摘要:
Hexafluoroisobutylene and its higher homologs are easily reacted with SO3 to give fluorosulfates of the formula CH2═C(R)CF2OSO2F, wherein R is a linear branched or cyclic fluoroalkyl group comprised of 1 to 10 carbon atoms and may contain ether oxygen. These compounds react under mild conditions with many nucleophiles to give CH2═C(R)CF2X, where X is derived from the nucleophile. This reaction provides a route to many substituted hexafluoroisobutylenes, which copolymerize easily with other fluoro- and hydrocarbon monomers such as vinylidene fluoride and ethylene.
摘要翻译:六氟异丁烯及其较高的同系物容易与SO 3反应,得到式CH 2 -C(R)CF 2 OSO 2 F的氟代硫酸盐,其中R为含1-10个碳原子的直链支链或环状氟代烷基,并可含有醚氧。 这些化合物在温和条件下与许多亲核试剂反应得到CH2-C(R)CF2X,其中X衍生自亲核试剂。 该反应提供了许多取代的六氟异丁烯的路线,其容易与其它氟代和烃单体如偏二氟乙烯和乙烯共聚。
摘要:
The present invention is generally directed to electroluminescent Pt(II) complexes which have emission maxima across the visible spectrum, and devices that are made with the Pt(II) complexes.
摘要:
The present invention is generally directed to electroluminescent Ir(III) compounds with phosphinoalkoxides and phenylpyridines or phenylpyrimidines, and devices that are made with the Ir(III) compounds.
摘要:
The present invention is generally directed to electroluminescent Ir(III) compounds, the substituted 2-phenylpyridines, phenylpyrimidines, and phenylquinolines that are used to make the Ir(III) compounds, and devices that are made with the Ir(III) compounds.
摘要:
The present invention is generally directed to electroluminescent Ir(III) compounds, the substituted 2-phenylpyridines, phenylpyrimidines, and phenylquinolines that are used to make the Ir(III) compounds, and devices that are made with the Ir(III) compounds.
摘要:
The present invention is generally directed to electroluminescent Ir(III) compounds with phosphinoalkoxides and phenylpyridines or phenylpyrimidines, and devices that are made with the Ir(III) compounds.
摘要:
A process for the preparation of perfluoroalkyl iodides, especially perfluoroethyl iodide, by reaction of perfluorinated compounds which contain a carbon carbon double bond with ICl in HF solvent in the presence of Lewis acid catalysts. The compounds are used as telogens for the telomerization of tetrafluoroethylene to long-chain perfluoroalkyl iodides.
摘要:
This invention relates to carbon based initiators for polymerization and telomerization reactions. Polymers produced are useful as water repellants and materials with high temperature resistance. Telomers are useful as intermediates in the production of chemically inert and temperature resistant materials.
摘要:
Compositions comprising a fluorosurfactant and a hydrotrope are disclosed. The hydrotropes are either cationic or anionic benzene derivatives comprising fluoro-substituted functional groups and polar groups. The compositions are useful in various surfactant applications.
摘要:
A process is disclosed for making RR1R2CCR1R2F wherein R is selected from the group consisting of CH3, CH2F, C2H4F, and F(CF2)nCH2CH2 where n is an integer from 1 to 10, each R1 is independently selected from the group consisting of H, Cl, F and CF3, and each R2 is independently selected from the group consisting of H, F and CF3. The process involves reacting RF with R1R2C═CR1R2 in the presence of SbF5 to produce a product mixture comprising RR1R2CCR1R2F, wherein the reaction temperature is from about −60° C. to about −10° C., provided that total number of carbon atoms in R1R2C═CR1R2 is 5 or less.
摘要翻译:公开了制备RR1R2CCR1R2F的方法,其中R选自CH 3,CH 2 F,C 2 H 4 F和F(CF 2)n CH 2 CH 2,其中n为1至10的整数,每个R 1独立地选自H, Cl,F和CF 3,并且每个R 2独立地选自H,F和CF 3。 该方法包括在SbF 5存在下使RF与R 1 R 2 C = CR 1 R 2反应以产生包含RR1R2CCR1R2F的产物混合物,其中反应温度为约-60℃至约-10℃,条件是总碳原子数 R1R2C=CR1R2为5以下。