公开(公告)号：US11834534B2

公开(公告)日：2023-12-05

申请号：US17268653

申请日：2019-08-12

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Gianpiero Ferraro ,  Gianni Vitale ,  Fabrizio Piemontesi ,  Benedetta Gaddi ,  Gianni Collina ,  Giampiero Morini ,  Caroline Cathelin ,  Marco Ciarafoni ,  Claudio Cavalieri

IPC: C08F210/16 ,  C08F210/06

CPC classification number: C08F210/06 ,  C08F210/16

Abstract: A propylene ethylene copolymer having the following features:



an ethylene content of between 1.0 and 4.0% by weight;
a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 4.0;
a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship:

(C2×1.1)+1.25

公开(公告)号：US10435490B2

公开(公告)日：2019-10-08

申请号：US15750391

申请日：2016-07-14

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Giuseppina Maria Algozzini ,  Diego Brita ,  Massimo Cenci ,  Gianni Collina ,  Tiziano Dall'occo ,  Maria Di Diego ,  Benedetta Gaddi ,  Ofelia Fusco ,  Giampiero Morini ,  Lorella Pedriali

IPC: C08F110/02 ,  C08F110/06 ,  C08F10/06 ,  C08F2/34 ,  C08F4/649 ,  C08F4/651

Abstract: A Prepolymerized catalyst component for the polymerization of olefins comprising a solid catalyst component which comprises Mg, Ti, and chlorine atoms and an electron donor (ID) said prepolymerized catalyst component being characterized by the fact that: the electron donor (ID) is constituted by at least 80% mol of 1,3 diethers with respect to the total molar amount of electron donor compounds; the prepolymerized catalyst has a porosity due to pores with diameters up to 1 μm of less than 0.2 cm3/g; it contains an amount of ethylene prepolymer of less than 45% with respect to the total weight of prepolymerized catalyst.

公开(公告)号：US09683062B2

公开(公告)日：2017-06-20

申请号：US15031913

申请日：2014-10-21

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Benedetta Gaddi ,  Marco Bocchino ,  Gianni Collina ,  Ofelia Fusco ,  Simona Guidotti ,  Antonio Mazzucco ,  Roberto Pantaleoni ,  Fabrizio Piemontesi

IPC: C08J9/00 ,  C08F210/06 ,  C08F10/06 ,  C08F210/02

CPC classification number: C08F210/02 ,  C08F10/06 ,  C08J9/0052 ,  C08J9/0066 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6545

Abstract: The present disclosure relates to a process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds, one of which is present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates, and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55° C.; optionally, ii) pre-polymerizing with one or more olefins of formula CH2═CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins for producing the porous propylene (co)polymer.

公开(公告)号：US20240209125A1

公开(公告)日：2024-06-27

申请号：US18287152

申请日：2022-04-08

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Benedetta Gaddi ,  Gianni Colina ,  Nicola Pazi ,  Ofelia Fusco ,  Paolo Vincenzi ,  Maria Di Diego ,  Giorgia Panno ,  Simone De Cicco ,  Giuseppina Maria Algozzini

IPC: C08F4/50 ,  C08F2/34 ,  C08F110/02 ,  C08F110/06

CPC classification number: C08F4/50 ,  C08F2/34 ,  C08F110/02 ,  C08F110/06

Abstract: A prepolymerized catalyst component for the polymerization of olefins made from or containing (i) a solid catalyst component made from or containing Ti, Mg, and an internal donor mixture (IDM) made from or containing (a) from 15 to 75% of 1,3-diethers and (b) from 25 to 85% of succinates based on the total amount of 1,3-diethers and succinates, and (ii) an amount of an ethylene polymer ranging from 0.1 up to 3 g per g of the solid catalyst component (i), wherein the prepolymerized catalyst component has an intrinsic viscosity [η] in tetraline at 135° C. ranging from 2.5 to 5.20 dl/g.

公开(公告)号：US09765161B2

公开(公告)日：2017-09-19

申请号：US14654201

申请日：2013-12-11

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Benedetta Gaddi ,  Gianni Collina ,  Daniele Evangelisti

IPC: C08F110/06 ,  C07F3/02 ,  C08F10/06

CPC classification number: C08F110/06 ,  C07F3/02 ,  C08F2/00 ,  C08F4/6548 ,  C08F10/06 ,  C08F10/00 ,  C08F4/6543 ,  C08F4/651 ,  C08F4/6465 ,  C08F2500/18

Abstract: Spherical adducts comprising a MgCl2, an alcohol ROH in which R is a C1-C10 hydrocarbon group, present in a molar ratio with MgCl2 ranging from 0.5 to 6 and less than 20% mol based on the mol of MgCl2 of a compound of formula Mg(OR1)2 in which R1 is selected from C1-C10 alkyl groups or R2CO groups in which R2 is selected from C1-C6 alkyl or aryl groups.

公开(公告)号：US20240309134A1

公开(公告)日：2024-09-19

申请号：US18577637

申请日：2022-06-24

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Marco Bocchino ,  Davide Tartari ,  Alberto Nardin ,  Benedetta Gaddi ,  Gianni Colina ,  Nicola Pazi

IPC: C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08J5/18 ,  C08J2323/16

Abstract: A biaxially oriented polypropylene (BOPP) film made from or containing a copolymer of propylene and ethylene having:



i) the content of ethylene derived units ranging from 0.5 wt % to 2.2 wt %;
ii) a xylene soluble fraction at 25°° C. ranging from 4.3 wt % to 6.5 wt %; and
iii) a melt flow rate, MFR, measured according to ISO 1133-1:2012 at 230° C. with a load of 2.16 kg, ranging from 0.5 g/10 min to 7.0 g/10 min.

