公开(公告)号：US20170081439A1

公开(公告)日：2017-03-23

申请号：US15366068

申请日：2016-12-01

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco ,  Qing Yang ,  Tony R. Crain

IPC: C08F110/02 ,  C07F17/00

CPC classification number: C08F110/02 ,  B01J31/2295 ,  B01J2531/46 ,  B01J2531/48 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F210/16 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/02 ,  C08F2500/07

Abstract: Disclosed herein are catalyst compositions containing boron bridged, cyclopentadienyl-indenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene homopolymers produced using these catalyst compositions can be characterized by a density less than 0.97 g/cm3 and a melt index greater than 50 g/10 min.

公开(公告)号：US09540465B2

公开(公告)日：2017-01-10

申请号：US14255076

申请日：2014-04-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco ,  Qing Yang ,  Tony R. Crain

IPC: C08F110/02 ,  C08F4/6592 ,  C08F210/16 ,  C08F10/02 ,  C08L23/08 ,  B01J31/22 ,  C08F4/659

CPC classification number: C08F110/02 ,  B01J31/2295 ,  B01J2531/46 ,  B01J2531/48 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F210/16 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/02 ,  C08F2500/07

Abstract: Disclosed herein are catalyst compositions containing boron bridged, cyclopentadienyl-indenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene homopolymers produced using these catalyst compositions can be characterized by a density less than 0.97 g/cm3 and a melt index greater than 50 g/10 min.

Abstract translation: 本文公开了含有桥连的具有烯基取代基的环戊二烯基 - 茚基金属茂化合物的催化剂组合物。 这些催化剂组合物可用于烯烃的聚合。 例如，使用这些催化剂组合物制备的乙烯均聚物的特征可以是密度小于0.97g / cm 3，熔体指数大于50g / 10min。

公开(公告)号：US20160159948A1

公开(公告)日：2016-06-09

申请号：US15044140

申请日：2016-02-16

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco

IPC: C08F210/16 ,  C07F7/00

CPC classification number: C08F210/16 ,  C07F7/00 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/08 ,  C08F210/14 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are catalyst compositions containing boron bridged, bis-indenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene copolymers produced using these catalyst compositions can be characterized by a density less than 0.92 g/cm3 and a melt index greater than 25 g/10 min.

公开(公告)号：US20160053035A1

公开(公告)日：2016-02-25

申请号：US14859638

申请日：2015-09-21

Applicant: Chevron Phillips Chemical Company LP

Inventor： Vivek Rohatgi ,  Jeffrey F. Greco ,  Yongwoo Inn ,  Qing Yang ,  Alfred E. Brown, JR.

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F10/08 ,  C08F10/14 ,  C08F2500/05 ,  C08F2500/07 ,  C08F2500/12 ,  C08F4/65927 ,  C08F4/65904 ,  C08F4/65925 ,  C08F210/14 ,  C08F2500/17 ,  C08F2500/13

Abstract: Disclosed herein are ethylene-based polymers having a higher molecular weight component and a lower molecular weight component, and characterized by a density greater than 0.945 g/cm3, a melt index less than 1.5 g/10 min, and a ratio of high load melt index to melt index ranging from 40 to 175. These polymers have the processability of chromium-based resins, but with improved stiffness and stress crack resistance, and can be used in blow molding and other end-use applications.

Abstract translation: 本文公开了具有较高分子量组分和较低分子量组分的乙烯基聚合物，其特征在于密度大于0.945g / cm 3，熔体指数小于1.5g / 10min，高负载熔体 熔体指数指数范围从40至175.这些聚合物具有铬基树脂的加工性，但具有改善的刚度和抗应力开裂性，并且可用于吹塑和其它终端应用。

公开(公告)号：US09988470B2

公开(公告)日：2018-06-05

申请号：US15366068

申请日：2016-12-01

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco

IPC: C07F17/00 ,  C08F4/6592 ,  C08F210/16 ,  C08F110/02 ,  C08F10/02 ,  C08L23/08 ,  B01J31/22 ,  C08F4/659

CPC classification number: C08F110/02 ,  B01J31/2295 ,  B01J2531/46 ,  B01J2531/48 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F210/16 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/02 ,  C08F2500/07

Abstract: Disclosed herein are catalyst compositions containing boron bridged, cyclopentadienyl-indenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene homopolymers produced using these catalyst compositions can be characterized by a density less than 0.97 g/cm3 and a melt index greater than 50 g/10 min.

