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公开(公告)号:US20210269564A1
公开(公告)日:2021-09-02
申请号:US16967587
申请日:2019-01-25
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: SIMONA GUIDOTTI , DARIO LIGUORI , GIAMPIERO MORINI , GIANNI VITALE
IPC: C08F110/06 , C08F4/02 , C08F4/20 , C08F4/646 , C08F4/657
Abstract: A solid catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, a halogen and an electron donor.
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公开(公告)号:US20200231723A1
公开(公告)日:2020-07-23
申请号:US16632175
申请日:2018-07-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PAOLA MASSARI , CAROLINE CATHELIN , CLAUDIO CAVALIERI , MARCO CIARAFONI , ROBERTO PANTALEONI , GIAMPIERO MORINI , GIANNI VITALE , FABRIZIO PIEMONTESI , GIANNI COLLINA , BENEDETTA GADDI
IPC: C08F210/06 , C08J5/18
Abstract: A propylene 1-hexene copolymer containing from 5.7 to 7.7% by weight of 1-hexene derived units, based upon the total weight of the propylene 1-hexene copolymer, having:a) a solubility in xylene at 25° C. ranging from 7.0 wt % to 15.0 wt %, based upon the total weight of the propylene 1-hexene copolymer; b) a melting temperature, measured by DSC ranging from 143.0° C. to 148.0° C.; c) a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg) from 3.5 to 8.0 g/10 min.; and d) a content of 1-hexene derived units in the fraction soluble in xylene at 25° C. ranging from 13.5 wt % to 18.5 wt %, based upon the total weight of the soluble fraction.
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公开(公告)号:US20180258199A1
公开(公告)日:2018-09-13
申请号:US15759419
申请日:2016-08-31
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: GIANNI VITALE , DARIO LIGUORI , GIAMPIERO MORINI
IPC: C08F10/06
CPC classification number: C08F10/06 , C08F110/06 , C08F4/6574 , C08F4/6465 , C08F4/651 , C08F2500/15 , C08F2500/12
Abstract: A process for preparing a solid catalyst component for the homopolymerization or copolymerization of CH2═CHR olefins, wherein R is hydrogen or hydrocarbyl radical with 1-12 carbon atoms, including a step (a), at a temperature ranging from 0 to 150° C., of reacting a Mg based compound of formula (MgClmX2-m).nLB, wherein m ranges from 0 to 2, n ranges from 0 to 6, X is, independently R1, OR1, —OCOR1 or O—C(O)—OR1 group, wherein R1 is a C1-C20 hydrocarbon group and LB is a Lewis base with a liquid medium made from or containing a Ti compound, having a Ti—Cl bond, in an amount such that the Ti/Mg molar ratio is higher than 3 and a Bi compound dissolved or dispersed in the liquid medium, wherein the solid catalyst compound is made from or contains the Ti compound, the Bi compound and optionally an electron donor on a Mg chloride based support.
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公开(公告)号:US20180223084A1
公开(公告)日:2018-08-09
申请号:US15750799
申请日:2016-07-19
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PAOLA MASSARI , CAROLINE CATHELIN , CLAUDIO CAVALIERI , MARCO CIARAFONI , ANDREA FELISATI , ANGELO FERRARO , GIAMPIERO MORINI , FABRIZIO PIEMONTESI , GIANNI VITALE
CPC classification number: C08L23/142 , B32B27/08 , B32B27/32 , B32B2250/242 , B32B2250/40 , B32B2307/412 , B32B2307/414 , B32B2307/548 , B32B2307/732 , B32B2307/75 , C08L23/14 , C08L2201/10 , C08L2203/162 , C08L2205/025 , C08L2308/00 , C08F210/06 , C08F2/001 , C08F4/6492 , C08F4/6574
Abstract: A multilayer film made from or containing a skin layer made from or containing a polyolefin composition made from or containing:A) from 19 wt % to 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and B) from 50 wt % to 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and 1-butene derived units content of between 4.8 wt % to 12.4 wt %; the sum of the amount of component A) and B) being 100; the composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; the creep and recovery curve measured on the polymer fuse at 200° C. shows a maximum value between 600 and 1200 seconds, lower than 53×10−5 1/Pa.