公开(公告)号：US09920144B2

公开(公告)日：2018-03-20

申请号：US15507998

申请日：2015-08-20

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  Brandon N. Hudder

Inventor： Arrigo Arletti ,  Lucia Caiazzo ,  Gianni Collina ,  Daniele Evangelisti ,  Ofelia Fusco ,  Benedetta Gaddi

IPC: C08F110/06

CPC classification number: C08F110/06 ,  B01J31/0204 ,  B01J31/0209 ,  B01J31/0274 ,  B01J31/0275 ,  B01J31/143 ,  B01J31/38 ,  C08F10/06 ,  C08F4/6543 ,  C08F2500/18 ,  C08F2500/15 ,  C08F2500/24

Abstract: The present disclosure relates to a porous solid adduct comprising magnesium chloride and ethanol, characterized by a relationship between the content of alcohol, average pore radius and amount of porosity deriving from pores with radii of 100-1000 nm, and catalyst components produced therefrom that are capable of producing polyolefins with increased porosity.

公开(公告)号：US09650458B2

公开(公告)日：2017-05-16

申请号：US14774591

申请日：2014-03-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Monica Galvan ,  Andreas Neumann ,  Tiziana Caputo ,  Stefano Squarzoni ,  Antonio Mazzucco ,  Ofelia Fusco ,  Benedetta Gaddi ,  Gianni Collina ,  Gisella Biondini ,  Claudio Cavalieri ,  Roberto Pantaleoni

IPC: C08F210/06 ,  C08F4/646 ,  C08F4/649 ,  C08F4/654

CPC classification number: C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F110/06 ,  C08F4/6492 ,  C08F210/16 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: Propylene terpolymers are prepared by polymerizing propylene, ethylene and an alpha-olefin selected from the group of C4-C8 alpha-olefins in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.

公开(公告)号：US20140316069A1

公开(公告)日：2014-10-23

申请号：US14358753

申请日：2012-11-07

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Roberto Pantaleoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Andreas Neumann ,  Antonio Mazzucco ,  Gianni Collina ,  Marco Ciarafoni

IPC: C08L23/12

CPC classification number: C08L23/12 ,  C08F10/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2/00 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08F2/001 ,  C08F110/06 ,  C08L23/16

Abstract: A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene (co)polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process comprising: (i) a first step of polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins, to produce a propylene (co)polymer being for at least 85% by weight insoluble in xylene at 25° C.; and (ii) a successive step, carried out in gas-phase, in the presence of the product coming from step (i), of copolymerizing a mixture of ethylene with one or more α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer; the process being carried out in the presence of a catalyst system comprising: the product obtained by contacting: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two internal electron donor compounds one of which being present in an amount from 35 to 90% by mol with respect to the total amount of donors and being selected from succinates and the other being selected from 1,3-diethers, the total amount of internal electron donor compounds being lower than 14.0% by weight with respect to the total weight of the solid catalyst component; with (b) an aluminum hydrocarbyl compound, and optionally with (c) an external electron donor compound.

Abstract translation: 一种制备丙烯聚合物组合物的方法，其包含50至90重量％的在25℃下不溶于二甲苯的丙烯（共）聚合物部分和10至50重量％的可溶于二甲苯的乙烯共聚物部分 所述方法包括：（i）在乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯以产生丙烯（共）聚合物至少85重量％的第一步骤 在25℃不溶于二甲苯。 和（ii）在来自步骤（i）的产物存在下，在气相中进行共聚合乙烯与一种或多种α-烯烃CH 2 = CHR的混合物的连续步骤，其中R是烃 具有1-10个碳原子的基团，以制备乙烯共聚物; 该方法在催化剂体系存在下进行，该催化剂体系包括：通过使（a）包含卤化镁的固体催化剂组分，至少具有Ti-卤素键的钛化合物和至少两个内部电子给体 其中一种相对于供体总量为35至90摩尔％，其中一种选自琥珀酸酯，另一种选自1,3-二醚，内给电子体化合物的总量为 相对于固体催化剂组分的总重量低于14.0重量％ 与（b）铝烃基化合物，和任选与（c）外电子给体化合物。

公开(公告)号：US11267907B2

公开(公告)日：2022-03-08

申请号：US16647766

申请日：2018-09-07

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Diego Brita ,  Nicolo Arich De Finetti ,  Ofelia Fusco ,  Benedetta Gaddi

IPC: C08F4/654 ,  C08F4/655 ,  C08F10/06 ,  C08F4/659

Abstract: A process for the preparation of a solid catalyst component for the polymerization of CH2═CHR olefins, wherein R is hydrogen or hydrocarbyl radical with 1-12 carbon atoms, made from or containing a Ti compound on a Mg chloride based support, including the steps of (a) reacting a Mg based compound with a liquid medium made from or containing a Ti compound, at a temperature ranging from 0 to 150° C., thereby yielding solid particles; and (b) suspending the solid particles coming from step (a) in a liquid medium made from or containing hydrocarbons at a temperature ranging from 10 to 100° C., wherein step (a) or (b) is carried out in the presence of 0.2 to 20.0% by weight, with respect to the amount of Mg compound, of particles of a solid compound containing more than 50% by weight of SiO2 units and having average particle size from 1 to 100 μm.