公开(公告)号：US20190233551A1

公开(公告)日：2019-08-01

申请号：US16377358

申请日：2019-04-08

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Chung C. Tso ,  Randall S. Muninger ,  Qing Yang ,  Youlu Yu ,  Yongwoo Inn

IPC: C08F4/6192 ,  C08L23/08 ,  C08F210/16 ,  C08J5/18 ,  C08F10/02 ,  C08F4/659 ,  C08F4/64

CPC classification number: C08F4/6192 ,  C08F4/64 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/02 ,  C08F210/16 ,  C08F2410/01 ,  C08F2420/04 ,  C08F2500/01 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2207/068 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/10 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26

Abstract: Disclosed herein are ethylene-based polymers generally characterized by a density from 0.89 to 0.93 g/cm3, a ratio of Mw/Mn from 3 to 6.5, a Mz from 200,000 to 650,000 g/mol, a CY-a parameter at 190° C. from 0.2 to 0.4, and a reverse short chain branching distribution. The ATREF profile of these polymers can have a high temperature peak from 92 to 102° C., and a low temperature peak from 18 to 36° C. less than that of the high temperature peak. These polymers can have comparable physical properties to that of a metallocene-catalyzed LLDPE, but with improved processability, shear thinning, and melt strength, and can be used in blown film and other end-use applications.

公开(公告)号：US10214603B2

公开(公告)日：2019-02-26

申请号：US15981489

申请日：2018-05-16

Applicant: Chevron Phillips Chemical Company LP

Inventor： Chung Tso ,  Carlos A. Cruz ,  Qing Yang ,  Max P. McDaniel ,  Jared L. Barr ,  Youlu Yu ,  Yongwoo Inn ,  Ashish M. Sukhadia ,  Brandy Rutledge-Ryal ,  Daniel G. Hert ,  Kelly Frey ,  Bill Bridendolph ,  William Fisher

IPC: C08F10/02 ,  C08J5/18 ,  B29D7/01 ,  B32B27/32 ,  C08F210/16 ,  C09D123/08 ,  C08J7/04 ,  B32B7/00 ,  B32B37/15 ,  B29C47/02 ,  B29C47/00 ,  B29C47/92 ,  C08F210/14

Abstract: A polyolefin having a density of greater than about 0.930 g/ml which when extruded at a temperature in the range of from about 590° F. to about 645° F. and then coated onto a substrate at a rate of from about 300 ft/min to about 1000 ft/min has an edge weave of from about 0 in/side to about 2.5 in/side and a neck-in of less than about 3.0 in/side.

公开(公告)号：US20180258205A1

公开(公告)日：2018-09-13

申请号：US15973610

申请日：2018-05-08

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Chung Ching Tso ,  Yongwoo Inn ,  Deloris R. Gagan ,  Randy S. Muninger

IPC: C08F210/16 ,  C08J9/228 ,  C08F4/659

Abstract: Disclosed herein are ethylene-based polymers generally characterized by a Mw ranging from 70,000 to 200,000 g/mol, a ratio of Mz/Mw ranging from 1.8 to 20, an 1B parameter ranging from 0.92 to 1.05, and an ATREF profile characterized by one large peak. These polymers have the dart impact, tear strength, and optical properties of a metallocene-catalyzed LLDPE, but with improved processability, melt strength, and bubble stability, and can be used in blown film and other end-use applications.

公开(公告)号：US09975976B1

公开(公告)日：2018-05-22

申请号：US15489663

申请日：2017-04-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Chung Tso ,  Jared L. Barr ,  Kelly Frey ,  Carlos A. Cruz ,  Youlu Yu ,  Bill Bridendolph ,  Qing Yang ,  Yongwoo Inn ,  William Fisher ,  Max P. McDaniel ,  Ashish M. Sukhadia ,  Brandy Rutledge-Ryal ,  Daniel G. Hert

IPC: C08F210/16 ,  C09D123/08 ,  C08J7/04 ,  B32B7/00 ,  B32B27/32 ,  B32B37/15 ,  C08F210/14

CPC classification number: C08F210/16 ,  B29C47/025 ,  B32B7/005 ,  B32B27/327 ,  B32B37/153 ,  B32B2250/02 ,  B32B2307/72 ,  B32B2323/046 ,  C08F210/14 ,  C08F2500/26 ,  C08J7/047 ,  C08J2323/20 ,  C09D123/0815

Abstract: A polyolefin having a density of greater than about 0.930 g/ml which when extruded at a temperature in the range of from about 590° F. to about 645° F. and then coated onto a substrate at a rate of from about 300 ft/min to about 1000 ft/min has an edge weave of from about 0 in/side to about 2.5 in/side and a neck-in of less than about 3.0 in/side.

