公开(公告)号：US10155827B2

公开(公告)日：2018-12-18

申请号：US15309138

申请日：2015-04-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Fabrizio Piemontesi ,  Gianni Vitale ,  Caroline Cathelin ,  Giampiero Morini ,  Marco Ciarafoni ,  Claudio Cavalieri ,  Tiziana Caputo

IPC: C08F210/02 ,  C08F210/06 ,  C08J5/18

Abstract: The present disclosure relates to a propylene ethylene copolymer comprising: an ethylene content of between 1.8 and 10.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: XS

公开(公告)号：US09650457B2

公开(公告)日：2017-05-16

申请号：US14402262

申请日：2013-05-21

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Roberta Marzolla ,  Monica Galvan ,  Tiziana Caputo

IPC: C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08L23/14

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/12 ,  C08J2323/14 ,  C08L23/14 ,  C08L23/142 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: A propylene, ethylene, 1-butene terpolymer containing from 0.5 wt % to 2.2 wt % of ethylene derived units and from 6.0 wt % to 20.0 wt % of 1 butene derived units; wherein: i) the ratio C2 wt %/C4 wt % ranges from 0.09 to 0.06; wherein C2 wt % is the weight percent of ethylene derived units and C4 wt % is the weight percent of 1-butene derived units; ii) the Melt flow rate ranges from 0.4 to 54 g/10 min; iii) the xylene soluble fraction at 25° C. is lower than 15.0 wt % the minimum value being 5.0 wt %.

公开(公告)号：US20150284488A1

公开(公告)日：2015-10-08

申请号：US14436412

申请日：2013-10-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Monica Galvan ,  Andreas Neumann ,  Tiziana Caputo ,  Stefano Squarzoni ,  Antonio Mazzucco ,  Ofelia Fusco ,  Benedetta Gaddi ,  Gianni Collina

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F4/651 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/26

Abstract: A process for the preparation of random copolymer of propylene containing up to 6.0% by weight of ethylene units, suitable for the manufacture of pipes, by copolymerizing propylene and ethylene in the presence of a catalyst system comprising the product obtained by contacting the following components:(a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers,(b) an aluminum hydrocarbyl compound, and(c) optionally an external electron donor compound.

Abstract translation: 一种制备含有至多6.0重量％乙烯单元的丙烯无规共聚物的方法，该乙烯单元通过在包含通过接触以下组分获得的产物的催化剂体系存在下共聚丙烯和乙烯来制备管道： （a）固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种以相对于总量为40至90摩尔％的量存在 选自琥珀酸盐，另一种选自1,3-二醚，（b）铝烃基化合物，和（c）任选的外电子给体化合物。

公开(公告)号：US20150232588A1

公开(公告)日：2015-08-20

申请号：US14429585

申请日：2013-09-05

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Enrico Balestra ,  Tiziana Caputo ,  Maurizio Dorini ,  Antonio Mazzucco ,  Silvia Soffritti

IPC: C08F10/06 ,  B01J19/24

CPC classification number: C08F10/06 ,  B01J8/24 ,  B01J8/26 ,  B01J8/388 ,  B01J19/24 ,  B01J2208/00274 ,  B01J2208/00283 ,  B01J2208/00734 ,  B01J2219/00164 ,  B01J2219/24 ,  C08F10/00 ,  C08F210/06 ,  C08F2/34 ,  C08F2/005 ,  C08F2/001 ,  C08F210/16 ,  C08F2500/12 ,  C08F2/01

Abstract: A process and apparatus for producing olefin polymers are disclosed, comprising:a. polymerizing one or more olefins in the gas phase, in the presence of an olefin polymerization catalyst, whereby growing polymer particles flow along a cylindrically-shaped downward path in densified form under the action of gravity so as to form a densified bed of downward-flowing polymer particles b. allowing said polymer particles to flow through a restriction of the densified bed, such restriction being positioned in a restriction zone extending from the bed upward to a distance of 15% of the total height of the densified bed; and c. metering an antistatic agent through a feed line connected to the densified bed at a feed point being located in a feed zone extending from the top of the restriction upward, to a distance five times the diameter of the section of the densified bed above the restriction.

Abstract translation: 公开了一种用于生产烯烃聚合物的方法和设备，包括：a。 在气相中聚合一种或多种烯烃，在烯烃聚合催化剂的存在下，由此生长的聚合物颗粒在致密形式的重力作用下沿着圆柱形的向下的路径流动，以形成向下流动的致密化床 聚合物颗粒b。 允许所述聚合物颗粒流过致密化床的限制，这种限制被定位在从床向上延伸到致密化床的总高度的15％的距离的限制区域中; 和c。 通过连接到致密化床的供给管线的计量抗静电剂，所述供给管线位于从限制件的顶部向上延伸的进料区域中的进料点，距离所述限制物上方的致密化床部分的直径的五倍。

公开(公告)号：US20150087770A1

公开(公告)日：2015-03-26

申请号：US14402262

申请日：2013-05-21

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Roberta Marzolla ,  Monica Galvan ,  Tiziana Caputo

IPC: C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/12 ,  C08J2323/14 ,  C08L23/14 ,  C08L23/142 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: A propylene, ethylene, 1-butene terpolymer containing from 0.5 wt % to 2.2 wt % of ethylene derived units and from 6.0 wt % to 20.0 wt % of 1 butene derived units; wherein: i) the ratio C2 wt %/C4 wt % ranges from 0.09 to 0.06; wherein C2 wt % is the weight per cent of ethylene derived units and C4 wt % is the weight per cent of 1-butene derived units; ii) the Melt flow rate ranges from 0.4 to 54 g/10 min; iii) the xylene soluble fraction at 25° C. is lower than 15.0 wt % the minimum value being 5.0 wt %.

Abstract translation: 含有0.5重量％至2.2重量％的乙烯衍生单元和6.0重量％至20.0重量％的1-丁烯衍生单元的丙烯，乙烯，1-丁烯三元共聚物; 其中：i）C2重量％/ C4重量％的比率范围为0.09至0.06; 其中C2重量％是乙烯衍生单元的重量百分比，C4重量％是1-丁烯衍生单元的重量百分数; ii）熔体流动速率范围为0.4至54g / 10min; iii）25℃下的二甲苯可溶级分低于15.0wt％，最小值为5.0wt％。