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公开(公告)号：US09598511B2
公开(公告)日：2017-03-21
申请号：US14782573
申请日：2014-04-02
CPC分类号： C08F10/06 , C08F4/6421 , C08F4/6574 , C08F110/06 , C08F2410/01 , C08F2500/15
摘要： A solid catalyst component for the (co)polymerization of olefins CH2═CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms, optionally in mixture with ethylene, comprising Ti, Mg, Cu, Cl, and an electron donor compound characterized by the fact that the Cu/Ti weight ratio is lower than 0.5.
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2.发明申请CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS AND CATALYSTS THEREFROM OBTAINED 审中-公开用于获得烯烃和催化剂聚合的催化剂组分公开(公告)号：US20150259443A1
公开(公告)日：2015-09-17
申请号：US14431590
申请日：2013-09-25
发明人： Simona Guidotti , Simona Esposito , Dario Liguori , Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C08F4/6574 , C08F4/651 , C08F110/02 , C08F2500/18 , C08F2500/21 , C08F110/06 , C08F210/06 , C08F210/16
摘要： Catalyst components component for the (co)polymerization of olefins CH2═CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms, optionally in mixture with ethylene, comprising Ti, Mg, Zn, Cl, and an electron donor compound characterized by the fact that more than 50% of the titanium atoms are in the +4 valence state, and that the amount of Zn ranges from 0.1 to 4% by weight based on then total weight of said solid catalyst component.
摘要翻译： 用于（共）聚合烯烃CH 2 = CHR的催化剂组分组分，其中R是具有1-12个碳原子的烃基，任选与乙烯混合，包括Ti，Mg，Zn，Cl和电子给体化合物，其特征在于 由于超过50％的钛原子处于+4价态，并且Zn的量基于所述固体催化剂组分的总重量为0.1至4重量％。
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公开(公告)号：US10155827B2
公开(公告)日：2018-12-18
申请号：US15309138
申请日：2015-04-28
发明人： Paola Massari , Fabrizio Piemontesi , Gianni Vitale , Caroline Cathelin , Giampiero Morini , Marco Ciarafoni , Claudio Cavalieri , Tiziana Caputo
IPC分类号： C08F210/02 , C08F210/06 , C08J5/18
摘要： The present disclosure relates to a propylene ethylene copolymer comprising: an ethylene content of between 1.8 and 10.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: XS
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公开(公告)号：US10113012B2
公开(公告)日：2018-10-30
申请号：US15123108
申请日：2015-03-10
发明人： Simona Guidotti , Tiziano Dall'Occo , Dario Liguori , Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale
摘要： The present disclosure relates to a solid catalyst component for the (co)polymerization of olefins CH2═CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Ti, Mg, and Cl, and optionally an electron donor compound selected from the group consisting of ethers, amines, silanes, carbamates ketones, esters of aliphatic acids, alkyl and aryl esters of optionally substituted aromatic polycarboxylic acids, diol derivatives chosen among monoesters monocarbamates and monoesters monocarbonates or mixtures thereof, comprising from 0.1 to 50% wt of Bi with respect to the total weight of the solid catalyst component.
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公开(公告)号：US10562990B2
公开(公告)日：2020-02-18
申请号：US15759143
申请日：2016-08-30
摘要： A catalyst for the homopolymerization or copolymerization of CH2═CHR olefins, made from or containing the product obtained by contacting: (i) a solid catalyst component made from or containing Ti, Mg, Cl, and an internal electron donor compound, wherein the solid catalyst component contains from about 0.1 to about 50 wt % of Bi, based upon the total weight of the solid catalyst component; (ii) an alkyl aluminum compound and, (iii) an external electron donor compound having the formula: (R1)aSi(OR2)b wherein R1 and R2 are independently selected from the group consisting of alkyl radicals with 1-8 carbon atoms and a is 0 or 1 and a+b=4.
