Abstract:
The following invention relates to copolymers containing silicone groups which comprise, in copolymerized form, at least one monomer with an ionogenic and/or ionic group and at least one crosslinking monomer, to a process for the preparation of such copolymers containing silicone groups by precipitation polymerization, and to the use of these copolymers.
Abstract:
Aqueous dispersion obtainable by free-radical polymerization of a) at least one N-vinyl-containing monomer b) at least one polymeric dispersant c) at least one polymeric precipitation agent d) at least one crosslinker e) optionally further monomers f) optionally at least one regulator g) optionally a buffer substance where the weight ratio of b) to c) is in the range from 1:50 to 1:0.02.
Abstract:
A process for preparing an aqueous polymer dispersion by free-radically initiated polymerization of free-radically polymerizable compounds I with moderate solubility in water, whose disperse polymer particles contain not only compounds I but also compounds II with a very low solubility in water where a mixture consisting of a portion of the compounds I and consisting of the compounds II is used to produce an aqueous emulsion I with a droplet size .ltoreq.500 nm, and at least a portion of the aqueous emulsion I is supplied continuously to the polymerization vessel as a feed stream I, in the course of continuing free-radical polymerization, during which the continuous feed stream I is accompanied, at least some of the time, by a feed stream II consisting of another portion of the compounds I or of the aqueous emulsion II thereof with a droplet size .gtoreq.1000 nm.
Abstract:
The process for producing pressure-sensitive adhesive tapes comprises the steps ofclamping a tube strip of a tube skin filled with a pressure-sensitive adhesive composition into an apparatus comprising a tubular appliance,passing the tube strip through the tubular appliance while opening the tube skin longitudinally to form a tape,separating the tape from the pressure-sensitive adhesive composition in such a way that some of the pressure-sensitive adhesive composition remains as a film on the tape,causing the separated pressure-sensitive adhesive composition to exit the apparatus by way of a discharge aperture, andwinding up the tape separated from the pressure-sensitive adhesive composition, with the pressure-sensitive adhesive film that has remained thereon, as a pressure-sensitive adhesive tape.
Abstract:
The invention relates to a reference electrode for chemical sensors based on ion-selective field-effect transistors (CHEMFETs) in an electrolyte/insulator/semiconductor system. The reference electrode is essentially composed of a polyglutamate-coated insulator/semiconductor substrate or of a polyglutamate-coated phthalocyaninato-polysiloxane polymer film applied to an insulator/semiconductor substrate.
Abstract:
Solid dispersions of thermoplastic polymers and a crosslinked water-insoluble polymer, which solid dispersions are suitable as filter aids, wherein the solid dispersions comprise 20 to 95% by weight of at least one thermoplastic polymer (component A) and 5 to 80% by weight of at least one crosslinked water-insoluble polymer selected from the group consisting of homopolymers of N-vinylformamide, N-vinylcaprolactam, N-vinylpiperidone, N-vinylpyridines, N-vinylimidazoles, styrene monomers, acrylates and methacrylates and also copolymers of basic N-vinyl compounds, styrene monomers, acrylates and methacrylates (component B).
Abstract:
The present invention relates to a mono- and/or polyallyl-polyether-urethane, to water-soluble or water-dispersible polymers which comprise such a polyether-urethane in copolymerized form, and to cosmetic or pharmaceutical compositions which comprise a water-soluble or water-dispersible polymer based on a mono- and/or polyallyl-polyether-urethane.
Abstract:
The present invention relates to the use of, if appropriate present in the form of an aqueous dispersion, polymers of ethylenically unsaturated anionic monomers for modifying the rheology of aqueous, alcoholic or aqueous/alcoholic cosmetic or dermatological compositions. The polymers are obtainable by free-radical emulsion copolymerization of water-soluble inorganic monomers in aqueous phase in the presence of, in each case, at least one stabilizing polymer of groups a) and b). The emulsion polymers are exceptionally suitable for thickening cosmetic or dermatological preparations based either on water or on alcohols.
Abstract:
Ampholytic copolymers which contain a molar excess of anionogenic and/or anionic groups, polyelectrolyte complexes which contain such an ampholytic copolymer, cosmetic and pharmaceutical compositions which contain at least one such copolymer or polyelectrolyte complex and the use of these copolymers and polyelectrolyte complexes are described.