公开(公告)号：US09758599B2

公开(公告)日：2017-09-12

申请号：US14863575

申请日：2015-09-24

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Lloyd W. Guatney ,  Jeffrey F. Greco

IPC: C08F4/6592 ,  C08F4/645 ,  C08F210/16

CPC classification number: C08F4/65925 ,  C08F4/6457 ,  C08F210/16 ,  C08F2410/04 ,  C08F4/6543 ,  C08F4/025 ,  C08F4/685 ,  C08F4/6343 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/17 ,  C08F110/02 ,  C08F4/65904

Abstract: Catalyst systems containing a Ziegler-Natta catalyst component are disclosed. Such catalyst systems can contain a co-catalyst and a supported catalyst containing a fluorided silica-coated alumina, a magnesium compound, and vanadium and/or tetravalent titanium.

公开(公告)号：US09469702B2

公开(公告)日：2016-10-18

申请号：US15046549

申请日：2016-02-18

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco

IPC: C08F4/6592 ,  C08F10/02 ,  C08F110/02 ,  C07F17/00 ,  C08F210/16 ,  C08L23/08 ,  C08F4/659

CPC classification number: C08F10/02 ,  C07F7/00 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are catalyst compositions containing boron-bridged, cyclopentadienyl-fluorenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene copolymers produced using these catalyst compositions can be characterized by a combination of a flat or a conventional comonomer distribution and low levels of long chain branching.

Abstract translation: 本文公开了含有硼桥连的具有烯基取代基的环戊二烯基 - 芴基茂金属化合物的催化剂组合物。 这些催化剂组合物可用于烯烃的聚合。 例如，使用这些催化剂组合物制备的乙烯共聚物可以通过平面或常规共聚单体分布和低水平的长链支化的组合来表征。

公开(公告)号：US20150141599A1

公开(公告)日：2015-05-21

申请号：US14533161

申请日：2014-11-05

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco

IPC: C08F10/02

CPC classification number: C08F10/02 ,  C07F7/00 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are catalyst compositions containing boron-bridged, cyclopentadienyl-fluorenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene copolymers produced using these catalyst compositions can be characterized by a combination of a flat or a conventional comonomer distribution and low levels of long chain branching.

Abstract translation: 本文公开了含有硼桥连的具有烯基取代基的环戊二烯基 - 芴基茂金属化合物的催化剂组合物。 这些催化剂组合物可用于烯烃的聚合。 例如，使用这些催化剂组合物制备的乙烯共聚物可以通过平面或常规共聚单体分布和低水平的长链支化的组合来表征。

公开(公告)号：US20170015769A1

公开(公告)日：2017-01-19

申请号：US15279512

申请日：2016-09-29

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C07F7/00 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/08 ,  C08F210/14 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are catalyst compositions containing boron bridged, bis-indenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene copolymers produced using these catalyst compositions can be characterized by a density less than 0.92 g/cm3 and a melt index greater than 25 g/10 min.

Abstract translation: 本文公开了含有桥连的具有烯基取代基的双茚基茂金属化合物的催化剂组合物。 这些催化剂组合物可用于烯烃的聚合。 例如，使用这些催化剂组合物生产的乙烯共聚物的特征可以是密度小于0.92g / cm 3，熔体指数大于25g / 10min。

公开(公告)号：US09475898B2

公开(公告)日：2016-10-25

申请号：US14859638

申请日：2015-09-21

Applicant: Chevron Phillips Chemical Company LP

Inventor： Vivek Rohatgi ,  Jeffrey F. Greco ,  Yongwoo Inn ,  Qing Yang ,  Alfred E. Brown, Jr.

IPC: C08F210/16 ,  C08F4/64 ,  C08F10/14 ,  C08F10/08

CPC classification number: C08F210/16 ,  C08F10/08 ,  C08F10/14 ,  C08F2500/05 ,  C08F2500/07 ,  C08F2500/12 ,  C08F4/65927 ,  C08F4/65904 ,  C08F4/65925 ,  C08F210/14 ,  C08F2500/17 ,  C08F2500/13

Abstract: Disclosed herein are ethylene-based polymers having a higher molecular weight component and a lower molecular weight component, and characterized by a density greater than 0.945 g/cm3, a melt index less than 1.5 g/10 min, and a ratio of high load melt index to melt index ranging from 40 to 175. These polymers have the processability of chromium-based resins, but with improved stiffness and stress crack resistance, and can be used in blow molding and other end-use applications.