tja) between a normal internal resistance Rj(Tja) at a predetermined battery temperature Tja in a normal temperature range ATj and an initial internal resistance R0(Tja) at the predetermined battery temperature, and a maximum voltage calculation unit for giving a maximum inter-terminal voltage Vm(T), when at least a battery temperature T is within a low-temperature range ATl, as a value obtained by adding a product of the difference resistance ΔR(Tja) and the allowable charging current Im(T) to the initial maximum inter-terminal voltage Vm0(T).
摘要:
The non-aqueous electrolyte secondary battery 10 provided by the present invention comprises a positive electrode 30, a negative electrode 50 and a non-aqueous electrolyte. The negative electrode 50 includes a negative electrode current collector 52 and a negative electrode active material layer 54 formed on the current collector 52, the negative electrode active material layer 54 containing a negative electrode active material 55 capable of storing and releasing charge carriers and having shape anisotropy so that the charge carriers are stored and released along a predefined direction. The negative electrode active material layer 54 includes, at a bottom thereof contacting the current collector 52, a minute conductive material 57 with granular shape and/or minute conductive material 57 with fibrous shape having an average particle diameter that is smaller than that of the negative electrode active material 55, and includes, at the bottom thereof; a part of the negative electrode active material 55. At least 50% by number of the total amount of the negative electrode active material 55 is oriented so that the direction of storage and release of the charge carriers is at an angle of 45° or more and 90° or less relative to the surface of the current collector 52.
摘要:
There is provided a lithium ion secondary cell excellent in charging and discharging cycle characteristics. A lithium ion secondary cell includes: an electrode body including a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, and a separator; and a non-aqueous electrolyte containing a lithium salt as a supporting salt in an organic solvent, the electrode body and the non-aqueous electrolyte being accommodated in a case. The positive electrode active material is a lithium transition metal oxide having a layered structure. The electrolyte contains a compound represented by a chemical formula (I) in an amount of β mol relative to the total content α mol of moisture to be mixed in the cell. β satisfies −1.3≦log(β/α)≦1.
摘要:
A nonaqueous electrolyte secondary battery includes a positive electrode (5), a negative electrode (6) and a porous insulation layer (7). The positive electrode (5) includes a positive electrode current collector (51) and a positive electrode mixture layer (52), and the negative electrode (6) includes a negative electrode current collector (61) and a negative electrode active material layer (62). After charging the nonaqueous electrolyte secondary battery, when a surface of the positive electrode mixture layer (52) and a surface of the negative electrode active material layer (62) are brought in contact with each other, terminals are provided, respectively, on the positive electrode current collector (51) and the negative electrode current collector (62) and a resistance value between the terminals is measured, the resistance value is 1.6 Ω·cm2 or more.
摘要:
A battery control system includes a lithium ion secondary battery and a control device and further includes a voltage storage unit, a resistance storage unit, a current storage unit, a difference obtaining unit for obtaining a difference resistance ΔR(Tja) between a normal internal resistance Rj(Tja) at a predetermined battery temperature Tja in a normal temperature range ATj and an initial internal resistance R0(Tja) at the predetermined battery temperature, and a maximum voltage calculation unit for giving a maximum inter-terminal voltage Vm(T), when at least a battery temperature T is within a low-temperature range ATl, as a value obtained by adding a product of the difference resistance ΔR(Tja) and the allowable charging current Im(T) to the initial maximum inter-terminal voltage Vm0(T).
摘要:
A process of manufacturing segments, an anisotropic direction of which is continuously changed in a plane vertically by a uniform magnetic field maintained in a constant direction and a process of arranging a plurality of segments on a circumference, extruding the segments in a ring shape by rheology based on the viscous deformation of the segments, from one thrust-direction end surface of the segments, and subsequently compressing the segments from both thrust-direction end surfaces of the segments are necessarily included. A ring magnet, anisotropy of which is controlled in a continuous direction, is provided, and a source for generating a static magnetic field has energy density (BH) max≧160 to 180 kJ/m3.
摘要:
A secondary battery includes an electrode group 4 in which a positive electrode plate 1 and a negative electrode plate 2 are wounded with a porous insulation layer interposed therebetween, wherein an electrode plate end portion 1a protrudes from the porous insulation layer and abuts the current collector plate 5, and the current collector plate 5 is placed in relation to the electrode group 4 so as to entirely cover the end portion 1a of the electrode group 4. Parts of the electrode plate end portion 1a abutting the current collector plate 5 are welded to the current collector plate 5 at discrete joint portions 6 on the current collector plate 5, and the joint portions 6 are discretely provided on a surface of the current collector plate 5 so that a current flowing from the electrode plate 1 to the current collector plate 5 is uniformly distributed.