Abstract:
The use of copolymers containing a) from 60% to 99% by weight of at least one vinyllactam or N-vinylamine selected from the group consisting of N-vinylpyrrolidone, N-vinylpiperidone, N-vinylcaprolactam or N-vinylformamide, and b) from 1% to 40% by weight of at least one monomer of the general formula where b1) R1, R2, R3 each denote oxygen, C1-C4-alkyl, C6-aryl, C7-C10-alkylaryl and R4 denotes the general formula II X denotes oxygen, NH, NR (where R=R1) R5 denotes C1-C6-alkyl, phenyl, A denotes OH, NH2, NR2 (wheret R2=R1) R6, R7 R8 each denote hydrogen, C1-C4-alkyl n denotes an integer between 1 and 4 B, F each denote C, N D denotes C1-C4-alkyl, O, NH p denotes an integer between 0 and 15 E denotes N, O l, m each denote 0 or 1 R9, R10, R11 each denote hydrogen, C1-C4-alkyl, C6-C10-aryl, C7-C10-alkylaryl and s, q each denote an integer between 0 and 2. For E=nitrogen the s+q sum is equal to 1 or 2. For E=oxygen the s+q sum is equal to zero. For E=nitrogen and s+q=2 the counterions needed for charge neutrality are selected from elements of groups 1, 2 or 13 with the proviso that there is one element of group 1 per R4 radical when a group 1 element is selected, one element of group 2 per two R4 radicals when a group 2 element is selected and one element of group 13 per three R4 radicals when a group 13 element is selected. b2) R1, R2, R3 each denote hydrogen, C1-C4-alkyl, C6-aryl, C7-C10-alkylaryl or a radical of the general formula III R4 denotes a radical of the general formula III R6, R7 each denote hydrogen, C1-C4-alkyl, C6-aryl, C7-C10-alkylaryl X denotes O, NH, NR (where R=R6) R5 denotes C1-C10-alkyl, C6-C10-aryl, C7-C14-alkylaryl n denotes an integer between 0 and 15 Y denotes O, N R6, R7 each denote hydrogen, C1-C4-alkyl, C6-aryl, C7-C10-alkylaryl p, q each denote an integer between 0 and 2 with the proviso that at least one of R1, R2, R3 and R4 but not more than two denote the general formula III. b3) R1, R2, R3 each denote hydrogen, C1-C4-alkyl, C6-aryl, C7-C10-alkylaryl R4 denotes a radical of the general formula IV R5 denotes C1-C8-alkyl n denotes an integer between 0 and 4 m, l each denote 0 or 1 R6 denotes C1-C4-alkyl R7 denotes hydrogen, C1-C4-alkyl and X N(R1)(R2) or halogen. b4) R1, R2, R3 each denote hydrogen, C1-C4-alkyl, C6-aryl, C7-C10-alkylaryl R4 denotes a radical of the general formula V X, Y each denote O, N, S R5, R6 each denote C1-C4-alkyl, C1-C4-alkenyl l, m each denote an integer between 0 and 4 n denotes an integer between 0 and 2 R7 denotes hydrogen, C1-C4-alkyl Z denotes sulfate, hydrogensulfate, chloride, bromide, iodide, phosphate, hydrogenphosphate, dihydrogenphosphate p denotes 0, ⅓, ½, 1 and q denotes an integer between 0 and 3. b5) R1, R2, R3 each denote hydrogen, C1-C4-alkyl, C6-aryl, C7-C10-alkylaryl, or a radical of the general formula VI R4 denotes a radical of the general formula VI R5, R7, R8, R11 each denote C1-C6-alkyl, C6-aryl, C7-C10-alkylaryl R6, R12 each denote hydrogen, C1-C4-alkyl, C6-aryl R9, R10 each denote hydrogen, C1-C4-alkyl, C6-aryl, C7-C10-alkylaryl X denotes O E, F, Y, D each denote O, N, S M denotes an element of group 1, 2 or 13 of the periodic table a, k, l, s each denote 0 or 1 m, n, r, w each denote an integer between 0 and 10 o denotes an integer between 0 and 3 p denotes an integer between 0 and 20 q, t, u, v, z each denote an integer between 0 and 2 x denotes 0, ⅓, ½, 1 and y an integer between 1 and 3 with the proviso that at least one of R1, R2, R3 and R4 but not more than 2 denote the general formula VI, in conjunction with c) optionally one or more hydrophilic polymers C or mixtures thereof d) and optionally also further polymers D and mixtures thereof for producing membranes.