公开(公告)号：US20240417554A1

公开(公告)日：2024-12-19

申请号：US18698632

申请日：2021-10-06

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Eleonora Ciaccia ,  Marco Ciarafoni ,  Caroline Cathelin ,  Alberta De Capua ,  Giansiro Prini ,  Daniele Po ,  Tiziana Caputo ,  Roberto Pantaleoni ,  Alessia Di Capua

IPC: C08L23/12

Abstract: A polypropylene composition made from or containing: A) from 71 wt % to 91 wt % of a propylene homopolymer, B) from 5 wt % to 15 wt % of a copolymer of propylene and ethylene containing from 18 wt % to 32.0 wt % of ethylene derived units; and C) from 4 wt % to 15 wt % of a copolymer of propylene and ethylene containing from 75 wt % to 90.0 wt % of ethylene derived units.

公开(公告)号：US11149101B2

公开(公告)日：2021-10-19

申请号：US16632175

申请日：2018-07-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Caroline Cathelin ,  Claudio Cavalieri ,  Marco Ciarafoni ,  Roberto Pantaleoni ,  Giampiero Morini ,  Gianni Vitale ,  Fabrizio Piemontesi ,  Gianni Collina ,  Benedetta Gaddi

IPC: C08F210/06 ,  C08F210/14 ,  C08J5/18

Abstract: A propylene 1-hexene copolymer containing from 5.7 to 7.7% by weight of 1-hexene derived units, based upon the total weight of the propylene 1-hexene copolymer, having:
a) a solubility in xylene at 25° C. ranging from 7.0 wt % to 15.0 wt %, based upon the total weight of the propylene 1-hexene copolymer;
b) a melting temperature, measured by DSC ranging from 143.0° C. to 148.0° C.;
c) a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg) from 3.5 to 8.0 g/10 min.; and
d) a content of 1-hexene derived units in the fraction soluble in xylene at 25° C. ranging from 13.5 wt % to 18.5 wt %, based upon the total weight of the soluble fraction.

公开(公告)号：US10894849B2

公开(公告)日：2021-01-19

申请号：US15750123

申请日：2016-07-19

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Fabrizio Piemontesi ,  Gianni Vitale ,  Caroline Cathelin ,  Giampiero Morini ,  Claudio Cavalieri ,  Marco Ciarafoni ,  Roberto Pantaleoni

IPC: C08J9/00 ,  C08F210/06 ,  C08J5/18 ,  C08L23/14

Abstract: A polyolefin composition made from or containing: A) from about 19 wt % to about 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt % B) from about 50 wt % to about 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt % and 1-butene derived units content between about 4.8 wt % and about 12.4 wt %; the sum of the amount of component A) and B) being 100; the polyolefin composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than about 4.0; the creep and recovery curve measured on the polymer fuse at 200° C. shows a maximum value between 600 and 1200 seconds, lower than about 53×10−4 1/Pa.

公开(公告)号：US20160032032A1

公开(公告)日：2016-02-04

申请号：US14774591

申请日：2014-03-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Monica Galvan ,  Andreas Neumann ,  Tiziana Caputo ,  Stefano Squarzoni ,  Antonio Mazzucco ,  Ofelia Fusco ,  Benedetta Gaddi ,  Gianni Collina ,  Gisella Biondini ,  Claudio Cavalieri ,  Roberto Pantaleoni

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F110/06 ,  C08F4/6492 ,  C08F210/16 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: Propylene terpolymers are prepared by polymerizing propylene, ethylene and an alpha-olefin selected from the group of C4-C8 alpha-olefins in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.

Abstract translation: 丙烯三元共聚物通过在催化剂体系存在下聚合丙烯，乙烯和选自C 4 -C 8α-烯烃的α-烯烃来制备，所述催化剂体系通过使包含卤化镁的固体催化剂组分，至少具有 Ti-卤素键和至少两种电子给体化合物，其中一种以相对于供体总量为40-90％摩尔量存在，选自琥珀酸盐，另一种选自1,3-二醚， 铝烃基化合物和任选的外电子给体化合物。

公开(公告)号：US20140235802A1

公开(公告)日：2014-08-21

申请号：US14346648

申请日：2012-09-17

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Roberto Pantaleoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Andreas Neumann ,  Antonio Mazzucco ,  Gianni Collina ,  Gabriella Sartori

IPC: C08F10/06

CPC classification number: C08F10/06 ,  B01J31/0204 ,  B01J31/0209 ,  C08J5/18 ,  C08J2323/14 ,  C08F4/651 ,  C08F4/6543 ,  C08F110/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15

Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by contacting: (a) a solid catalyst component comprising Mg, Ti and at least a first internal electron donor compound (HD) selected among the succinates and a second internal electron donor compound (2ID) selected among the 1,3-diethers, wherein the molar ratio of first internal donor over second internal donor 1ID:2ID is comprised between 4:6 and 9:1, with (b) an organo-aluminium compound, and optionally with (c) an external electron donor compound, said process being carried out at a temperature equal or higher than 78° C. and by employing a molar ratio of organo-aluminum compound over solid catalyst component (b):(a) of lower than 5.

Abstract translation: 一种制备高纯度丙烯聚合物的方法，该催化剂包括通过使（a）包含Mg，Ti和至少第一内电子给体化合物（HD）的固体催化剂组分与 所述琥珀酸盐和选自所述1,3-二醚中的第二内部电子给体化合物（2ID），其中所述第一内给体相对于所述第二内供体1ID：2ID的摩尔比为4：6至9：1，与（b ）有机铝化合物，任选地与（c）外电子给体化合物反应，所述方法在等于或高于78℃的温度下进行，并且通过使用有机铝化合物与固体催化剂组分的摩尔比 （b）:( a）低于5。