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公开(公告)号：US10316122B2
公开(公告)日：2019-06-11
申请号：US15768875
申请日：2016-10-25
发明人： Paola Massari , Caroline Cathelin , Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Marco Ciarafoni , Claudio Cavalieri , Roberto Pantaleoni , Michele Grazzi
摘要： A polypropylene composition made from or containing: A) from 50 wt % to 90 wt %; of a propylene homopolymer; B) from 10 wt % to 50 wt %; of a copolymer of propylene having from 30.0 wt % to 70.0 wt %, of ethylene derived units, based upon the total weight of the copolymer; the sum of the amount of component A) and B) being 100; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from 0.5 to 100 g/10 min; iii) a xylene soluble fraction ranging from 20 wt % to 50 wt %, based upon the total weight of the polypropylene composition; wherein the polypropylene composition being obtained by a polymerization process wherein the catalyst system contains bismuth.
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公开(公告)号：US09683062B2
公开(公告)日：2017-06-20
申请号：US15031913
申请日：2014-10-21
发明人： Benedetta Gaddi , Marco Bocchino , Gianni Collina , Ofelia Fusco , Simona Guidotti , Antonio Mazzucco , Roberto Pantaleoni , Fabrizio Piemontesi
IPC分类号： C08J9/00 , C08F210/06 , C08F10/06 , C08F210/02
CPC分类号： C08F210/02 , C08F10/06 , C08J9/0052 , C08J9/0066 , C08F210/06 , C08F210/16 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F4/6492 , C08F4/651 , C08F2/001 , C08F4/6545
摘要： The present disclosure relates to a process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds, one of which is present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates, and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55° C.; optionally, ii) pre-polymerizing with one or more olefins of formula CH2═CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins for producing the porous propylene (co)polymer.
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公开(公告)号：US20150353653A1
公开(公告)日：2015-12-10
申请号：US14761571
申请日：2014-01-14
发明人： Gianni Vitale , Simona Esposito , Simona Guidotti , Alessandro Mignogna , Giampiero Morini , Fabrizio Piemontesi
IPC分类号： C08F10/08
CPC分类号： C08F10/08 , C08F110/08 , C08F4/651 , C08F4/6555 , C08F4/6565 , C08F4/6567 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/17
摘要： A liquid phase process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups, equal to or different from each other, are C1-C10 hydrocarbon groups; (b) an aluminium alkyl cocatalyst and (c) an external electron donor.
摘要翻译： 在催化剂存在下进行丁烯-1聚合的液相方法，包括（a）包含Mg，Ti的固体催化剂组分和下式（I）的电子给体化合物，其中R基团相等 彼此是或不同的是C 1 -C 10烃基; （b）烷基铝助催化剂和（c）外电子给体。
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公开(公告)号：US20150141595A1
公开(公告)日：2015-05-21
申请号：US14406390
申请日：2013-05-13
发明人： Alessandro Mignogan , Simona Esposito , Simona Guidotti , Giampiero Morini , Joachim T.M. Pater , Fabrizio Piemontesi , Gianni Vitale
IPC分类号： C08F110/08
CPC分类号： C08F4/52 , C08F4/10 , C08F4/16 , C08F110/08 , C08F4/651 , C08F2500/15 , C08F2500/17 , C08F110/06 , C08F2500/12
摘要： Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I) In which the R groups equal to or different from each other, are C1-C15 hydrocarbon groups, the R1-R2 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor
摘要翻译： 在催化剂存在下进行丁烯-1的聚合方法，包括（a）包含Mg，Ti和下式（I）的电子给体化合物的固体催化剂组分：其中R基团等于或不同于 彼此是C1-C15烃基，R1-R2基彼此相同或不同，是氢，卤素或C1-C15烃基，任选地含有选自卤素，P，S，N和Si的杂原子 ，n和m为0〜3的整数，条件是它们中的至少一个不同于0; （b）烷基铝助催化剂和（c）外电子给体
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公开(公告)号：US11028259B2
公开(公告)日：2021-06-08
申请号：US15750799
申请日：2016-07-19
发明人： Paola Massari , Caroline Cathelin , Claudio Cavalieri , Marco Ciarafoni , Andrea Felisati , Angelo Ferraro , Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale
摘要： A multilayer film made from or containing a skin layer made from or containing a polyolefin composition made from or containing:
A) from 19 wt % to 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and
B) from 50 wt % to 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and 1-butene derived units content of between 4.8 wt % to 12.4 wt %;
the sum of the amount of component A) and B) being 100;
the composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; the creep and recovery curve measured on the polymer fuse at 200° C. shows a maximum value between 600 and 1200 seconds, lower than 53×10−5 1/Pa.
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