摘要:
Disclosed is an olefin thermoplastic elastomer composition obtained by dynamically heat treating, in the presence of an organic peroxide, a blend comprising 10 to 60 parts by weight of a crystalline polyolefin resin (A) and 40 to 90 parts by weight of an unsaturated olefin copolymer (B) of at least one .alpha.-olefin of 2 to 20 carbon atoms, a conjugated diene monomer represented by the following formula (I), and optionally, an aromatic vinyl compound, the total amount of said components (A) and (B) being 100 parts by weight; ##STR1## wherein R.sup.1 and R.sup.2 are each independently a hydrogen atom, an alkyl group of 1 to 8 carbon atoms or an aryl group, and at least one of R.sup.1 and R.sup.2 is a hydrogen atom. The composition has excellent moldability and can provide a molded product having excellent elastomeric properties, tensile strength properties and appearance.
摘要:
Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
摘要:
Disclosed is a foamable olefin thermoplastic elastomer composition comprising (A) a partially crosslinked thermoplastic elastomer composition, (B) long-chain branch-containing polypropylene and (C) a foaming agent. The partially crosslinked thermoplastic elastomer composition (A) is obtained by dynamically heat-treating a mixture in the presence of organic peroxide, said mixture comprising specific proportions of a peroxide-crosslinking type olefin copolymer rubber (a), which is an ethylene/.alpha.-olefin copolymer rubber composed of ethylene, an .alpha.-olefin of 3 to 20 carbon atoms and optionally a nonconjugated diene, and a peroxide-decomposition type olefin plastic (b), which is an .alpha.-olefin (co)polymer containing a specific amount of an .alpha.-olefin of 3 to 20 carbon atoms and having a specific MFR. Also disclosed is a foamed product obtained by heating the foamable olefin thermoplastic elastomer composition. From the foamable olefin thermoplastic elastomer composition, a foamed product having an expansion ratio of at least 2 times, being free from surface roughening caused by defoaming, being soft to the touch and showing excellent heat resistance and weathering resistance can be produced with high productivity through simplified steps.
摘要:
A crosslinked foamed body obtained by subjecting a rubber compounded product comprising (A) a chlorinated ethylene/.alpha.-olefin copolymer rubber, (B) a triazinethiol as a vulcanization agent, (C) an alkyl ammonium halide as a vulcanization promotor, and (D) a hydrazide-type blowing agent to two step vulcanization and foaming at a vulcanization temperature of 120.degree. to 140.degree. C. for a vulcanization time of 5 to 10 minutes in a first step and at a vulcanization temperature of 125.degree. to 160.degree. C. for a vulcanization time of 5 to 20 minutes in a second step, the second step vulcanization temperature being higher than the first step by at least 5.degree. C., so that the expansion factor will be 3 to 10 times. This crosslinked foamed body can be colored brilliantly, exhibit excellent weatherability, suppleness and shape retention as well as good outer appearance. This product is well usable, for example, as wet suits.
摘要:
A spiral wound gasket having an annular body serving as a centering member which is integrally disposed at the inner periphery side of a gasket body formed by winding, in the form of a spiral. The gasket body comprises a metal hoop material and a filler material overlapping each other. When this gasket is disposed at fit-joint-type pipe connection portions of the exhaust pipe system in a motor vehicle, the annular body serves as a centering member to prevent the gasket body from protruding into the fit joint. This prevents the gasket body from deterioration and damage, thus assuring a high sealing property for a long period of time. Further, merely by inserting and fitting the gasket, the gasket may be automatically aligned and positioned with respect to the fit joint. Further, the inner peripheral surface of the gasket body and the annular body form an annular closed space, thus making the entire gasket into a lightweight design.
摘要:
A propylene elastomer (PBER) comprising (a) 50 to 85 mol % of units derived from propylene, (b) 5 to 25 mol % of units derived from 1-butene and (c) 10 to 25 mol % of units derived from ethylene, and having a molar ratio of propylene content to ethylene content of from 89/11 to 70/30, and a modulus in tension (YM), as measured in accordance with JIS 6301, of not more than 40 Mpa.
摘要:
Disclosed are a conjugated polyene copolymer comprising a random copolymer having structural units derived from α-olefin (A1) of 2 to 20 carbon atoms and structural units derived from nonconjugated polyene (A2), said nonconjugated polyene copolymer having a glass transition temperature (Tg) of −25 to 20 □ and Mooney viscosity of [ML(1+4)100□] of 5 to 190; a rubber composition comprising the nonconjugated polyene copolymer and a diene-based rubber (B); a modifier for tires comprising the copolymer; a rubber material for tires comprising the rubber composition; a tire tread obtained from the rubber material for tires; and a tire having the tire tread.
摘要:
A mover device and an ion implanter apparatus having a processing base that reciprocates at a high speed without undesirable noise and vibration are provided. The mover device includes: a fixed base; a movable base that is linearly movable with respect to the fixed base; a processing base that is linearly movable with respect to the movable base; a main linear motor that generates a moving force to move the processing base with respect to the movable base, thereby moving the processing base with respect to the fixed base; and a velocity control unit that controls the moving velocity of the processing base with respect to the fixed base. In this mover device, the movable base is moved by virtue of a reaction force caused by the moving force to move the processing base.