公开(公告)号：US11905400B2

公开(公告)日：2024-02-20

申请号：US17282294

申请日：2019-09-11

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Monica Galvan ,  Claudio Cavalieri ,  Thomas Boehm ,  Roberto Pantaleoni

IPC: C08L23/14 ,  F16L9/12

CPC classification number: C08L23/14 ,  F16L9/12 ,  C08L2203/18 ,  C08L2205/025

Abstract: A polypropylene composition made from or containing:



A) from 88.0 wt. % to 98.0 wt. %, of a random copolymer of propylene containing from 0.8 wt. % to 4.8 wt. % of 1-hexene derived units; the random copolymer of propylene having:

a Melt Flow Rate: measured according to ISO 1133 (230° C., 5 Kg) ranging from 0.5 to 4.4 g/10 min; and


B) from 2.0 wt. % to 12.0 wt. % of a terpolymer of propylene ethylene and 1-hexene having a content of ethylene derived units ranging from 35 wt. % to 60 wt.; and a content of 1-hexene derived units ranging from 1 wt. % to 6 wt. %;
wherein the polypropylene composition has a Melt Flow Rate: measured according to ISO 1133 (230° C., 5 Kg) ranging from 0.5 to 5.0 g/10 min.

公开(公告)号：US11098143B2

公开(公告)日：2021-08-24

申请号：US16649044

申请日：2018-09-13

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Antonio Mazzucco ,  Enrico Balestra ,  Roberto Pantaleoni ,  Davide Tartari ,  Riccardo Rinaldi

IPC: B01J8/26 ,  C08F210/06 ,  B01J8/22

Abstract: A process for the polymerization of olefins in gas phase carried out in a reactor having two interconnected polymerization zones, a first zone (riser) and a second zone (downcomer), wherein growing polymer particles: a) flow through the riser under fast fluidization conditions established by feeding a mixture of gas and liquid; b) leave the riser and enter the downcomer, through which the growing polymer particles flow downward in a densified form; and c) leave the downcomer and are reintroduced into the riser, thereby establishing a circulation of polymer between the riser and the downcomer; the reactor is operated at a temperature between 0° C. and 5° C. above the dew point of the riser gas at the operating pressure, and in the riser, besides the growing polymer particles and gas flow, an amount of liquid is present.

公开(公告)号：US10759933B2

公开(公告)日：2020-09-01

申请号：US16341584

申请日：2017-10-05

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Andrea Felisati ,  Marco Izzi ,  Claudio Cavalieri ,  Marco Ciarafoni ,  Silvia Guerra ,  Roberto Pantaleoni ,  Federica Malizia

IPC: C08L23/12 ,  C08K5/00 ,  C08K5/098 ,  C08K5/1575 ,  C08K5/56 ,  C08L23/14

Abstract: A nucleated propylene polymer composition made from or containing: A) a propylene homopolymer; B) a copolymer of propylene with ethylene derived units; the nucleated composition having a fraction soluble in xylene at 25° C. between 9.0 and 21.0 wt %, an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 1.0 and 1.9 dl/g, a total melt flow rate between 1.5 and 5 g/10 min and the value of the relation (I): 22.5+0.2*MFR−1.2*Xs+0.2*IV  (I) is higher than 5.9; wherein MFR is the melt flow rate of the nucleated composition; IV is the intrinsic viscosity of the fraction soluble in xylene at 25° C.; and Xs is the fraction soluble in xylene at 25° C., the amount of A+B is equal to 100 wt %, and the nucleating agent is selected from the group consisting of aromatic or aliphatic carboxylic acids, aromatic metal phosphates, sorbitol derivatives and talc.