公开(公告)号：US20180044454A1

公开(公告)日：2018-02-15

申请号：US15792271

申请日：2017-10-24

Applicant: Chevron Phillips Chemical Company LP

Inventor： Vivek Rohatgi ,  Yongwoo Inn ,  Ashish M. Sukhadia ,  Qing Yang ,  Paul J. DesLauriers

IPC: C08F210/16 ,  C08L23/08 ,  C08F4/659 ,  C08F4/6592

CPC classification number: C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08L23/0815 ,  C08L2203/18 ,  C08L2205/025 ,  C08L2312/00 ,  C08F4/65904 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/17

Abstract: A crosslinked metallocene-catalyzed polyethylene copolymer having a higher molecular weight (HMW) component and lower molecular weight (LMW) component wherein the HMW component is present in an amount of from about 10 wt. % to about 30 wt. % and wherein the LMW component is present in an amount of from about 70 wt. % to about 90 wt. %.

公开(公告)号：US09605100B2

公开(公告)日：2017-03-28

申请号：US15193195

申请日：2016-06-27

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Errun Ding ,  Paul DesLauriers ,  Yongwoo Inn ,  Lili Cui ,  Qing Yang ,  Ashish M. Sukhadia ,  Guylaine St. Jean ,  Richard M. Buck

IPC: C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08L23/08 ,  C08F4/659 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65922 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00 ,  C08J2323/08 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/12

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.

公开(公告)号：US09550849B2

公开(公告)日：2017-01-24

申请号：US14995268

申请日：2016-01-14

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Qing Yang ,  Yongwoo Inn ,  William M. Whitte ,  John R. Rathman ,  Steven J. Secora ,  Daniel G. Hert

IPC: C08L23/08 ,  C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/659

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65916 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/07 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/05 ,  C08F4/65927 ,  C08F4/65925

Abstract: Disclosed herein are ethylene-based polymers having a density greater than 0.945 g/cm3, a high load melt index less than 25 g/10 min, a peak molecular weight ranging from 52,000 to 132,000 g/mol, and an environmental stress crack resistance of at least 250 hours. These polymers have the processability of chromium-based resins, but with improved impact strength and stress crack resistance, and can be used in large-part blow molding applications.

Abstract translation: 本文公开了具有密度大于0.945g / cm 3，高负荷熔融指数小于25g / 10min，峰值分子量为52,000至132,000g / mol的乙烯基聚合物和环境应力开裂抗性 至少250小时。 这些聚合物具有铬基树脂的加工性，但具有改善的冲击强度和抗应力开裂性，并且可用于大部分吹塑应用。

公开(公告)号：US20160017069A1

公开(公告)日：2016-01-21

申请号：US14870361

申请日：2015-09-30

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Max P. McDaniel ,  Tony R. Crain ,  Youlu Yu ,  Yongwoo Inn

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/00 ,  C08F210/16 ,  C08L23/00 ,  C08L23/0815 ,  C08L2314/06 ,  Y10S526/943 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/05 ,  C08F210/14 ,  C08L23/06

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes use a catalyst system containing three metallocene components, often resulting in polymers having a reverse comonomer distribution and a broad and non-bimodal molecular weight distribution.

Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法使用含有三种茂金属组分的催化剂体系，其常常导致聚合物具有反向共聚单体分布和广泛的和非双峰分子量分布。

公开(公告)号：US20150376312A1

公开(公告)日：2015-12-31

申请号：US14842888

申请日：2015-09-02

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Errun Ding ,  Paul DesLauriers ,  Yongwoo Inn ,  Lili Cui ,  Qing Yang ,  Ashish Sukhadia ,  Guylaine St. Jean ,  Richard M. Buck

IPC: C08F210/16 ,  C08J5/00

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65922 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00 ,  C08J2323/08 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/12

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.

公开(公告)号：US09169337B2

公开(公告)日：2015-10-27

申请号：US14205461

申请日：2014-03-12

Applicant: Chevron Phillips Chemical Company LP

Inventor： Vivek Rohatgi ,  Jeffrey F. Greco ,  Yongwoo Inn ,  Qing Yang ,  Alfred E. Brown, Jr.

IPC: C08F210/16 ,  C08F210/02 ,  C08F10/14 ,  C08F10/08

CPC classification number: C08F210/16 ,  C08F10/08 ,  C08F10/14 ,  C08F2500/05 ,  C08F2500/07 ,  C08F2500/12 ,  C08F4/65927 ,  C08F4/65904 ,  C08F4/65925 ,  C08F210/14 ,  C08F2500/17 ,  C08F2500/13

Abstract: Disclosed herein are ethylene-based polymers having a higher molecular weight component and a lower molecular weight component, and characterized by a density greater than 0.945 g/cm3, a melt index less than 1.5 g/10 min, and a ratio of high load melt index to melt index ranging from 40 to 175. These polymers have the processability of chromium-based resins, but with improved stiffness and stress crack resistance, and can be used in blow molding and other end-use applications.

Abstract translation: 本文公开了具有较高分子量组分和较低分子量组分的乙烯基聚合物，其特征在于密度大于0.945g / cm 3，熔体指数小于1.5g / 10min，高负载熔体 熔体指数指数范围从40至175.这些聚合物具有铬基树脂的加工性，但具有改善的刚度和抗应力开裂性，并且可用于吹塑和其它终端应用。