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公开(公告)号：US10435492B2
公开(公告)日：2019-10-08
申请号：US15890524
申请日：2018-02-07
Applicant: Chevron Phillips Chemical Company LP
Inventor： Errun Ding , Chung C. Tso , Youlu Yu , Qing Yang , Richard M. Buck
IPC: C08F210/02 , C08F210/16 , C08F4/659
Abstract: Catalyst systems having both a metallocene catalyst component and a Ziegler-Natta component are disclosed. Such catalyst systems can contain a metallocene compound, an activator-support, an organoaluminum compound, and a Ziegler-Natta component comprising titanium supported on magnesium chloride.
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22.发明申请公开(公告)号：US20190263943A1
公开(公告)日：2019-08-29
申请号：US15908033
申请日：2018-02-28
Applicant: Chevron Phillips Chemical Company LP
Inventor： Youlu Yu , Paul J. DesLauriers , Yongwoo Inn
Abstract: A method of determining multimodal polyethylene quality comprising the steps of (a) providing a multimodal polyethylene resin sample; (b) determining, in any sequence, the following: that the multimodal polyethylene resin sample has a melt index within 30% of a target melt index; that the multimodal polyethylene resin sample has a density within 2.5% of a target density; that the multimodal polyethylene resin sample has a dynamic viscosity deviation (% MVD) from a target dynamic viscosity of less than about 100%; that the multimodal polyethylene resin sample has a weight average molecular weight (Mw) deviation (% MwD) from a target Mw of less than about 20%; and that the multimodal polyethylene resin sample has a gel permeation chromatography (GPC) curve profile deviation (% GPCD) from a target GPC curve profile of less than about 15%; and (c) responsive to step (b), designating the multimodal polyethylene resin sample as a high quality resin.
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公开(公告)号：US10358506B2
公开(公告)日：2019-07-23
申请号：US15723225
申请日：2017-10-03
Applicant: Chevron Phillips Chemical Company LP
Inventor： Errun Ding , Chung C. Tso , Randall S. Muninger , Qing Yang , Youlu Yu , Yongwoo Inn
IPC: C08F4/653 , C08F4/6592 , C08F210/16 , C08L23/08 , C08F4/6192 , C08F4/64 , C08F10/02 , C08F4/659
Abstract: Disclosed herein are ethylene-based polymers generally characterized by a density from 0.89 to 0.93 g/cm3, a ratio of Mw/Mn from 3 to 6.5, a Mz from 200,000 to 650,000 g/mol, a CY-a parameter at 190° C. from 0.2 to 0.4, and a reverse short chain branching distribution. The ATREF profile of these polymers can have a high temperature peak from 92 to 102° C., and a low temperature peak from 18 to 36° C. less than that of the high temperature peak. These polymers can have comparable physical properties to that of a metallocene-catalyzed LLDPE, but with improved processability, shear thinning, and melt strength, and can be used in blown film and other end-use applications.
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24.发明授权公开(公告)号：US09791358B2
公开(公告)日：2017-10-17
申请号：US15471414
申请日：2017-03-28
Applicant: Chevron Phillips Chemical Company LP
Inventor： Youlu Yu , Qing Yang , Paul J. Deslauriers , Mark J. Lamborn , Yongwoo Inn
CPC classification number: G01N5/00 , C08F110/02 , C08J5/18 , C08J2323/06 , C08J2323/08 , C08L23/06 , G01N11/00 , G01N11/06 , G01N33/442
Abstract: A method of preparing a polymer article comprising determining a zero-shear viscosity for a polymer sample; sieving the polymer sample to produce a plurality of sieved polymer samples; determining a molecular weight distribution for each of the plurality of sieved polymer samples; determining a zero-shear viscosity for each of the plurality of sieved polymer samples; determining a compositional diversity of each of the plurality of sieved polymer samples based on a ratio of the zero shear viscosity for each of the plurality of sieved polymer samples to the zero shear viscosity for the polymer sample; identifying a polymer sample having a ratio of the zero shear viscosity to zero shear viscosity for the polymer sample of from about 0.5 to equal to or greater than about 3; and preparing a polymer article from the identified polymer sample.
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公开(公告)号：US09718907B2
公开(公告)日：2017-08-01
申请号：US15194622
申请日：2016-06-28
Applicant: Chevron Phillips Chemical Company LP
Inventor： Errun Ding , Chung C. Tso , Youlu Yu , Qing Yang , Richard M. Buck
IPC: C08F4/00 , C08F210/00 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/02 , C08F210/16 , C08F4/659
CPC classification number: C08F210/02 , C08F4/65912 , C08F210/16 , C08F4/65904 , C08F4/6592 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F110/02
Abstract: Catalyst systems having both a metallocene catalyst component and a Ziegler-Natta component are disclosed. Such catalyst systems can contain a metallocene compound, an activator-support, an organoaluminum compound, and a Ziegler-Natta component comprising titanium supported on magnesium chloride.