公开(公告)号：US10385199B2

公开(公告)日：2019-08-20

申请号：US15738782

申请日：2016-06-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Claudio Cavalieri ,  Michele Grazzi ,  Roberto Pantaleoni

IPC: C08L23/16 ,  C08L23/20 ,  C08F210/16

Abstract: Polyolefin compositions made from or containing:(A) about 5 to about 35% by weight of a propylene-based polymer containing about 90% by weight or more of propylene units and containing about 10% by weight or less of a fraction soluble in xylene at 25° C. (XSA);(B) about 25 to about 50% by weight, of a copolymer of ethylene and a C3-C8 alpha-olefin containing from about 0.1% to about 15% by weight of alpha-olefin units and containing about 75% by weight or less of a fraction soluble in xylene at 25° C. (XSB); and(C) about 30 to about 60% by weight, of a copolymer of ethylene and propylene containing from about 45% to about 75% by weight of ethylene units and containing from about 55% to about 95% by weight, of a fraction soluble in xylene at 25° C. (XSC).

公开(公告)号：US20160272802A1

公开(公告)日：2016-09-22

申请号：US15079313

申请日：2016-03-24

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Marco Ciarafoni ,  Paola Massari ,  Gisella Biondini ,  Roberto Pantaleoni ,  Sander Willems

IPC: C08L23/12

CPC classification number: C08L23/12 ,  C08L23/10 ,  C08L23/14 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2207/04 ,  C08L2310/00 ,  C08L2666/06

Abstract: A masterbatch composition comprising: 70-90% wt of a component (A) being a propylene homopolymer or copolymer of propylene with ethylene or C4-C10 alpha olefins, having a MFRA according to ISO 1133 (230° C./2.16 Kg) ranging from 15 to 70 g/10 min; and 10-30% wt of a component B) being a propylene-ethylene copolymer comprising 25-45% wt of ethylene derived units and having a value of the intrinsic viscosity [η] of the fraction soluble in xylene at room temperature ranging from 5 to 9 dl/g, said masterbatch composition having a total MFR higher than 4 g/10 min, and a value of the flexural modulus measured according to ISO method 178 ranging from 950 to 2000 MPa.

Abstract translation: 一种母料组合物，其包含：70-90重量％的组分（A）为丙烯均聚物或丙烯与乙烯或C 4 -C 10α-烯烃的共聚物，其具有根据ISO 1133（230℃/ 2.16Kg）的MFRA范围 15〜70g / 10min; 和10-30重量％的组分B）作为丙烯 - 乙烯共聚物，其包含25-45重量％的乙烯衍生单元，并且在室温下可溶于二甲苯的馏分的特性粘度[η]值为5 至9dl / g，所述母料组合物的总MFR高于4g / 10min，根据ISO方法178测量的弯曲模量值为950至2000MPa。

公开(公告)号：US10316122B2

公开(公告)日：2019-06-11

申请号：US15768875

申请日：2016-10-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Caroline Cathelin ,  Giampiero Morini ,  Fabrizio Piemontesi ,  Gianni Vitale ,  Marco Ciarafoni ,  Claudio Cavalieri ,  Roberto Pantaleoni ,  Michele Grazzi

IPC: C08F210/06 ,  C08L23/12 ,  C08L23/16 ,  C08F10/06 ,  C08F2/00 ,  C08F4/657 ,  C08F4/659

Abstract: A polypropylene composition made from or containing: A) from 50 wt % to 90 wt %; of a propylene homopolymer; B) from 10 wt % to 50 wt %; of a copolymer of propylene having from 30.0 wt % to 70.0 wt %, of ethylene derived units, based upon the total weight of the copolymer; the sum of the amount of component A) and B) being 100; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from 0.5 to 100 g/10 min; iii) a xylene soluble fraction ranging from 20 wt % to 50 wt %, based upon the total weight of the polypropylene composition; wherein the polypropylene composition being obtained by a polymerization process wherein the catalyst system contains bismuth.

