Catalytic addition of hydrofluorocarbons to fluoroolefins
    30.
    发明授权
    Catalytic addition of hydrofluorocarbons to fluoroolefins 失效
    向氟烯烃催化加成氢氟烃

    公开(公告)号:US08247625B2

    公开(公告)日:2012-08-21

    申请号:US12307754

    申请日:2007-07-03

    IPC分类号: C07C17/266 C07C17/26

    CPC分类号: C07C17/278 C07C19/08

    摘要: A process is disclosed for making RR1R2CCR1R2F wherein R is selected from the group consisting of CH3, CH2F, C2H4F, and F(CF2)nCH2CH2 where n is an integer from 1 to 10, each R1 is independently selected from the group consisting of H, Cl, F and CF3, and each R2 is independently selected from the group consisting of H, F and CF3. The process involves reacting RF with R1R2C═CR1R2 in the presence of SbF5 to produce a product mixture comprising RR1R2CCR1R2F, wherein the reaction temperature is from about −60° C. to about −10° C., provided that total number of carbon atoms in R1R2C═CR1R2 is 5 or less.

    摘要翻译: 公开了制备RR1R2CCR1R2F的方法,其中R选自CH 3,CH 2 F,C 2 H 4 F和F(CF 2)n CH 2 CH 2,其中n为1至10的整数,每个R 1独立地选自H, Cl,F和CF 3,并且每个R 2独立地选自H,F和CF 3。 该方法包括在SbF 5存在下使RF与R 1 R 2 C = CR 1 R 2反应以产生包含RR1R2CCR1R2F的产物混合物,其中反应温度为约-60℃至约-10℃,条件是总碳原子数 R1R2C=CR1R2为5以下。