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公开(公告)号:US20170327603A1
公开(公告)日:2017-11-16
申请号:US15533856
申请日:2015-12-01
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PIETRO BAITA , TIZIANO DALL'OCCO , MARIA DI DIEGO , DARIO LIGUORI , LORELLA MARTURANO , ANDREAS MAUS , GABRIELE MEI , GERHARDUS MEIER , GIAMPIERO MORINI , ROBERTA PICA , ULF SCHUELLER
IPC: C08F2/34 , C08F110/02 , C08F4/649
CPC classification number: C08F2/34 , C08F4/6493 , C08F4/6494 , C08F110/02 , C08F2410/02 , C08F2500/12 , C08F2500/18 , C08F4/6543 , C08F210/02
Abstract: The present disclosure provides a gas-phase polymerization process for preparing polyethylene, wherein halogenated alcohols in combination with a Ti based catalyst component and aluminum alkyls as co-catalyst suppress ethane formation or increase polymerization activity.
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公开(公告)号:US20170066855A1
公开(公告)日:2017-03-09
申请号:US15309138
申请日:2015-04-28
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PAOLA MASSARI , FABRIZIO PIEMONTESI , GIANNI VITALE , CAROLINE CATHELIN , GIAMPIERO MORINI , MARCO CIARAFONI , CLAUDIO CAVALIERI , TIZIANA CAPUTO
IPC: C08F210/06 , C08J5/18
CPC classification number: C08F210/06 , C08F210/02 , C08F2800/20 , C08J5/18 , C08J2323/14 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/26 , C08F10/00 , C08F4/6492 , C08F4/6574
Abstract: The present disclosure relates to a propylene ethylene copolymer comprising: an ethylene content of between 1.8 and 10.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: XS
Abstract translation: 一种丙烯乙烯共聚物,其特征在于以下特征:乙烯含量在1.8至10.0重量%之间; 分子量分布(MWD),以Mw / Mn表示,大于4.0; 二甲苯可溶成分(XS)和乙烯含量(C2)的含量满足下列关系:XS <(C2x2.1)-2.4其中:XS =在25℃下可溶于二甲苯的馏分的重量% C2 =通过NMR确定的共聚物中乙烯单元的重量%。
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公开(公告)号:US20160208027A1
公开(公告)日:2016-07-21
申请号:US14917549
申请日:2014-09-08
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: ALESSANDRO MIGNOGNA , REYNALD CHEVALIER , GIAMPIERO MORINI , MARTIN SCHNEIDER
IPC: C08F110/06
CPC classification number: C08F110/06 , C07C271/12 , C08F4/651 , C08F2500/12
Abstract: The present technology relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the general formula (I): where R1 is selected from C1-C15 hydrocarbon groups, the R2 groups are equal to or different from each other, are hydrogen, or the R1 groups can be fused together to form one or more cycles and A is a bivalent bridging group. The catalyst components of the present disclosure exhibit high activity and stereospecificity in the polymerization of olefins.
Abstract translation: 本技术涉及用于烯烃聚合的固体催化剂组分,包括Mg,Ti和通式(I)的电子给体:其中R1选自C1-C15烃基,R2基团等于或不同于 彼此是氢,或者R1基团可以稠合在一起形成一个或多个循环,A是二价桥连基团。 本公开的催化剂组分在烯烃聚合中表现出高的活性和立体定向性。
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公开(公告)号:US20230028786A1
公开(公告)日:2023-01-26
申请号:US17781952
申请日:2020-11-30
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: SIMONA GUIDOTTI , DARIO LIGUORI , GIAMPIERO MORINI
IPC: C08F110/02 , C08F210/16
Abstract: A solid catalyst component for the homopolymerization or copolymerization of olefins, made from or containing Ti, Mg, halogen, and at least one non-aromatic diazo compounds.
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公开(公告)号:US20220332856A1
公开(公告)日:2022-10-20
申请号:US17620968
申请日:2020-06-24
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: ALESSANDRO MIGNOGNA , DARIO LIGUORI , GIAMPIERO MORINI
Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti and an electron donor of formula (I) where the R1 and R5 groups, equal to or different from each other, are selected from C1-C15 hydrocarbon groups, R2 group is selected from C2-C10 hydrocarbon groups, R3 to R4 groups, independently, are selected from hydrogen or C1-C20 hydrocarbon groups, optionally fused together to form one or more cycles, with the proviso that at least one of R3 to R4 groups is a C1-C20 alkyl group.
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公开(公告)号:US20220033539A1
公开(公告)日:2022-02-03
申请号:US17312264
申请日:2019-12-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: ALESSANDRO MIGNOGA , DARIO LIGUORI , GIAMPIERO MORINI , GIANNI VITALE
Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from diphenol derivatives.
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