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Patent Agency Ranking
26.发明授权公开(公告)号：US09371407B2
公开(公告)日：2016-06-21
申请号：US14870361
申请日：2015-09-30
Applicant: Chevron Phillips Chemical Company LP
Inventor： Qing Yang , Max P. McDaniel , Tony R. Crain , Youlu Yu , Yongwoo Inn
IPC: C08F4/653 , C08F4/6592 , C08L23/00 , C08F110/02 , C08L23/08 , C08F4/659 , C08F210/00 , C08F210/16
CPC classification number: C08F110/02 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F210/00 , C08F210/16 , C08L23/00 , C08L23/0815 , C08L2314/06 , Y10S526/943 , C08F2500/04 , C08F2500/12 , C08F2500/24 , C08F2500/05 , C08F210/14 , C08L23/06
Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes use a catalyst system containing three metallocene components, often resulting in polymers having a reverse comonomer distribution and a broad and non-bimodal molecular weight distribution.
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27.发明授权Metallocene and half sandwich dual catalyst systems for producing broad molecular weight distribution polymers 有权茂金属和半夹心双重催化剂体系，用于生产宽分子量分布聚合物公开(公告)号：US09273159B2
公开(公告)日：2016-03-01
申请号：US14493384
申请日：2014-09-23
Applicant: Chevron Phillips Chemical Company LP
Inventor： Errun Ding , Qing Yang , Youlu Yu , Lloyd W. Guatney , Jim B. Askew
IPC: C08F4/642 , C08F4/653 , C08F4/6592 , C08F210/16 , C08F4/76 , C08F4/659 , C08F10/02 , C08F10/00 , C08L23/00 , C08L23/04 , C08L23/10
CPC classification number: C08F4/76 , C08F4/52 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/02 , C08L23/00 , C08L23/04 , C08L23/10 , C08F110/02 , C08F2500/04 , C08F2500/12 , C08F210/16 , C08F210/14 , C08F2500/03
Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can use a dual catalyst system containing a zirconium or hafnium based metallocene compound and a titanium based half-metallocene compound containing an indenyl group.
Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法可以使用含有锆或铪基茂金属化合物和含有茚基的钛基半茂金属化合物的双重催化剂体系。
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28.发明申请Catalyst System with Three Metallocenes for Producing Broad Molecular Weight Distribution Polymers 有权具有三种茂金属的催化剂体系用于生产广泛的分子量分布聚合物公开(公告)号：US20150005460A1
公开(公告)日：2015-01-01
申请号：US14485897
申请日：2014-09-15
Applicant: Chevron Phillips Chemical Company LP
Inventor： Qing Yang , Max P. McDaniel , Tony R. Crain , Youlu Yu , Yongwoo Inn
IPC: C08F210/16
CPC classification number: C08F110/02 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F210/00 , C08F210/16 , C08L23/00 , C08L23/0815 , C08L2314/06 , Y10S526/943 , C08F2500/04 , C08F2500/12 , C08F2500/24 , C08F2500/05 , C08F210/14 , C08L23/06
Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes use a catalyst system containing three metallocene components, often resulting in polymers having a reverse comonomer distribution and a broad and non-bimodal molecular weight distribution.
Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法使用含有三种茂金属组分的催化剂体系，其常常导致聚合物具有反向共聚单体分布和广泛的和非双峰分子量分布。
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29.发明授权Use of hydrogen and an organozinc compound for polymerization and polymer property control 有权氢和有机锌化合物用于聚合和聚合物性质控制公开(公告)号：US08829125B2
公开(公告)日：2014-09-09
申请号：US13927165
申请日：2013-06-26
Applicant: Chevron Phillips Chemical Company LP
Inventor： Errun Ding , Qing Yang , Albert P. Masino , Youlu Yu , Lloyd W. Guatney , Jim B. Askew
IPC: C08F4/00 , C08F4/06 , C08F4/12 , C08F2/00 , C08F210/00 , C08F210/16 , C08F10/00 , C08F110/02
CPC classification number: C08F210/16 , C08F10/00 , C08F110/02 , C08F2400/02 , C08F2/00 , C08F2/42 , C08F2500/04 , C08F2500/12
Abstract: Methods of controlling polymerization reactions using a synergistic amount of hydrogen and an organozinc compound are disclosed. The resulting polymers have lower molecular weights and higher melt flow indices.
Abstract translation: 公开了使用协同量的氢和有机锌化合物控制聚合反应的方法。 所得聚合物具有较低的分子量和较高的熔体流动指数。
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30.发明申请Metallocene and Half Sandwich Dual Catalyst Systems for Producing Broad Molecular Weight Distribution Polymers 有权茂金属和半夹心双重催化剂体系，用于生产广泛的分子量分布聚合物公开(公告)号：US20140088274A1
公开(公告)日：2014-03-27
申请号：US13625898
申请日：2012-09-25
Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP
Inventor： Errun Ding , Qing Yang , Youlu Yu , Lloyd W. Guatney , Jim B. Askew
CPC classification number: C08F4/76 , C08F4/52 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/02 , C08L23/00 , C08L23/04 , C08L23/10 , C08F110/02 , C08F2500/04 , C08F2500/12 , C08F210/16 , C08F210/14 , C08F2500/03
Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can use a dual catalyst system containing a zirconium or hafnium based metallocene compound and a titanium based half-metallocene compound containing an indenyl group.
Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法可以使用含有锆或铪基茂金属化合物和含有茚基的钛基半茂金属化合物的双重催化剂体系。
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