公开(公告)号：US09683062B2

公开(公告)日：2017-06-20

申请号：US15031913

申请日：2014-10-21

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Benedetta Gaddi ,  Marco Bocchino ,  Gianni Collina ,  Ofelia Fusco ,  Simona Guidotti ,  Antonio Mazzucco ,  Roberto Pantaleoni ,  Fabrizio Piemontesi

IPC: C08J9/00 ,  C08F210/06 ,  C08F10/06 ,  C08F210/02

CPC classification number: C08F210/02 ,  C08F10/06 ,  C08J9/0052 ,  C08J9/0066 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6545

Abstract: The present disclosure relates to a process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds, one of which is present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates, and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55° C.; optionally, ii) pre-polymerizing with one or more olefins of formula CH2═CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins for producing the porous propylene (co)polymer.

公开(公告)号：US20230383107A1

公开(公告)日：2023-11-30

申请号：US18032531

申请日：2021-10-06

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Eleonora Ciaccia ,  Marco Ciarafoni ,  Caroline Cathelin ,  Alberta De Capua ,  Giansiro Prini ,  Daniele Po ,  Tiziana Caputo ,  Roberto Pantaleoni ,  Alessia Di Capua

IPC: C08L23/12

CPC classification number: C08L23/12 ,  C08L2205/025

Abstract: A polypropylene composition made from or containing:



A) from 76 wt % to 95 wt % of a propylene homopolymer having:

fraction soluble in xylene at 25° C. between 2.0 wt % and 4.5 wt %; and
melt flow rate ranging from 60.0 to 110.0 g/10 min; and


B) from 5 wt % to 24 wt % of a copolymer of propylene and ethylene containing from 75 wt % to 90.0 wt % of ethylene derived units;
wherein the polypropylene composition has
content of ethylene derived units in the fraction soluble in xylene at 25° C. lower than the content of ethylene derived units of component B) and ranging from 51.0 wt % to 74.0 wt %; and
at least two melting points, wherein the higher melting points ranges from 156.0° C. to 166.0° C. and the lower melting point ranges from 90.0° C. to 125.0° C.;
wherein the sum of the amounts of component A) and B) being 100 wt %.

公开(公告)号：US20230312897A1

公开(公告)日：2023-10-05

申请号：US18010421

申请日：2021-06-01

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Gianpiero Ferraro ,  Claudio Cavalieri ,  Caroline Cathelin ,  Eleonora Ciaccia ,  Marco Ciarafoni ,  Ambra Montaletti ,  Alberta De Capua ,  Roberto Pantaleoni ,  Tiziana Caputo ,  Giansiro Prini ,  Alberto Nardin

IPC: C08L23/14 ,  C08L23/16

CPC classification number: C08L23/142 ,  C08L23/16 ,  C08L2205/025 ,  C08L2203/14 ,  C08L2314/02

Abstract: A polypropylene composition made from or containing:



from 70 wt % to 90 wt % of a propylene 1-hexene copolymer containing from 1.0 wt % to 5.0 wt % of 1-hexene derived units and a polydispersity index (PI) between 9.2 and 21.3; and
from 10 wt % to 30 wt % of a copolymer of propylene and ethylene containing from 45.0 wt % to 65.0 wt % of ethylene derived units;
the sum A)+B) being 100.

公开(公告)号：US11124636B2

公开(公告)日：2021-09-21

申请号：US16610332

申请日：2018-04-12

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Claudio Cavalieri ,  Marco Ciarafoni ,  Roberto Pantaleoni

IPC: C08L23/14 ,  C08L23/16

Abstract: A propylene polymer composition made from or containing: a) from 35 wt % to 65 wt %, based upon the total weight of the propylene polymer composition, of a propylene 1-hexene copolymer containing from 10.2 to 13.0% by weight, based upon the weight of the propylene 1-hexene copolymer, of 1-hexene derived units and having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg, (at 230° C., with a load of 2.16 kg)) from 3.5 to 12.0 g/10 min; b) from 35 wt % to 65 wt %, based upon the total weight of the propylene polymer composition, of a propylene ethylene copolymer containing from 1.5 wt % to 6.5 wt %, based upon the weight of the propylene ethylene copolymer, of ethylene derived units and having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg, (at 230° C., with a load of 2.16 kg)) from 3.5 to 12.0 g/10 min.